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Nanocomposites halloysite

Du et al. (50) reported the synthesis of butadiene styrene rubber nanocomposites with halloysite nanotubes. The tensile properties of the composites containing various amounts of nanotubes are depicted in Table 2.2. The tensile properties were observed to significantly increase as a function of increasing amount of nanotubes in the composites. For the maximum loading of the nanotubes, a tensile modulus of 5.56 MPa was observed as compared to 1.52 MPa for the pure polymer. [Pg.32]

Table 2.2. Mechanical properties of butadiene styrene rubber nanocomposites with halloysite nanotubes... Table 2.2. Mechanical properties of butadiene styrene rubber nanocomposites with halloysite nanotubes...
Pooria Pasbakhsh, PhD, is currently a Lecturer at the School of Engineering, Monash University Sunway Campus, Malaysia. Dr. Pasbakhsk s research has been centered on the development and application of computational approaches and experimental tools for modern polymers, halloysite nanotubes, and polymer clay nanocomposites. [Pg.309]

AUi Alhuthali, A., Low, I. M. Water absorption, mechanical, and thermal properties of halloysite nanotube reinforced vinyl-ester nanocomposites. J. Mater. Sci. 48 (2013) 4260-4273. [Pg.556]

Well-defined coaxial tubular halloysite nanotubes (HNTs)/PPy nanocomposites were synthesized for use as electrode materials for supercapacitors by the in situ chemical oxidative polymerization method based on self-assembled monolayer amine-functionalized HNTs [72]. It showed their greatest conductivity (40 S/cm) at room temperature and a weak temperature dependence of the conductivity from 298 K to 423K. A maximum discharge capacity of 522 F/g after correcting for the weight percent of the PPy phase at a current density of 5 mA/cm in a 0.50 mol/L Na SO electrolyte solution could be achieved in a half-cell setup configuration for the HNTs/PPy composites electrode. [Pg.438]

Pasbakhsh, R, Ismail, FI., Ahmad Fauzi, M. N., and Abu Bakar, A. 2009. Influence of maleic anhydride grafted ethylene propylene diene monomer (MAH-g-EPDM) on the properties of EPDM nanocomposites reinforced by halloysite nanotubes. Polymer Testing 28 548-559. [Pg.326]

Haroosh, H., Chaudhary, D, Dong, Y, and Hawkins, B (2011) Electrospun PLA PCL/halloysite nanotube nanocomposites fibers for drug delivery. Proceedings... [Pg.212]

PLA Electrospun Nanocomposite Fibres witb Halloysite Nanotubes... [Pg.180]

Sepiolite is a fibrillar silicate which has been also used as a nanoclay in PLA, compared with both montmorillonite and halloysite. The use of pillared serpentines as support for ZnO catalyst for PLA polymerization has been recently reported. Zhang et al. obtained vermiculite/PLA nanocomposite by in situ polymerization of the PLA °. The use of different synthetic micas as nanofillers in PLA has also been evaluated. ... [Pg.218]

Nanocomposites of plasticized starch with halloysite nanotubes (HNT) were investigated for their use in controlled drug delivery applications and showed retarding of drug release. They exhibited swelling, which depends on temperatme but not pH [46]. Nanocomposites of starch with bis-demethoxy curcumin analog loaded Chitosan also showed retarded and sustainable drug release [47]. [Pg.493]

H. Schmitt, N. Creton, K. Prashantha, J. Soulestin, M.R Lacrampe, and P. Krawczak, Melt-blended halloysite nanotubes/wheat starch nanocomposites as drug delivery system, Polym. Eng. Sci., 55, 573-580,2015. [Pg.513]

Clay minerals, the micas, chlorite, serpentine, talc, between them can also find within the group of minerals phyllosilicates or layered silicates. They all have different morphology, structure, and texture (Bergaya et al. 2009). The some representative layer silicates used mainly in nanocomposites-based starch are listed in Table 2. It is important to note that the some phyllosilicates do not display a normal layered strucmre, for example, the sepiolite shows a fibrous structure meanwhile halloysite has spheroidal aggregates morphology (Duquesque et al. 2007 Bergaya et al. 2009). [Pg.43]

The dispersion state of a typical phyllosilicate (except sepiolite and halloysite) in a matrix polymer depends on the preparation conditions and the matrix-nanolayer affinity. This effect determines the structure of the resulting composites, which can be either phase separated composites (microcomposites), intercalated nanocomposites, or exfoliated nanocomposites (Alexandre and Dubois 2000). [Pg.44]

Abdullayev E, Joshi A, Wei W, Zhao Y, Lvov Y (2012) Enlargement of halloysite clay nanotube lumen by selective etehing of aluminum oxide. ACS Nano 6(8) 7216-7226 Alexandre M, Dubois P (2000) Polymer-layered silicate nanocomposites preparation, properties and uses of a new class of materials. Mater Sci Eng R Rep 28(1-2) 1-63 Aice A, Earle MJ, Katdare SP, Rodriguez H, Seddon KR (2007) Phase equilibria of mixtures of mutually immiscible ionie liquids. Fluid Phase Equilib 261(l-2) 427 33 Azizi Samir MAS, Alloin F, Dufresne A (2005) Review of recent research into cellulosic whiskers, their properties and their application in nanocomposite field. Biomacromolecules 6(2) 612-626... [Pg.316]

Du M, Guo B, Lei Y, Liu M, Jia D (2008) Carboxylated butadiene-styrene rubber/halloysite nanotube nanocomposites interfacial interaction and performance. Polymer 49(22) 4871-4876 Feng L, Chen Z (2008) Research progress on dissolution and functional modification of cellulose in ionic liquids. J Mol Liq 142(1-3) 1-5... [Pg.317]

Guo B, Chen F, Lei Y, Liu X, Wan J, Jia D (2009) Styrene-butadiene rubber/halloysite nanotubes nanocomposites modified by sorbic acid. Appl Surf Sci 255(16) 7329-7336 Gutowski KE, Broker GA, Willauer HD, Huddleston JG, Swatloski RP, Holbrey JD, Rogers RD (2003) Controlling the aqueous miscibility of ionic liquids aqueous biphasic systems of water-miscible ionic liquids and water-structuring salts for recycle, metathesis, and separations. J Am Chem Soc 125(22) 6632-6633... [Pg.317]

Hanid NA, Wahit MU, Guo Q, Mahmoodian S, Soheilmoghaddam M (2014) Development of regenerated cellulose/halloysites nanocomposites via ionic liquids. Carbohydr Polym 99 91-97 Hashemifard SA, Ismail AF, Matsuura T (2011) Mixed matrix membrane incorporated with large pore size halloysite nanotubes (HNT) as filler for gas separation experimental. J Colloid Interf... [Pg.317]

Hedicke-Hbchstotter K, T.im GT, Altstadt V (2009) Novel polyamide nanocomposites based on silicate nanotubes of the mineral halloysite. Compos Sci Technol 69(3-4) 330-334 Hermanutz F, Gahr F, Utadingen E, Meister F, Kosan B (2008) New developments in dissolving and processing of cellulose in ionic liquids. Macromol Symp 262(l) 23-27 Hyden WL (1929) Manufacture and poperties of regenerated cellulose films. Ind Eng Chem 21 (5) 405-410... [Pg.317]

Tang Y, Deng S, Ye L, Yang C, Yuan Q, Zhang J, Zhao C (2011) Effects of unfolded and intercalated halloysites on mechanical properties of halloysite-epoxy nanocomposites. Compos A Appl Sci Manuf 42(4) 345-354... [Pg.319]

Styryltropylium (a carbo-cation) was used to modify clay for producing PS nanocomposites by in situ emulsion polymerization (Table 3.4) [60]. The resulting nanocomposites exhibited a mixture of intercalated and exfoliated structures. The nanocomposites exhibited improved thermal stability and fire retardancy. Halloysite nanotubes (HNT) are a kind of aluminosilicate clay with a hollow nanotubular structure (about 20-50 nm in diameter and several hundred nanometers in length) [61]. HNT was modified with y-methacryloxypropyltrimethoxysilane to produce a nanoclay (Table 3.4). HNT/PS nanocomposites were prepared by in situ bulk polymerization. The thermal stability of the HNT/PS nanocomposites was better than that of the pure polystyrene. [Pg.82]

M. Zhao and P. Liu, Halloysite nanotubes/polystyrene (HNTs/PS) nanocomposites via in situ bulk polymerization. Journal of Thermal Analysis and Calorimetry, 94 (2008), 103-7. [Pg.97]

Guo et al. has shown the interfacial interaction in the nanocomposites between carboxylated SBR and halloysite nanotube (HNT) [106]. Lower content of HNT tends to impediment the vulcanization of SBR/HNT compounds, while higher HNT loading promotes the vulcanization presumably due to polar interactions. It is noteworthy to mention that HNT are dispersed uniformly in the matrix with strong interfacial bonding between SBR and HNT. [Pg.29]

Rybinski P, Janowska G (2012) Thermal properties and flammability of nanocomposites based on nitrile rubbers and activated halloysite nanotubes and carbon nanofibers. Thermochim Acta 549 6-12... [Pg.39]

Khunova V, Kristof J, Kelnar I, Dybal J (2013) The effect of halloysite modification combined with in situ matrix modifications on the structure and properties of polypropylene/halloysite nanocomposites. eXPRESS Polym Lett 7(5) 471-479... [Pg.58]


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