Methyl cyclohexyl ether, oxidation

The (partial) description of the synthesis and coupling of the five fragments starts with the cyclohexyl moiety C —C. The first step involved the enantio- and diastereoselective harpless epoxidation of l,4-pentadien-3-ol described on p. 126f. The epoxide was converted in four steps to a d-vinyl d-lactone which gave a 3-cyclohexenecarboxylate via Ireland-CIaisen rearrangement (cf. p. 87). Uncatalysed hydroboration and oxidation (cf. p. 131) yielded the desired trans-2-methoxycyclohexanol which was protected as a silyl ether. The methyl car-... 

Cyclohexanone, 23,35 Cyclohexene oxide, 137 Cyclohcxyl methyl ether, 137 l-Cydohexyl-2-methylpropene, 68-9 ( )-l-Cyclohexyl-2-trimethyl ilylethene, 12 (Z)-l-Cyclohexyl-2-trimethylsilylelhene, 12 l-Cydohcxyl-2-trimethylsilylethyne, 12 (2-Cyclohexylidene-eihyl)trimethylsilane, 29 Cyclopentadec-2-ynone, 48 Cydopentadiene, 25 Cyclopentanone, 72 Cyclopentenones, 15 Cyclopropanone, 133... 

PB PBI PBMA PBO PBT(H) PBTP PC PCHMA PCTFE PDAP PDMS PE PEHD PELD PEMD PEC PEEK PEG PEI PEK PEN PEO PES PET PF PI PIB PMA PMMA PMI PMP POB POM PP PPE PPP PPPE PPQ PPS PPSU PS PSU PTFE PTMT PU PUR Poly(n.butylene) Poly(benzimidazole) Poly(n.butyl methacrylate) Poly(benzoxazole) Poly(benzthiazole) Poly(butylene glycol terephthalate) Polycarbonate Poly(cyclohexyl methacrylate) Poly(chloro-trifluoro ethylene) Poly(diallyl phthalate) Poly(dimethyl siloxane) Polyethylene High density polyethylene Low density polyethylene Medium density polyethylene Chlorinated polyethylene Poly-ether-ether ketone poly(ethylene glycol) Poly-ether-imide Poly-ether ketone Poly(ethylene-2,6-naphthalene dicarboxylate) Poly(ethylene oxide) Poly-ether sulfone Poly(ethylene terephthalate) Phenol formaldehyde resin Polyimide Polyisobutylene Poly(methyl acrylate) Poly(methyl methacrylate) Poly(methacryl imide) Poly(methylpentene) Poly(hydroxy-benzoate) Polyoxymethylene = polyacetal = polyformaldehyde Polypropylene Poly (2,6-dimethyl-l,4-phenylene ether) = Poly(phenylene oxide) Polyp araphenylene Poly(2,6-diphenyl-l,4-phenylene ether) Poly(phenyl quinoxaline) Polyphenylene sulfide, polysulfide Polyphenylene sulfone Polystyrene Polysulfone Poly(tetrafluoroethylene) Poly(tetramethylene terephthalate) Polyurethane Polyurethane rubber... 

Butyl myristate Methyl cocoate Oleyl alcohol PEG-300 oleate PEG-300 stearate Propylene glycol myristate plasticizer, delayed tack latex 1,4-Cyclohexanedimethanol dibenzoate plasticizer, dental adhesives n-Butyl phthalyl-n-butyl glycolate plasticizer, dental compounds Carnauba (Copemica cerifera) wax plasticizer, dental impression compounds Japan (Rhus succedanea) wax plasticizer, deodorants Hexyldecyl benzoate plasticizer, depilatories Oxidized beeswax plasticizer, detergents PPG-20 lanolin alcohol ether plasticizer, dip parts Diphenyl octyl phosphate plasticizer, dopes Di butyl tartrate plasticizer, dry cleaning PEG-8 cocoate PEG-20 hydrogenated castor oil PEG-60 hydrogenated tallowate PEG-12 ricinoleate PEG-2 stearate PEG-2 tallowate plasticizer, elastomers Butyl acetyl ricinoleate Butyl cyclohexyl phthalate Dibutyl phthalate Dibutyl tartrate n-Dioctyl phthalate... 

Mesityl oxide Methyl benzoate Nitroethane Propyl alcohol Propylene dichloride Tetrahydrofurfuryl alcohol Trichloroethylene solvent, cellulose ethers Acetone oxime Acetophenone Butyl benzoate Butyl formate Cyclohexane Cyclohexyl acetate Dibutyl tartrate Diethyl oxalate Epichlorohydrin Ethyl butyrate Ethylene glycol diacetate Ethyl-(S)-lactate Ethyl propionate Isopropyl butyrate Mesityl oxide... 

Notes The values of A, B, and C and thus of y are based on a reference volume Vre/ = 0.1 nm Polymer notation A d- label preceding the polymer acronym indicates a per-deuterated polymer partially deuterated polymers are labeled as dy, df, etc., for selective deuteration of 3, 4, etc., hydrogens. Numbers in subscripted parentheses after the polymer name indicate the primary comonomer fraction, e.g., SPB(6s) is a saturated polybutadiene with 66 mol% butadiene Polymer acronyms P2VP poly(2-vinyl pyridine), P4MS poly(4-methylstyrene), PBMA poly(n-butyl methacrylate), PCHA poly(cyclohexyl acrylate), PEB poly(ethyl butylene), PIB polyisobutylene, PI polyisoprene, PMMA poly(methyl methacrylate), PPMA poly(n-pentyl methacrylate), PP polypropylene, HHPP head-to-head polypropylene, PS polystyrene, PVME poly(vinyl methyl ether), PXE poly(2,6-dimethyl-l,4-phenylene oxide), SPB saturated polybutadiene, SPI saturated polyisoprene... 

---