Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Ionic liquids substitution

Li JL, Feng DP, Liang YM et al (2010) Synthesis and tribological behavior of ionic liquid substituted lluoroalkoxycyclophosphazene derivatives in steel-steel contacts. Ind Lubr Tribol... [Pg.234]

Ionic liquids (substituted imidazolium salts) were utilized in the electrochemical synthesis of PEEKTT films with specific structural or morphological features randomly oriented nanofibers and particles in submicrometersized domains with EMI-bis(pentafluoroethylsulfonyl)imide, the structure of a solid polymer actuator with PEDOT layer on the surface of a solid nitrile rubber-BMI/BH-mixture, single strand nanowires with BMI-hexafluorophosphate, and codeposited polypyrrole/PEEXDT in BMI-BTI. ... [Pg.338]

The alkylation process possesses the advantages that (a) a wide range of cheap haloalkanes are available, and (b) the substitution reactions generally occur smoothly at reasonable temperatures. Furthermore, the halide salts formed can easily be converted into salts with other anions. Although this section will concentrate on the reactions between simple haloalkanes and the amine, more complex side chains may be added, as discussed later in this chapter. The quaternization of amines and phosphines with haloalkanes has been loiown for many years, but the development of ionic liquids has resulted in several recent developments in the experimental techniques used for the reaction. In general, the reaction may be carried out with chloroalkanes, bromoalkanes, and iodoalkanes, with the reaction conditions required becoming steadily more gentle in the order Cl Br I, as expected for nucleophilic substitution reactions. Fluoride salts cannot be formed in this manner. [Pg.9]

The viscosities of non-haloaluminate ionic liquids are also affected by the identity of the organic cation. For ionic liquids with the same anion, the trend is that larger allcyl substituents on the imidazolium cation give rise to more viscous fluids. For instance, the non-haloaluminate ionic liquids composed of substituted imidazolium cations and the bis-trifyl imide anion exhibit increasing viscosity from [EMIM], [EEIM], [EMM(5)IM], [BEIM], [BMIM], [PMMIM], to [EMMIM] (Table 3.2-1). Were the size of the cations the sole criteria, the [BEIM] and [BMIM] cations from this series would appear to be transposed and the [EMMIM] would be expected much earlier in the series. Given the limited data set, potential problems with impurities, and experimental differences between laboratories, we are unable to propose an explanation for the observed disparities. [Pg.64]

The size of the cation in the chloroaluminate ionic liquids also appears to have an impact on the viscosity. For ionic liquids with the same anion(s) and compositions, the trend is for greater viscosity with larger cation size (Table 3.2-2). An additional contributing factor to the effect of the cation on viscosity is the asymmetry of the alkyl substitution. Highly asymmetric substitution has been identified as important for obtaining low viscosities [17]. [Pg.64]

Ionic liquids are similar to dipolar, aprotic solvents and short-chain alcohols in their solvent characteristics. These vary with anion (from very ionic Cl to more covalent [BETI] ). IFs become more lipophilic with increasing alkyl substitution, resulting in increasing solubility of hydrocarbons and non-polar organics. [Pg.79]

The description of electronic distribution and molecular structure requires quantum mechanics, for which there is no substitute. Solution of the time-independent Schrodinger equation, Hip = Eip, is a prerequisite for the description of the electronic distribution within a molecule or ion. In modern computational chemistry, there are numerous approaches that lend themselves to a reasonable description of ionic liquids. An outline of these approaches is given in Scheme 4.2-1 [1] ... [Pg.152]

These reactions occur with similar rates to those carried out in dipolar aprotic solvents such as DMF or DMSO. An advantage of using the room-temperature ionic liquid for this reaction is that the lower reaction temperatures result in higher selec-tivities for substitution on the oxygen or nitrogen atoms. The by-product (sodium or potassium halide) of the reaction can be extracted with water and the ionic liquid recycled. [Pg.185]

In addition to the applications reported in detail above, a number of other transition metal-catalyzed reactions in ionic liquids have been carried out with some success in recent years, illustrating the broad versatility of the methodology. Butadiene telomerization [34], olefin metathesis [110], carbonylation [111], allylic alkylation [112] and substitution [113], and Trost-Tsuji-coupling [114] are other examples of high value for synthetic chemists. [Pg.252]

NEW Green chemistry promotes environmentally sound chemistry. Passages in the text created in consultation with Michael Cann and new end-of-chapter exercises are accompanied by a (IT). Topics include ionic liquids (Chapter 5), supercritical C02 (Chapter 8), yttrium in paint (Chapter 12), chelates as a substitute for chlorine bleach (Chapter 16), and transesterification (Chapter 19). [Pg.17]

Microwave-Assisted Synthesis of a Substituted Pyran Using Ionic Liquid Tagging... [Pg.118]

All these cations are bulky and asymmetric. In addition, their alkyl groups make it possible to modify them almost endlessly. The length of the alkyl chains can be varied, they can be straight or branched, and functional groups such as —OH can be substituted. This feature makes it possible to vary the characteristics of ionic liquids to suit a particular application. [Pg.1111]

Ionic LCs are interesting systems because they combine the properties of LCs with those of ionic liquids. Although alkali metal soaps were among the first thermotropic LCs to be systematically studied, ionic liquid crystalline derivatives have been reported less frequently than those based on neutral molecular and macromolecular species [39]. When the halide of [AuX(CNR)] complexes is substituted by a second isocyanide, ionic complexes [Au(CNR)2][Y] [R = C6H40C H2 + i (27a),... [Pg.379]

Some theoretical aspects of thiophene reactivity and structure have also been discussed, for example the kinetics of proton transfer from 2,3-dihydrobenzo[6]thiophenc-2-onc <06JOC8203>, the configuration of imines derived from thiophenecarbaldehydes <06JOC7165>, and the relative stability of benzo[c]thiophene <06T12204>. The kinetics of nucleophilic aromatic substitution of some 2-substituted-5-nitrothiophenes in room temperature ionic liquids have also been investigated <06JOC5144>. [Pg.121]

The microwave-assisted thionation of amides has been studied by Ley and coworkers using a polymer-supported thionating reagent [115]. This polymer-supported amino thiophosphate serves as a convenient substitute for its homogeneous analogue in the microwave-induced rapid conversion of amides to thioamides. Under microwave conditions, the reaction is complete within 15 min, as opposed to 30 h by conventional reflux in toluene (Scheme 7.95). The reaction has been studied for a range of secondary and tertiary amides and GC-MS monitoring showed that it proceeded almost quantitatively. More importantly, this work was the first incidence of the use of the ionic liquid l-ethyl-3-methylimidazolium hexafluorophosphate... [Pg.362]

The reaction of 3,4-diacyl-l,2,5-oxadiazole 2-oxides (furoxans) with activated nitriles in ionic liquids and in ethanol unexpectedly resulted in 3-acyl-4-acylamino-l,2,5-°xadiazoles (furazans) <2003MC230>. 3-Formyl-4-phenyl-l,2,5-oxadiazole Ar-oxide 105 is a good precursor for the synthesis of functional substituted furoxans (Scheme 28) <1999JME1941, 2000MOL520, 2000JFA2995>. [Pg.340]


See other pages where Ionic liquids substitution is mentioned: [Pg.57]    [Pg.198]    [Pg.57]    [Pg.198]    [Pg.25]    [Pg.15]    [Pg.42]    [Pg.44]    [Pg.50]    [Pg.51]    [Pg.52]    [Pg.53]    [Pg.54]    [Pg.66]    [Pg.96]    [Pg.107]    [Pg.132]    [Pg.135]    [Pg.224]    [Pg.261]    [Pg.956]    [Pg.218]    [Pg.366]    [Pg.103]    [Pg.308]    [Pg.112]    [Pg.96]    [Pg.263]    [Pg.33]    [Pg.161]    [Pg.165]    [Pg.225]    [Pg.362]    [Pg.357]    [Pg.358]    [Pg.212]   
See also in sourсe #XX -- [ Pg.167 ]




SEARCH



Ionic Liquid Aromatic substitution

Ionic liquids highly substituted pyridine synthesi

Ionic liquids nucleophilic substitution

Ionic liquids nucleophilic substitution with

Liquid substitution

© 2024 chempedia.info