Metals testing

Hepner H., Stroppe H. Magnetic and induction metal tests Issued by Slqsk 1972... 

Section 3. Metals Test Methods and Analytical Practices (6 vols.)... 

For contact testing a couplant normally is used between the probe and the test piece. This material may be oil, water, or some gel or other Hquid or paste. Compatibihty with the test object is important, so that no unexpected chemical attack occurs, causing a crack to initiate. Whereas the frequency range for ultrasonic tests may extend from approximately 50 kH2 to 50 MH2, the range most commonly used for metallic test materials is 0.5—25 MH2. 

Multiple Metals Testing The samphng method commonly used to measure emissions of metals from stationaiy sources is contained in 40 CFR 266, Appendix IX. The procedure is titled Methodology for the Determination of Metals Emissions in Exhaust Gases from Hazardous Waste Incineration and Similar Combustion Processes. It is also currently pubhshed as Draft EPA Method 29 for inclusion in 40 CFR 60. 

Chemical composition or trade name of metals tested Form and metallurgical conditions of specimens Exact size, shape, and area of specimens Treatment used to prepare specimens for test... 

Corrosion tests of metals under static conditions reveal nothing relating to erosion-corrosion susceptibilities. It is entirely possible that a metal tested under static conditions will fail in service when sufficient fluid velocity produces erosion-corrosion. Similarly, it has been observed that galvanic corrosion between coupled, dissimilar metals may be accelerated or even initiated under flow conditions when little or no galvanic corrosion is observed under static conditions (see Chap. 16, Galvanic Corrosion ). 

Lefrancois, P. A. and Hoyt, W. B., Chemical Thermodynamics of High Temperature Reactions in Metal Testing Corrosion , Corrosion, 19, 360t (1963)... 

Because cast iron components are normally very heavy in section, the relatively low rates of attack associated with atmospheric corrosion do not constitute a problem and little work has been carried out on the phenomenon. A summary of some of the data available is given in Table 3.42. The most extensive work in this field was initiated by the A.S.T.M. in 1958 and some of the results produced by these studies are quoted in Table 3.43. It will be noted that there is a marked fall in corrosion rate with time for all the metals tested. 

The precautions generally applicable to the preparation, exposure, cleaning and assessment of metal test specimens in tests in other environments will also apply in the case of field tests in the soil, but there will be additional precautions because of the nature of this environment. Whereas in the case of aqueous, particularly sea-water, and atmospheric environments the physical and chemical characteristics will be reasonably constant over distances covering individual test sites, this will not necessarily be the case in soils, which will almost inevitably be of a less homogeneous nature. The principal factors responsible for the corrosive nature of soils are the presence of bacteria, the chemistry (pH and salt content), the redox potential, electrical resistance, stray currents and the formation of concentration cells. Several of these factors are interrelated. 

Recommended practice for conducting atmospheric stress corrosion tests on metals Test method for pH of soil for use in corrosion testing... 

It is important for the designer to become familiar with all the information that is available for each plastic, especially that which is pertinent to the product design requirements. Designers, who are knowledgeable of the data derived from metal tests, could have a tendency to apply the plastic data sheet information in a manner similar to that used for metals. This could be understood because there is no warning that some of the data supplied by the manufacturer are applicable only when use and test conditions are nearly the same. 

Spirodela intermedia, L. minor, and P. stratiotes were able to remove Pb(II), Cd(II), Ni(II), Cu(II), and Zn(II), although the two former ions were removed more efficiently. Data fitted the Langmuir model only for Ni and Cd, but the Freundlich isotherm for all metals tested. The adsorption capacity values (K ) showed that Pb was the metal more efficiently removed from water solution (166.49 and 447.95 mg/g for S. intermedia and L. minor, respectively). The adsorption process for the three species studied followed first-order kinetics. The mechanism involved in biosorption resulted in an ion-exchange process between monovalent metals as counterions present in the macrophytes biomass and heavy metal ions and protons taken up from water.112... 

Laser ablation ICP-AES and LA-ICP-MS were also proposed for rapid, direct analysis of tablets containing metallic species.194 Compendial heavy metal tests based on wet chemistry are among the most labor-intensive tasks in pharmaceutical laboratories. Both ICP-MS and ICP-OES have been proposed as alternatives for compendial methods and have the advantages of smaller sample size, element-specific information, quantitation, rapid sample throughput, and significantly improved accuracy.195-198... 

Over most of the alumina supported metals tested by Grenoble and coworkers,229 the reaction orders were found to be close to zero for the metal, and close to 1 /2 for H20, lending further credence to the possibility of a formate-based mechanism operating for water-gas shift. 

G = A metal test tube cover to exclude extraneous light. 

The separation of basic and metal-sensitive compounds is difficult on silica-based stationary phase materials, but these separations can be performed on vinyl alcohol copolymer gels. Examples are the separation of methallothionein from dolphin kidney, a-, j8-, and y-endorphin, and nucleotide and nucleoside mixtures.8 However, an analytical-scale separation may also be performed on surface-modified wide-pore silica gels (pore size 300 A or more), using columns which showed a negative response in the heavy metal test described above. 

Upon obtaining this information a nnmber of heavy metal tests were carried out but the levels were found to be insignificant. Enrther reflection on the problem led to the idea that EDTA is itself a base and the degradation was also known to be enhanced via low pH. Accordingly, experiments were carried out varying the bases used to determine if the cnlprit of the degradation problem was excess acid in the drug substance (Table 3). 

Ozone decay was measured in an office, a home, and several metal test facilities. Measurements were carried out with a Mast ozone meter and an MEC chemiluminescence ozone detector. The latter was calibrated with a stable ozone source and the epa neutral buffered potasaum iodide procedure. (It was noted over a wide range of concentrations that the mec meter measurements were consistently higher than those of the Mast meter by a factor of 1.3. That this is essentially identical with the findings of the DeMore committee is interesting.) Ozone generated by a positive corona ionizer was introduced into the test facilities. Ozone decay in a metal-walled room was found to be first-order, with the rate constant... 

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