Cyclohexyl acetate

M-Butyl formate. Ethyl iso-butyrate IsO -butyl acetate Ethyl butyrate -Propyl propionate Iso-amyl formate, -But> l acetate Iso-propyl butyrate Iso-butyl propionate n-Propyl -butyrate -Butyl propionate Iso-butyl isobutyrate Ethyl lactate Iso-butyl butyrate Cycloheicyl formate -Butyl -butyrate Iso-propyl lactate. Cyclohexyl acetate Diethyl oxalate Di-iao-propyl oxalate... 

Isoamyl acetate (banana Vinyl acetate Methyl vinyl acetate Benzyl acetate Cyclohexyl acetate... 

Cyclohexyl methyl ketone gives cyclohexyl acetate, bp 74-77°/23 mm,... 

In nucleophilic solvents, products that arise from reaction of the solvent with the cationic intermediate may be formed. For example, reaction of cyclohexene with hydrogen bromide in acetic acid gives cyclohexyl acetate as well as cyclohexyl bromide. This occurs because acetic acid acts as a nucleophile in competition with the... 

The stereochemistry of products 27 (Table 6, entries 2, 3, and 4) can be explained distinctly on the same basis that alkyl substituents R1, R2 are positioned in quasi equatorial positions in the transition structure. Exclusive formation of the all-cis isomer in the reaction of cyclohexyl acetate (entry 5) is further evidence to support the oxido-carbene interaction in a double-chaired bicyclic structure 28, as depicted in Scheme 13, Eq. 1. 

Cyclohexyl halides may undergo elimination or substitution reactions. They are usually more prone to elimination, but the acetate anion MeCC>2 is not particularly basic, and nucleophiles are particularly nucleophilic in the polar aprotic solvent DMF. More cyclohexyl acetate (substitution) than cyclohexene (elimination) is likely to form. 

Lead tetraacetate is used as a highly selective oxidizing agent in organic synthesis. This includes oxidation of glycols into aldehydes, preparation of cyclohexyl acetate, production of oxahc acid, and in structural analysis of sugars. 

The equation (conformational) for the pyrolysis of cyclohexyl acetate drawn and explained ... 

Two possible chair conformations for cyclohexyl acetate are axial-acetoxyl and equatorial-acetoxyl. 

Apple Allyl butyrate, cyclohexylvalerate, isovalerate, propionate Benzyl isovalerate Butyl isovaleratc. valerate Cinnamyl formate, isobuiyrate. isovaleraie Citronellyl isovaleraie Cyclohexyl acetate, butyrate, isovalerate Ethyl isovalerate, valerate Isopropyl acetate, valerate 2-Methylallyl butyrate Methyl butyrate Terpenyl isovaleraie... 

Banana Cyclohexyl acetate, butyrate, propionate Ethyl valerate. 

The influence of the heteroatom on the acid strength is shown, for example, in Fig. 28. Here the rates of alkylation of 1,3,5-trimethylbenzene and the decomposition of cyclohexyl acetate catalyzed by the acid forms of several 12-tungstates are plotted against the negative charge of polyanion for solid heteropolyacids (63, 183). The catalytic activities correlate well with the acid strength in solution (Fig. 14). This correlation indicates that the acid strength of... 

Fig. 28. Catalytic activities (per surface proton) as a function of the negative charge of polyanion, XW12O40. (O) Alkylation of 1,3,5-trimethyIbenzene with cyclohexene ( ) decomposition of cyclohexyl acetate. (From Ref. 183.)...

As described in Section II, the pore size of the acidic Cs salts can be controlled by the Cs content. CS2.2H0.8PW12O40 (Cs2.2) has pores having an effective size of 6.2-7.5 A, and the pore size of Cs2.5 is larger than 8.5 A. Figure 30 shows the catalytic activities of Cs2.1 (the pore size is less than 5.9 A) and Cs2.2 for each reaction relative to the activity of Cs2.5 (48). Cs2.5 catalyzed all the reactions with considerable activities (the reaction rates are shown in parentheses in Fig. 30). On the other hand, although Cs2.2 was found to be as active as Cs2.5 for dehydration of 2-hexanol (molecular size, 5.0 A) and decomposition of isopropyl acetate (molecular size, 5.0 A), it was much less active for the decomposition of cyclohexyl acetate (molecular size, 6.0 A) and alkylation of 1,3,5-trimethylbenzene (molecular size, 7.5 A). Therefore, Cs2.2 is... 

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