Percolating

These fascinating bicontinuous or sponge phases have attracted considerable theoretical interest. Percolation theory [112] is an important component of such models as it can be used to describe conductivity and other physical properties of microemulsions. Topological analysis [113] and geometric models [114] are useful, as are thermodynamic analyses [115-118] balancing curvature elasticity and entropy. Similar elastic modulus considerations enter into models of the properties and stability of droplet phases [119-121] and phase behavior of microemulsions in general [97, 122]. 

From polarization curves the protectiveness of a passive film in a certain environment can be estimated from the passive current density in figure C2.8.4 which reflects the layer s resistance to ion transport tlirough the film, and chemical dissolution of the film. It is clear that a variety of factors can influence ion transport tlirough the film, such as the film s chemical composition, stmcture, number of grain boundaries and the extent of flaws and pores. The protectiveness and stability of passive films has, for instance, been based on percolation arguments [67, 681, stmctural arguments [69], ion/defect mobility [56, 57] and charge distribution [70, 71]. 

The percolation argument is based on the idea that with an increasing Cr content an insoluble interlinked cliromium oxide network can fonn which is also protective by embedding the otherwise soluble iron oxide species. As the tlireshold composition for a high stability of the oxide film is strongly influenced by solution chemistry and is different for different dissolution reactions [73], a comprehensive model, however, cannot be based solely on geometrical considerations but has in addition to consider the dissolution chemistry in a concrete way. 

Its purpose is twofold first of all to prevent any particles of the analysis sample, which is to be added next, from percolating through the coarse porous w ire-form " copper oxide and so into that portion of the tube heated by the furnace and secondly as a heat insulator, to present the sample being heated too rapidly by the nearby furnace. Both these safeguards are required, as otherwise some portion of the sample would be decomposed as soon as the furnace was sw-itched on the nitrogen so produced would be carried away during the initial sweeping of the air out of the tube with the carbon dioxide stream, and would not be collected. Low results w ould thus be obtained. 

The sample solution flows onto a piece of fritted glass through which argon gas flows. The flow of argon is broken down into narrow parallel streams of high linear velocity, which meet the thin film of liquid percolating into the pores of the frit. At the interfaces, an aerosol is formed and is blown from the top of the frit. 

A. E. Rodrigues and D. Tondeur, eds.. Percolation Processes, NATO ASI No. 33, Sijthoff Noordhoff, Alpen aan den Rijn, 1980. 

The sohd can be contacted with the solvent in a number of different ways but traditionally that part of the solvent retained by the sohd is referred to as the underflow or holdup, whereas the sohd-free solute-laden solvent separated from the sohd after extraction is called the overflow. The holdup of bound hquor plays a vital role in the estimation of separation performance. In practice both static and dynamic holdup are measured in a process study, other parameters of importance being the relationship of holdup to drainage time and percolation rate. The results of such studies permit conclusions to be drawn about the feasibihty of extraction by percolation, the holdup of different bed heights of material prepared for extraction, and the relationship between solute content of the hquor and holdup. If the percolation rate is very low (in the case of oilseeds a minimum percolation rate of 3 x 10 m/s is normally required), extraction by immersion may be more effective. Percolation rate measurements and the methods of utilizing the data have been reported (8,9) these indicate that the effect of solute concentration on holdup plays an important part in determining the solute concentration in the hquor leaving the extractor. 

Batch Extractors. Coarse soHds are leached by percolation in fixed or moving-bed equipment. Both open and closed tanks (qv) having false bottoms are used, into which the soHds are dumped to a uniform depth and then treated with the solvent by percolation, immersion, or intermittent drainage methods. 

Moving-bed percolation systems are used for extraction from many types of ceUular particles such as seeds, beans, and peanuts (see Nuts). In most of these cases organic solvents are used to extract the oils from the particles. Pre-treatment of the seed or nut is usually necessary to increase the number of ceUs exposed to the solvent by increasing the specific surface by flaking or rolling. The oil-rich solvent (or misceUa) solution often contains a small proportion of fine particles which must be removed, as weU as the oil separated from the solvent after leaching. 

Immersion extraction systems are usefiil in handling finely ground material or when the percolation rate through the material to be extracted is too rapid to aUow effective diffusion from the soHds. These systems are appHed extensively in the sugar industry, in extraction from oilseeds having a high oil... 

Poly(ethylene oxide). The synthesis and subsequent hydrolysis and condensation of alkoxysilane-terniinated macromonomers have been studied (39,40). Using Si-nmr and size-exclusion chromatography (sec) the evolution of the siUcate stmctures on the alkoxysilane-terniinated poly(ethylene oxide) (PEO) macromonomers of controlled functionahty was observed. Also, the effect of vitrification upon the network cross-link density of the developing inorganic—organic hybrid using percolation and mean-field theory was considered. 

Percolation Leaching. Ground material coarse enough to permit circulation of a solution through a bed of particles can be leached by percolation of the solvent through the material placed ia a tank or vat. The process usually takes several days. 

Dosage forms of naturally occurring materials having therapeutic activity are prepared by extractive processes, especially percolation and maceration. Examples of such dosage forms have included certain tinctures, symps, fluid extracts, and powdered extracts. 

Eor pesticides to leach to groundwater, it may be necessary for preferential flow through macropores to dominate the sorption processes that control pesticide leaching to groundwater. Several studies have demonstrated that large continuous macropores exist in soil and provide pathways for rapid movement of water solutes. Increased permeabiUty, percolation, and solute transport can result from increased porosity, especially in no-tiUage systems where pore stmcture is stiU intact at the soil surface (70). Plant roots are important in creation and stabilization of soil macropores (71). 

The presence of polysulfonates in petroleum sulfonates used in lube formulations has a destabilizing effect on the formulation stabiUty and function of the sulfonate in motor oils, etc. Special techniques are utilized to help reduce the carryover of residual sludge components, including the use of hydrocarbon solvents such as hexane or heptane to faciUtate separation of sludge, often with centrihigation. Other desludging procedures include water wash, H2SO4 wash, clay percolation, and filtration. 

Ma.nufa.cture. In a typical process, a solution of sodium carbonate is allowed to percolate downward through a series of absorption towers through which sulfur dioxide is passed countercurrently. The solution leaving the towers is chiefly sodium bisulfite of typically 27 wt % combined sulfur dioxide content. The solution is then mn into a stirred vessel where aqueous sodium carbonate or sodium hydroxide is added to the point where the bisulfite is fully converted to sulfite. The solution may be filtered if necessary to attain the required product grade. A pure grade of anhydrous sodium sulfite can then be crystallized above 40°C because the solubiUty decreases with increasing temperature. 

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