Measurement optical methods

Combustion (Flame) Temperature of Propellants Measurements. Optical methods are the most widely used for the measurement of flame temperature. Since the study of a flame depends not only on temperature, but also on other factors (the radiation factor, the chemical reactions in the gases, etc), it is necessary first of all to study the spectral characteristics of the objects under investigation. Flame spectra were studied in Russia on the ISP-51 spectrograph... 

Another method which should be cited apart from the others is to pyrolyze the sample in a hydrogen atmosphere. The sulfur is converted to H2S which darkens lead-acetate-impregnated paper. The speed of darkening, measured by an optical device, provides the concentration measurement. This method attains sensitivity thresholds of 0.02 ppm. 

Often industry requires fast techniques to measure movements, deformations, etc. The optics methods, between them those based in speckle K gives quick solutions to this problems. 

We present two optical methods for characterizing wire surfaces. These methods allow us to measure the roughness and the correlation length of the surface. It is also possible to identify qualitatively, at a glance, the variations of the roughness along a wire or among its different zones. 

The absolute measurement of the distance, D, between the surfaces is central to the SFA teclmique. In interferometric SFAs, it is realized tluough an optical method called multiple beam interferometry (MBI), which has been described by Tolansky [47]. 

We can imagine measuring experimental curves equivalent to those in Fig. 9.11 by, say, scanning the length of the diffusion apparatus by some optical method for analysis after a known diffusion time. Such results are then interpreted by rewriting Eq. (9.85) in the form of the normal distribution function, P(z) dz. This is accomplished by defining a parameter z such that... 

Magnesium anodes are usually built into the object to be protected through isolating sockets or holes (see Fig. 20-6) and joined to them with cables. They must be readily accessible and easily exchangeable for convenient control [4]. The directions for use have to indicate the necessity for an inspection after 2 years of operation. During operation, control can be exercised by electrical measurements (current, resistance). In addition, acoustic and optical methods exist to determine the amount of anode consumption [4]. The life of the anodes is usually more than 5 years (see Section 6.6). 

Basically, the optical method uses equipment such as alignment telescopes, jig transits, and sight levels. Instruments with built-in optical micrometers for measuring displacements from a referenced line of sight enable an accurate determination of target movements, which are mounted on the machine. 

For SFM, maintaining a constant separation between the tip and the sample means that the deflection of the cantilever must be measured accurately. The first SFM used an STM tip to tunnel to the back of the cantilever to measure its vertical deflection. However, this technique was sensitive to contaminants on the cantilever." Optical methods proved more reliable. The most common method for monitoring the defection is with an optical-lever or beam-bounce detection system. In this scheme, light from a laser diode is reflected from the back of the cantilever into a position-sensitive photodiode. A given cantilever deflection will then correspond to a specific position of the laser beam on the position-sensitive photodiode. Because the position-sensitive photodiode is very sensitive (about 0.1 A), the vertical resolution of SFM is sub-A. 

From a practical sense, MOKE is a versatile technique it is an optical method the polarization measurement is fairly easy to do the necessary optical components are common and relatively inexpensive and it has no intrinsic vacuum requirements. 

The number of measurable layers of a stack is limited only by the optical contrast between the different layers. In practice stacks of ten layers and more can be analyzed by ellipsometry. Further advantages of ellipsometry compared with other metrological methods are the non-invasive and non-destructive character of the optical method, the low energy entry into the sample, the direct measurement of the dielectric function of materials, and the possibility of making the measurement in any kind of optical transparent environment. 

In view of this apparent contradictory outcome from the transport and magnetic properties, we were motivated to investigate the dynamics of the charge excitation spectrum by optical methods. In fact, the optical measurement is a powerful contactless experimental tool which should in principle allow to unfold the disagreement between and p(7 since the optical response of a metal... 

While the dial-indicator and optical methods differ in the equipment and/or equipment setup used to align machine components, the theory on which they are based is essentially identical. Each method measures the offset and angularity of the shafts of movable components in reference to a pre-selected stationary component. Each assumes that the stationary unit is properly installed and that good mounting, shimming, and bolting techniques are used on all machine components. 

Optical methods of analysis are dependent either upon (i) measurement of the amount of radiant energy of a particular wavelength absorbed by the sample, or (ii) the emission of radiant energy and measurement of the amount of energy of a particular wavelength emitted. Absorption methods are usually classified according to the wavelength involved as (a) visible spectrophotometry (colorimetry), (b) ultraviolet spectrophotometry, and (e) infrared spectrophotometry. 

Phosphoric acid ester was used as a model for the estimation of concentration of a reagent in an adsorbed layer by optical measurements of the intensity of a beam reflecting externally from the liquid-liquid interface. The refractive index of an adsorbed layer between water and organic solution phases was measured through an external reflection method with a polarized incident laser beam to estimate the concentration of a surfactant at the interface. Variation of the interfacial concentration with the bulk concentration estimated on phosphoric acid ester in heptane and water system from the optical method agreed with the results determined from the interfacial tension measurements... 

As a major branch of nanotribology. Thin Film Lubrication (TFL) has drawn great concerns. The lubricant him of TFL, which exists in ultra precision instruments or machines, usually ranges from a few to tens of nanometres thick under the condition of point or line contacts with heavy load, high temperature, low speed, and low viscosity lubricant. One of the problems of TFL study is to measure the him thickness quickly and accurately. The optical method for measuring the lubricant him thickness has been widely used for many years. Goher and Cameron [3] successfully used the technique of interferometry to measure elastohydrody-namic lubrication him in the range from 100 nm to 1 /rm in 1967. Now the optical interference method and Frustrated Total Reflection (FTR) technique can measure the him thickness of nm order. 

A number of variations of the transient hot-wire method have been devised, and an optical method to detect the temperature rise has been used. A modified transient hot-wire technique using a mercury-incapillary probe was introduced by Nagashima et al., in which a thin mercury thread was used as a heater-thermometer and the capillary wall as an insulator. Using this method, they measured the thermal conductivity in mixture systems such as (Na, K)N03, (Li, Na)N03, and HTS(KN03-NaN03-NaN02, 44-7-49 mol.%). ... 

Optical Methods Reflectance and ellipsometry snffer from lack of a theory at the molecnlar level. The same is true for SERS and SHG. The main advances will be in the nse of far-IR spectroscopy and SFG. SFG measurements performed with femtosecond lasers open np new possibilities for time-resolved adsorbate stndies. 

The water content is measured most conveniently via the dew point, but electrical and optical methods are also available. The dew point is connected most directly to hydrate formation, because it is believed that condensate formation is essential before the formation of hydrates. 

Nucleation and growth of gas hydrate crystals have been investigated with optical methods under different pressures and temperatures. The particle sizes measured during gas hydrate nucleation ranged from 2 to 80 imi [1334,1335]. The nucleation process is nondeterministic, because of a probabilistic element within the nucleation mechanism [1393]. 

To assess homogeneity, the distribution of chemical constituents in a matrix is at the core of the investigation. This distribution can range from a random temporal and spatial occurrence at atomic or molecular levels over well defined patterns in crystalline structures to clusters of a chemical of microscopic to macroscopic scale. Although many physical and optical methods as well as analytical chemistry methods are used to visualize and quantify such spatial distributions, the determination of chemical homogeneity in a CRM must be treated as part of the uncertainty budget affecting analytical chemistry measurements. 

Three types of methods are used to study solvation in molecular solvents. These are primarily the methods commonly used in studying the structures of molecules. However, optical spectroscopy (IR and Raman) yields results that are difficult to interpret from the point of view of solvation and are thus not often used to measure solvation numbers. NMR is more successful, as the chemical shifts are chiefly affected by solvation. Measurement of solvation-dependent kinetic quantities is often used (<electrolytic mobility, diffusion coefficients, etc). These methods supply data on the region in the immediate vicinity of the ion, i.e. the primary solvation sphere, closely connected to the ion and moving together with it. By means of the third type of methods some static quantities entropy and compressibility as well as some non-thermodynamic quantities such as the dielectric constant) are measured. These methods also pertain to the secondary solvation-sphere, in which the solvent structure is affected by the presence of ions, but the... 

Capacitance or conductance measurement This method is applied where the working fluid acts as a capacitive or conductive element in a circuit (Jones et al., 1981). Use of fiber optics sensors has been developed recently (Moujaes and Dougall, 1987, 1990). These methods are used to measure film thickness in annular flow. Further discussion appears in Section 3.3.4.4. For other regimes, the use of the electrical impedience imaging method has also been introduced (Lin et al., 1991). 

Raman measurements of skin carotenoid levels could be used as an indirect, rapid optical method to assess fruit and vegetable consumption in large populations. 

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