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Partly integrated models

The model that is most widely used was first revealed by Tryson and Schultz in 1979 [18]. This model analyses a non-steady-state kinetic experiment and allows one to calculate the propagation and termination rate coefficients. The model is based on classical equations and assumes that the only termination reaction is the reaction between two macroradicals, i.e., bimolecular termination. [Pg.132]

The experimental procedure involves initiation of the polymerization by irradiation followed by cutting off the light after a certain time at a degree of conversion chosen, and monitoring the reaction in the dark. As experimental methods, both isothermal differential scanning calorimetry (photocalorimetry, photo-DSC) [2,6, 7, 18-32] and real-time infrared [Pg.132]

The polymerization in the dark (post-effect) that occurs in the absence of initiation, may be described by following equations for reaction rates  [Pg.133]

Expression (4.11) represents a partly integrated bimolecular termination model. [Pg.134]

A plot of the ratio [M]/(Rp), i ,j. t should yield a straight line, which allows the calculation from its slope of the 2k/kf ratio. However, just at the beginning of the dark period, often deviations from linearity are observed. These deviations are attributed to the response time of DSC and to sample conductivity [18]. Thus, this technique can be applied for the determination of the rate coefficients of those monomers which show an appreciable residua) rate, well beyond the time of reaching linearity of [M],/(Rp), vs. t function. However, deviations may also result, in part, from the fact that the kinetic model used is inadequate, or that the rate coefficients change with the time of the dark reaction. [Pg.134]


Calculating a geochemical model provides not only results, but uncertainty about the accuracy of the results. Uncertainty, in fact, is an integral part of modeling that deserves as much attention as any other aspect of a study. To evaluate the sources of error in a study, a modeler should consider a number of questions ... [Pg.22]

The last part of the book is devoted to the development of simple integrative models of organic chemicals in real environmental systems. The compound-specific tools derived in Parts II and III will be combined with the modeling tools of Part IV. As before, the aim of the discussion is not to compete with the many rather sophisticated models of environmental systems which can be found in the literature, but to concentrate on the simple models which can be analyzed by hand or with desk calculators. [Pg.1050]

Supporting information is obtained for this period from interviews and by reviewing documentation generated by operations, R D, QA, and Engineering/IT. Part 11 should be included as part of the integrated model of the operation to be automated or reengineered. [Pg.206]

The numerical model-Simulator NV-Simulator V. At this point, we must find the more suitable variant for passing from the differential or partly differential model equations to the numerical state. For the case of the monodimensional model, we can select the simplest numerical method - the Euler method. In order to have a stable integration, an acceptable value of the integration time increment is recommended. In a general case, a differential equations system given by relations (3.55)-(3.56) accepts a simple numerical integration expressed by the recurrent relations (3.57) ... [Pg.57]

The extension on the meta level comprises two parts First, graph- and integration-related definitions are added. These are used by all integration rule sets. Second, domain-specific extensions can be made. They can facilitate the definition of integration models when being combined with domain-specific... [Pg.232]

In the case study on integrator modeling (see Sect. 6.3, column (c) in Fig. 6.1) we find general specifications, either as a basic layer of the conceptual realization model in the form of graph transformation rules, or in a coded form as a part of the integrator framework. Specific models are introduced to represent link types, link templates, and rules of TGGs. Thereby, different forms of determinations for specific are introduced in one step. [Pg.633]

The CIMOSA reference architecture, developed by the AMICE consortium within the European ESPRIT project, is a set of semiformal structures and semantics that is intended to be used as a modeling language environment for any business enterprise. The basic constructs and fundamental control structures of the architecture are collected in volumes called Eormal Reference Base 11 (FRB) and Eormal Reference Base III. FRB consists of two parts the modeling framework and the integrating infrastructure (IIS). [Pg.511]

Enterprise-Control System Integration Part 1 Models and Terminology (ANSI/ISA... [Pg.1769]

Adachi, T, Talavage, J. J., and Moodie, C. L. (1989), A Rule-Based Control Method for a Multiloop Production System, Artificial Intelligence in Engineering, Vol. 4, No. 3, pp. 115-125. ANS1/1SA-S95.00.01-2000 (2000), Enterprise-Control System Integration Part I Models and Terminology, International Standards Assocation, Research Triangle Park, NC. [Pg.1787]

An advanced approach to assembly modeling is its full integration with part modeling. Assembly modeling is done in an assembly model space where parts are modeled to define shapes and dimensions that are affected by the assembly. Additional details of the part are modeled in the part model space. Part models can be created for an assembly in accordance with their place in a predefined product assembly tree. This is the top-down approach. Existing part models can be used to create a product assembly tree. This is the bottom-up approach. Engineering practice mixes these two approaches because some parts are available at the start of the modeling of a mechanical system while other parts are to be modeled on the basis of their place in the assembly tree. Eor multiple applications of a part model, it is not duplicated but referred from the assembly model. [Pg.35]

Concurrent modeling in the form of group work of engineers is the advanced style of engineering. The assembly and its individual parts are developed concurrently, in an integrated process. Parts are modeled in an assembly context with user-controlled associativity. At the same time, part related specifications can be managed independently from assembly related specifications. The shape description of a part can be reused in other parts. Splitting a... [Pg.287]

H. Van Brussel, J. Wyns, P. Valckenaers, L. Bongaerts, P. Peeters, Reference architecture for holonic manufacturing systems PROSA, Computers in Industry. 37 (1998) 255-274. International Electrotechnical Commission, Enterprise-control system integration - Part 1 Models and terminology, lEC, Geneva, Switzerland, 2003. [Pg.156]

Substituting [P ]=(/fp)/(< p[M]) and rearranging we obtain a partly integrated monomolecular termination model ... [Pg.136]

Model II corresponds to the model introduced by Tryson and Schuiz but is fully integrated. Model I corresponds to the partly integrated monomolecular termination model. Note that models (4.19)-(4.21) are not linear thus, because they do not require assumption of linearity, they are more accurate. From these models the following parameters can be calculated p[P ]o and ki/k. These models require only the knowledge of the... [Pg.137]

The bimolecular termination model in its simplified, partly integrated form (equation (4.11)) has been extensively used for the estimation of the polymerization rate coefficients in cross-linking systems [2,6,7,18,20-25]. [Pg.138]

Mutlu, F. and S. (Jetinkaya. 2010. An integrated model for stock replenishment and shipment scheduling under common carrier dispatch costs. Transportation Research Part E. 46(6) 844-854. [Pg.226]

Incorporation of uncertainties on data, parameters, models into the assessment and to consider quality assurance as an integral part in model development and application is needed ... [Pg.80]

Panopoulos K D, Frida. E, Karl J, Poulou S and Kakaras E, High temperature solid oxide fuel cell integrated with novel allothermal biomass gasification - Part I Modeling and feasibility study , Journal of Power Source, 2006,159, 570-585. [Pg.39]

Quelhas A., Gil E., McCalley J.D. et al., 2007. A Multiperiod Generalized Network Flow Model of the U.S. Integrated Energy System Part I Model Description. IEEE Transactions on Power Systems, 22(2) 829-36. [Pg.2067]


See other pages where Partly integrated models is mentioned: [Pg.132]    [Pg.132]    [Pg.199]    [Pg.233]    [Pg.345]    [Pg.119]    [Pg.313]    [Pg.108]    [Pg.46]    [Pg.152]    [Pg.100]    [Pg.165]    [Pg.748]    [Pg.232]    [Pg.343]    [Pg.616]    [Pg.2455]    [Pg.2726]    [Pg.341]    [Pg.777]    [Pg.42]    [Pg.199]    [Pg.286]    [Pg.442]    [Pg.206]    [Pg.85]    [Pg.299]    [Pg.1027]   


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