Liquid Terminology

Vibrational transitions accompanying an electronic transition are referred to as vibronic transitions. These vibronic transitions, with their accompanying rotational or, strictly, rovibronic transitions, give rise to bands in the spectrum, and the set of bands associated with a single electronic transition is called an electronic band system. This terminology is usually adhered to in high-resolution electronic spectroscopy but, in low-resolution work, particularly in the liquid phase, vibrational structure may not be resolved and the whole band system is often referred to as an electronic band. 

Because of the diverse appHcatioas involving Hquid atomizers, a large vocabulary of terms has evolved ia the spray community. The American Society for Testing and Materials, ASTM Subcommittee E29.04 on Liquid Particle Characterization, has attempted to standardize the terminology relating to atomizing devices (1). The definitions adopted by ASTM are used herein. 

ASTM E1620-96, Terminology Relating to Liquid Particles and Atomization, ASTM, Philadelphia, Pa., 1996. 

For fully developed incompressible cocurrent upflow of gases and liquids in vertical pipes, a variety of flow pattern terminologies and descriptions have appeared in the hterature some of these have been summarized and compared by Govier, Radford, and Dunn Can. J. Chem. Eng., 35, 58-70 [1957]). One reasonable classification of patterns is illustrated in Fig. 6-28. 

A number of types of bituminous material exist and terminology is still somewhat confusing. The term bitumens in its widest sense includes liquid and solid hydrocarbons but its popular meaning is restricted to the solid and semisolid materials. The bitumens occur widely in nature and may be considered to be derived from petroleum either by evaporation of the lighter fraction under atmospheric conditions or by a deeper seated metamorphism. The purer native bitumens are generally known as asphaltites and include Gilsonite, extensively used for moulding, which occurs in Utah. 

Disposal of Drainage of Process Equipment Contents - When items of onsite process equipment are taken out of service, either individually during plant operation or for general turnaround, means of draining and safe disposal of the residual liquid hydrocarbon contents must be provided. The following are important considerations and terminology in the design ... 

Throughout this bocdt, several mass-exchange operations will be considered simultaneously. It is therefore necessary to use a unified terminology such that y is always the composition in die rich phase and x is the composition in the lean phase. The reader is cautioned here that tiiis terminology may be different ftom other literature, in which y is used for gas-phase composition and x is used for liquid-phase composition. 

Therefore, one might ask what is meant by the terms hquid and gas. We all know what is the characteristic of a liquid. It has a free surface. However, as soon as we compress the hquid, there is no free surface and the distinction between a gas and liquid is lost. The most logical terminology would be to reserve the terms hquid and vapor for the two coexisting phases and call all other states fluid. A more common terminology is to call the fluid a hquid if its density exceeds the critical density and a gas if its density is lower. Generally speaking, in this chapter we will use the term fluid to describe both the gas and liquid phases and not make any distinction. 

Because the reboiler is usually used in conjunction with distillation columns, the terminology and symbols used here will relate to that application. Assume a column with an overhead total condenser and a bottoms reboiler (see Figures 10-96D and 10-96E). Assuming all liquid feed, the heat balance is ... 

Increase in mass-transfer rate per unit area. As stated above, agitated gas-liquid contactors are used, in general, when it is necessary to deal with sparingly soluble gases. According to the terminology of the film theory, absorption is then controlled by the liquid resistance, and agitation of the liquid phase could increase the mass-transfer rate per unit area. As will be... 

In the previous sections, we have seen how computer simulations have contributed to our understanding of the microscopic structure of liquid crystals. By applying periodic boundary conditions preferably at constant pressure, a bulk fluid can be simulated free from any surface interactions. However, the surface properties of liquid crystals are significant in technological applications such as electro-optic displays. Liquid crystals also show a number of interesting features at surfaces which are not seen in the bulk phase and are of fundamental interest. In this final section, we describe recent simulations designed to study the interfacial properties of liquid crystals at various types of interface. First, however, it is appropriate to introduce some necessary terminology. 

The terminology of L-B films originates from the names of two scientists who invented the technique of film preparation, which transfers the monolayer or multilayers from the water-air interface onto a solid substrate. The key of the L-B technique is to use the amphiphih molecule insoluble in water, with one end hydrophilic and the other hydrophobic. When a drop of a dilute solution containing the amphiphilic molecules is spread on the water-air interface, the hydrophilic end of the amphiphile is preferentially immersed in the water and the hydrophobic end remains in the air. After the evaporation of solvent, the solution leaves a monolayer of amphiphilic molecules in the form of two-dimensional gas due to relatively large spacing between the molecules (see Fig. 15 (a)). At this stage, a barrier moves and compresses the molecules on the water-air interface, and as a result the intermolecular distance decreases and the surface pressure increases. As the compression from the barrier proceeds, two successive phase transitions of the monolayer can be observed. First a transition from the gas" to the liquid state. 

The system of distinctions and terminology of the thermodynamic and electric potentials introduced by Lange is still very useful and recommended for describing all electrified phases and interphases. Therefore these potentials can be assigned to metal/solution (M/s), as well as the liquid/liquid boundaries created at the interfaces of two immiscible electrolyte solutions water (w) and an organic solvent (s). 

Viscosity is a measure of a fluid s resistance to flow. The knowledge of viscosity is needed for proper design of required temperatures for storage, pumping, or injection of hazardous fluids. Define the viscosity terminologies, and provide technical data of typical liquid pollutants for illustration. 

Some confusion exists in the terminology regarding liquid helium (LHe) containers. In the following, we shall call dewars the storage and the transport containers, and cryostats the cryogen containers used in experiments. Because of their large capacity (typically... 

Tomonaga-Luttinger liquid state [14-16], unconventional superconductivity [17], etc. These molecular conductors once used to be called organic metals, but nowadays this terminology has become obsolete in order to avoid possible confusion with organometallies. ... 

These are sometimes referred to as oils and fats. The only difference between the two is that materials are normally referred to as fats if they are solids at room temperatures and oils if they are liquids. The terminology is not always consistent as the material from coconut is normally referred to as coconut oil when in fact it is a hard fat. Most animal fats are solid at room temperature while most vegetable oils are liquid at room temperature. However, there are animal fats that are liquid at ambient temperatures and vegetable fats that are solid. 

The author was supported by the Ferroelectric Liquid Crystal Materials Research Center (National Science Foundation MRSEC award No. DMR-9809555) during the writing of this chapter. The author thanks Professors Tom Lubensky, Leo Radzihovsky, and Joseph Gal for helpful discussions around the issue of terminology for reflection symmetry breaking, and especially Professor Noel Clark for his help on this and many other banana-phase issues. The author also thanks Dr. Renfan Shao for the photomicrographs shown in Figures 8.32 and 8.33. 

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