Gas-liquid contactor

Only a relatively small recirculation stream of an aqueous silver nitrate. solution is required. Other e. amples are the removal of acid gases such as CO . H S. CO. SO and NO. from flue gas, biogas and natural gas and the removal of NH3. 

---

TABLE 14 1 Directory to Key Data for Absorption and GaS Liquid Contactor Design... 

Mass Transfer Mass transfer in plate and packed gas-liquid contactors has been covered earHer in this subsection. Attention nere will be limited to deep-bed contactors (bubble columns and agitated vessels). Theory underlying mass transfer between phases is discussed in Sec. 5 of this handbook. 

Fiber-Bed Scrubbers Fibrous-bed structures are sometimes used as gas-liquid contactors, with cocnrrent flow of the gas and hqnid streams. In such contactors, both scrubbing (particle deposition on droplets) and filtration (particle deposition on fibers) may take place. If only mists are to be collected, small fibers may be used, but if solid particles are present, the use of fiber beds is limited by the tendency of the beds to phig. For dnst-cohectiou service, the fiber bed must be composed of coarse fibers and have a high void fraction, so as to minimize the tendency to plug. The fiber bed may be made from metal or... 

Gas-liquid contactors may be operated either by way of gas bubble dispersion into liquid or droplet dispersion in gas phase, while thin film reactors, i.e. packed columns and trickle beds are not suitable for solid formation due... 

Westerterp et al. (W5) measured interfacial areas in mechanically agitated gas-liquid contactors. The existence of two regions was demonstrated At agitation rates below a certain minimum value, interfacial areas are unaffected by agitation and depend only on nominal gas velocity and the type of gas distributor, whereas at higher agitation rates, the interfacial areas are... 

Gal-Or and Resnick (Gl) have developed a simplified theoretical model for the calculation of mass-transfer rates for a sparingly soluble gas in an agtitated gas-liquid contactor. The model is based on the average gas residencetime, and its use requires, among other things, knowledge of bubble diameter. In a related study (G2) a photographic technique for the determination of bubble flow patterns and of the relative velocity between bubbles and liquid is described. 

Foust et al. (F4) measured gas holdup in mechanically stirred gas-liquid contactors of various diameters (from 1 to 8 ft) and various liquid contents (from 5 to 2250 gal). The nominal gas velocity varied from 1 to 5 ft/min and the power input from 0.01 to 6.5 hp. The contact time (sec/ft) could be correlated by the following expression ... 

Kramers et al. (K21) measured gas residence-time distribution in a mechanically agitated gas-liquid contactor of 0.6-m diameter for various gas velocities and agitator speeds. In the region where agitation has an effect on the gas-liquid interfacial area (cf. the study by Westerterp et al. (W5), Section V,D,1), the residence-time distribution was found to resemble closely that of a perfect mixer. 

Efficient contact is produced between the phases in agitated gas-liquid contactors and, therefore, this type of equipment can also be useful for those absorption and stripping operations for which conventional plate or packed towers may not be suited. It may also be useful where the operation involves the contact of three phases—say, gas, liquid, and suspended solids. The latter application could be represented by the low-pressure polymerization of ethylene with solid catalysts (F5). 

Increase in mass-transfer rate per unit area. As stated above, agitated gas-liquid contactors are used, in general, when it is necessary to deal with sparingly soluble gases. According to the terminology of the film theory, absorption is then controlled by the liquid resistance, and agitation of the liquid phase could increase the mass-transfer rate per unit area. As will be... 

Gal-Or (G4) has recently reported bubble-size distribution data in air-water dispersions. The equipment used to evaluate the bubble-size distribution is a new type of multistage gas-liquid contactor without pressure drop in each stage, in which the gas is drawn in from the bottom of the vessel. Typical bubble-size—cumulative-volume data are given in Fig. 2.f The data show that for 99% of the bubbles, 0.1 < 1.4 mm. The surface mean radius a32... 

Fig. 4. Sectional view of one stage of a new type of gas-liquid contactor without pressure drop. (1) Vaned-disk impeller (2) stator (3) contacting tank (4) impeller shaft (5) gas inlet pipe (gas is self-induced through this pipe into the dispersion) (6) gas outlet thermometer (7) thermometer pocket (8) drainage tank (9) lid [after Gal-Or (G4)].

Unfortunately, relatively little information has been made available for industrial gas-liquid contactors. Further data from industry could permit significant tests of the reliability of the present correlations and their applicability to scale-up. Steel and Maxon (SI 1) reported on the power requirements during novobiacin fermentation in 20- and 250-liter pilot-plant vessels and in 12,000- and 24,000-gal vessels. The comparative data are difficult to evaluate because of changes that occurred in viscosity and gas retention during the course of the fermentation. In addition, geometric similarity did not prevail... 

In a gas-liquid contactor, a pure gas is absorbed in a solvent and the Penetration Theory provides a reasonable model by which to describe the transfer mechanism. As fresh solvent is exposed to the gas, the transfer rate is initially limited by the rate at which the gas molecules can reach the surface. If at 293 K and a pressure of 1 bar the maximum possible rate of transfer of gas is 50 m3/m2s, express this as an equivalent resistance, when the gas solubility is 0.04 kmol/m3. 

Since many different gas/liquid contactors were used, the experimental conditions differed for each device and the reader is referred to the listing in the original reference [5], The liquid flows range from 10 to 1042 ml h and the gas volume flows from 180 to 25 020 ml h. The corresponding residence times were 0.01-19.58 s. The ratio of carbon dioxide to sodium hydroxide was fixed at 0.4. 

GL 22] [R 3] [R 9] [R 10] [P 23] The mass transfer efficiency of different gas/liquid contactors as a function of residence time was compared qualitatively (Figure 5.29), including an interdigital micro mixer, a caterpillar mini mixer, a mixing tee and three micro bubble columns using micro channels of varying diameter [5]. 

The most widely used element-selective electrochemical detector is the Hall electrolytic conductivity detector (HECD) [98,116,206]. This is an improved version of an earlier design by Coulson [207,208]. In both detectors the reaction products are swept from the furnace into a gas-liquid contactor trtiere they are mixed with an appropriate solvent. The liquid phase is separated from insoluble gases in a gas-liquid separator and then passed through a conductivity cell. The Coulson detector employed a... 

Gas lasers, 14 681-696 carbon dioxide, 14 693-696 excimer lasers, 14 691-693 helium-neon, 14 681-683 ion lasers, 14 683-688 molecular nitrogen, 14 688-691 Gas lift electrolyte circulation, 9 621 Gas-liquid base stocks, 15 217 Gas-liquid chromatography (glc), 6 374 analysis of sugars via, 23 476 silylation for, 22 692, 697 Gas-liquid contactor, reciprocating jet,... 

Gas-liquid contactors, 16 700-701 Gas-liquid equilibria, simulation, 1 30 Gas/liquid extractions, ionic liquids in, 26 876... 

Reciprocating internal combustion engines (ICEs), 73 854, 855-856 Reciprocating jet gas-liquid contactor, 75 709-710... 

A large tank (860 liters) is used as a gas-liquid contactor. Gas bubbles up through the vessel and out the top, liquid flows in at one part and out the other at 5 liters/s. To get an idea of the flow pattern of liquid in this tank a pulse of tracer (M = 150 gm) is injected at the liquid inlet and measured at the outlet, as shown in Fig. E112a. 

From the measured pulse tracer response curves (see figure), find the fraction of gas, of flowing liquid, and of stagnant liquid in the gas-liquid contactor shown in Fig. E12.1. 

A variety of gas-liquid contacting equipment with mechanical moving elements (e.g., stirred (agitated) tanks with gas sparging) are discussed in Chapters 7 and 12, including rotating-disk gas-liquid contactors and others. 

Miscellaneous types, for example, rotating-disk, gas-liquid contactors, and so on. 

Unsteady-State Mass Balance Method One widely used technique for determining Kj a in bubbling gas-liquid contactors is the physical absorption of oxygen or COj into water or aqueous solutions, or the desorption of such a gas from a solution into a sparging inert gas such as air or nitrogen. The time-dependent concentration of dissolved gas is followed by using a sensor (e.g., for O2 or CO2) with a sufficiently fast response to changes in concentration. 

Ozone is an unstable gas which has to be produced at the point of use. A wide variety of gas-liquid contactors has been used to transfer ozone into water where chemical reactions occur simultaneously. 

Estimate the volumetric mass-transfer coefficient kLa for the gas-liquid contactor described in Example. 4 by using the correlation for kLa in this section. 

---