Critical densities

At moderate densities. Equation (3-lOb) provides a very good approximation. This approximation should be used only for densities less than (about) one half the critical density. As a rough rule, the virial equation truncated after the second term is valid for the present range... 

For simple fluids Nq is estimated to be about 0.01, and Kostrowicka Wyczalkowska et aJ [29] have vised this to apply crossover theory to the van der Waals equation with interesting resnlts. The critical temperature is reduced by 11% and the coexistence curve is of course flattened to a cvibic. The critical density is almost unchanged (by 2%), bnt the critical pressure p is reduced greatly by 38%. These changes redvice the critical... 

The critical volume, V, is the volume of 1 mol at the critical temperature and the critical pressure. It can be computed from the critical density, p, as follows ... 

Transverse electromagnetic waves propagate in plasmas if their frequency is greater than the plasma frequency. For a given angular frequency, CO, there is a critical density, above which waves do not penetrate a plasma. The propagation of electromagnetic waves in plasmas has many uses, especially as a probe of plasma conditions. 

This expression, which has an average error of 2% or less, is vaUd up to the critical density. It also allows a corrective factor to be added to the critical pressure and temperature so that hydrogen and helium behavior can be accurately predicted (3,21). 

The regression constants A, B, and D are determined from the nonlinear regression of available data, while C is usually taken as the critical temperature. The hquid density decreases approximately linearly from the triple point to the normal boiling point and then nonhnearly to the critical density (the reciprocal of the critical volume). A few compounds such as water cannot be fit with this equation over the entire range of temperature. Liquid density data to be regressed should be at atmospheric pressure up to the normal boihng point, above which saturated liquid data should be used. Constants for 1500 compounds are given in the DIPPR compilation. 

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