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Substitution, aromatic, nucleophilic

A more detailed classification of chemical reactions will give specifications on the mechanism of a reaction electrophilic aromatic substitution, nucleophilic aliphatic substitution, etc. Details on this mechanism can be included to various degrees thus, nucleophilic aliphatic substitutions can further be classified into Sf l and reactions. However, as reaction conditions such as a change in solvent can shift a mechanism from one type to another, such details are of interest in the discussion of reaction mechanism but less so in reaction classification. [Pg.173]

The general approaches for the synthesis of poly(arylene ether)s include electrophilic aromatic substitution, nucleophilic aromatic substitution, and metal-catalyzed coupling reactions. Poly(arylene ether sulfone)s and poly(arylene ether ketone)s have quite similar structures and properties, and the synthesis approaches are quite similar in many respects. However, most of the poly(arylene ether sul-fone)s are amorphous while some of the poly(arylene ether)s are semicrystalline, which requires different reaction conditions and approaches to the synthesis of these two polymer families in many cases. In the following sections, the methods for the synthesis of these two families will be reviewed. [Pg.329]

Substituted imidazole 1-oxides 228 are predicted to be activated toward electrophilic aromatic substitution, nucleophilic aromatic substitution, and metallation as described in Section 1. Nevertheless little information about the reactivity of imidazole 1-oxides in these processes exists. The reason for this lack may be the high polarity of the imidazole 1-oxides, which makes it difficult to find suitable reaction solvents. Another obstacle is that no method for complete drying of imidazole 1-oxides exists and dry starting material is instrumental for successful metallation. Well documented and useful is the reaction of imidazole 1-oxide 228 with alkylation and acylation reagents, their function as 1,3-dipoles in cycloadditions, and their palladium-catalyzed direct arylation. [Pg.47]

Background Needed for this Chapter References to Clayden, Organic Chemistry Electrophilic aromatic substitution chapter 22. (Electrophilic Aromatic Substitution) Nucleophilic aromatic substitution chapter 23 (Electrophilic Alkenes). [Pg.7]

Antiaromaticity. 194 Antibonding orbitals. 15 Anti-elimination. 128ff Arenes. electrophilic substitution. 205/T niirosation, 206 Aromatic character. 193 Aromaticity. 193 Aromatic reactions. 199 Aromatic substitutions, nucleophilic. 2 Sff Aromafization. 202... [Pg.464]

AROMATIC SUBSTITUTION, NUCLEOPHILIC AND ORGANOMETALLIC TABLE 13.1. Continued)... [Pg.866]


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1.2.4- Triazine aromatic nucleophilic substitution

Active hydrogen compounds aromatic nucleophilic substitution

Addition elimination mechanism of nucleophilic aromatic substitution

Addition reactions nucleophilic aromatic substitution

Addition-elimination mechanism for nucleophilic aromatic substitution

Aliphatic and Aromatic Nucleophilic Substitution

Alkoxides aromatic nucleophilic substitution

Amides nucleophilic aromatic substitution

Amines aromatic nucleophilic substitution

And nucleophilic aromatic substitution

Aromatic Polyethers by Nucleophilic Substitution

Aromatic Substitution, Nucleophilic and Organometallic

Aromatic compounds, nucleophilic substitution

Aromatic compounds, substituted nucleophilic reactions

Aromatic nucleophiles

Aromatic nucleophilic substitution (SNAr

Aromatic nucleophilic substitution synthesis

Aromatic substitution nucleophilic, 11-14, Table

Aryl azides nucleophilic aromatic substitution

Aryl ethers nucleophilic aromatic substitution

Aryl halides and nucleophilic aromatic substitution

Aryl halides nucleophilic aromatic substitution

Arylamines aromatic nucleophilic substitution

Arylboronic nucleophilic aromatic substitutions

Asymmetric nucleophilic aromatic substitution

Asymmetric nucleophilic aromatic substitution chiral catalyzed

Asymmetric nucleophilic aromatic substitution chiral nucleophiles

B Nucleophilic aromatic substitution

Benzene Nucleophilic aromatic substitution reactions

Benzene nucleophilic aromatic substitution

Benzene, tris aromatic nucleophilic substitution

Benzothiazoles aromatic nucleophilic substitution

Bimolecular displacement mechanism for nucleophilic aromatic substitution

Bis-annulation aromatic nucleophilic substitution

Carbanions nucleophilic aromatic substitution

Carbon nucleophiles aromatic nucleophilic substitution

Carbon nucleophilic aromatic substitution via

Catalyzed Nucleophilic Aromatic Substitution

Chlorobenzene nucleophilic aromatic substitution

Conjugate addition and nucleophilic aromatic substitution

Copper compounds Cu in aromatic nucleophilic substitution

Criteria for Nucleophilic Aromatic Substitution

Cyanides aromatic nucleophilic substitution

Cyclohexadienyl anion, intermediate nucleophilic aromatic substitution

Delocalization in nucleophilic aromatic substitution

Electron Pushing for Nucleophilic Aromatic Substitution

Electrophilic and Nucleophilic Aromatic Substitution

Electrophilic and nucleophilic substitution in aromatic

Electrophilic arenes nucleophilic aromatic substitution

Electrophilic aromatic substitution reactions arene nucleophiles

Elimination addition reactions nucleophilic aromatic substitution with

Fluoroarenes aromatic nucleophilic substitution

Formylation aromatic nucleophilic substitution and hydrolysis

Grignard reagents aromatic nucleophilic substitution

Halides aromatic nucleophilic substitution

Heterocyclic compounds nucleophilic aromatic substitution

Hydrides aromatic nucleophilic substitution

INDEX nucleophilic aromatic substitution

Imine formation nucleophilic aromatic substitution

In nucleophilic aromatic substitution

Indazolinones by Ugi-4CR with N-deprotection and Aromatic Nucleophilic Substitution

Intramolecular Reactions Nucleophilic Aromatic Substitution

Intramolecular nucleophilic aromatic substitution

Intramolecular nucleophilic aromatic substitution iodine

Ipso nucleophilic aromatic substitution

Isotopes nucleophilic aromatic substitution

Kinetic studies nucleophilic aromatic substitution

Kinetic studies of nucleophilic aromatic substitution

Leaving groups in nucleophilic aromatic substitution

Leaving groups, reactivity in nucleophilic aromatic substitution

Mechanism nucleophilic aromatic substitution

Mechanism of aromatic nucleophilic substitution

Multicomponent Synthesis of Annelated Thiopyranones by Coupling-Addition-Nucleophilic Aromatic Substitution Sequence

NASH (nucleophilic aromatic substitution

Nitro compounds aromatic, nucleophilic substitution

Nitrogen nucleophiles aromatic nucleophilic substitution

Nucleophile aromatic substitution

Nucleophile aromatic substitution

Nucleophile olefin combination, aromatic substitution reaction

Nucleophilic Aromatic Substitution An Addition-Elimination Reaction

Nucleophilic Aromatic Substitution An Update Overview

Nucleophilic Aromatic Substitution Diazonium Ions

Nucleophilic Aromatic Substitution by the Addition-Elimination Mechanism

Nucleophilic Aromatic Substitution. Benzyne

Nucleophilic Aromatic and Vinylic Substitution

Nucleophilic Substitution of Aromatic Chlorides

Nucleophilic aromatic

Nucleophilic aromatic oxidative substitution

Nucleophilic aromatic substitution (the SNAr mechanism)

Nucleophilic aromatic substitution 1,3-azoles

Nucleophilic aromatic substitution 2- nitrothiophene

Nucleophilic aromatic substitution 2-nitrofurans

Nucleophilic aromatic substitution 3- nitroaniline

Nucleophilic aromatic substitution 6-nitroquinoline

Nucleophilic aromatic substitution Meisenheimer adducts

Nucleophilic aromatic substitution Meisenheimer complexes

Nucleophilic aromatic substitution SnAt mechanism

Nucleophilic aromatic substitution activating groups, effects

Nucleophilic aromatic substitution addition-elimination mechanism

Nucleophilic aromatic substitution adducts

Nucleophilic aromatic substitution amine nucleophiles

Nucleophilic aromatic substitution amines, base catalysis

Nucleophilic aromatic substitution aniline derivatives

Nucleophilic aromatic substitution approach

Nucleophilic aromatic substitution aryl-copper complexes

Nucleophilic aromatic substitution benzyne mechanism

Nucleophilic aromatic substitution bimolecular displacement

Nucleophilic aromatic substitution by addition-elimination

Nucleophilic aromatic substitution copper

Nucleophilic aromatic substitution copper-catalyzed

Nucleophilic aromatic substitution coupling

Nucleophilic aromatic substitution diasteroselectivity

Nucleophilic aromatic substitution diphenylamines

Nucleophilic aromatic substitution elimination process

Nucleophilic aromatic substitution elimination-addition

Nucleophilic aromatic substitution enantioselectivity

Nucleophilic aromatic substitution examples

Nucleophilic aromatic substitution fluoro derivative

Nucleophilic aromatic substitution for

Nucleophilic aromatic substitution for hydrogen

Nucleophilic aromatic substitution general discussion

Nucleophilic aromatic substitution halogen exchange reactions

Nucleophilic aromatic substitution heterocyclic systems

Nucleophilic aromatic substitution homolytic

Nucleophilic aromatic substitution hydrogen

Nucleophilic aromatic substitution intermediate complexes

Nucleophilic aromatic substitution intramolecular rearrangements

Nucleophilic aromatic substitution isoquinoline

Nucleophilic aromatic substitution kinetic features

Nucleophilic aromatic substitution leaving groups

Nucleophilic aromatic substitution limitations

Nucleophilic aromatic substitution metal-catalyzed

Nucleophilic aromatic substitution nitro-group activated

Nucleophilic aromatic substitution nitro-group displacement

Nucleophilic aromatic substitution nucleophiles

Nucleophilic aromatic substitution nucleophiles

Nucleophilic aromatic substitution of hydrogen

Nucleophilic aromatic substitution of hydrogen NASH)

Nucleophilic aromatic substitution of pyridines

Nucleophilic aromatic substitution organic reaction mechanisms

Nucleophilic aromatic substitution orientation

Nucleophilic aromatic substitution ortho-selectivity

Nucleophilic aromatic substitution palladium

Nucleophilic aromatic substitution phase transfer catalysis

Nucleophilic aromatic substitution photochemical

Nucleophilic aromatic substitution polymerization

Nucleophilic aromatic substitution quinoline

Nucleophilic aromatic substitution radical

Nucleophilic aromatic substitution radical chain mechanism

Nucleophilic aromatic substitution reaction characteristics

Nucleophilic aromatic substitution reactions diazonium ions

Nucleophilic aromatic substitution reactivity

Nucleophilic aromatic substitution rearrangements

Nucleophilic aromatic substitution reviews

Nucleophilic aromatic substitution solid-state

Nucleophilic aromatic substitution solvent effects

Nucleophilic aromatic substitution substituent effects

Nucleophilic aromatic substitution synthetic applications

Nucleophilic aromatic substitution systems

Nucleophilic aromatic substitution water

Nucleophilic aromatic substitution, quinoxaline

Nucleophilic substitution aromaticity

Nucleophilic substitution aromatics

Nucleophilic substitution reaction aromatic compounds

Nucleophilic substitution, aromatic activated aryl halides

Nucleophilic substitution, aromatic anionic intermediates

Nucleophilic substitution, aromatic aryne intermediates

Nucleophilic substitution, aromatic deuterium exchange

Nucleophilic substitution, aromatic diazonium salts

Nucleophilic substitution, aromatic nitrobenzene

Nucleophilic substitution, aromatic pyridine

Nucleophilic substitution, aromatic rates

Nucleophilic substitution—continued mechanisms for aromatic compounds

Organolithium compounds aromatic nucleophilic substitution

Organolithium reagents aromatic nucleophilic substitution

Organometallic compounds aromatic nucleophilic substitution

Orientation in nucleophilic aromatic substitution

Oxygen nucleophiles aromatic nucleophilic substitution

P-Toluenesulfonic acid nucleophilic aromatic substitution

Peterson reagent aromatic nucleophilic substitution

Phenols and Aryl Halides Nucleophilic Aromatic Substitution

Phenols nucleophilic aromatic substitution

Phosphorus nucleophiles aromatic nucleophilic substitution

Photochemical Nucleophile-Olefin Combination, Aromatic Substitution

Photochemical reactions aromatic nucleophilic substitution

Photoinduced radical reactions nucleophilic aromatic substitution

Polyglymes aromatic nucleophilic substitution

Preparation of Phenols Nucleophilic Aromatic Substitution

Pyridazines, nucleophilic aromatic substitution

Pyridines derivatives, nucleophilic aromatic substitution

Quinolines, nucleophilic aromatic substitution

Quinone methides, generation water, nucleophilic aromatic substitution

Radical-nucleophilic aromatic substitution carbanions

Radical-nucleophilic aromatic substitution electron transfer

Radical-nucleophilic aromatic substitution experiments

Radical-nucleophilic aromatic substitution halides

Radical-nucleophilic aromatic substitution heterocyclic synthesis

Radical-nucleophilic aromatic substitution initiation step

Radical-nucleophilic aromatic substitution intermolecular

Radical-nucleophilic aromatic substitution intramolecular

Radical-nucleophilic aromatic substitution propagation steps

Reaction mechanisms nucleophilic aromatic substitution

Reactions of Arenes Electrophilic and Nucleophilic Aromatic Substitution

Reactivity in nucleophilic aromatic substitution

Regioselectivity nucleophilic aromatic substitution

Related Nucleophilic Aromatic Substitution Reactions

Related Nucleophilic Aromatic Substitutions

Resonance nucleophilic aromatic substitution

SNAr reaction nucleophilic aromatic substitution

Selenium nucleophiles aromatic nucleophilic substitution

Solvent effects in aromatic nucleophilic substitution

Substituent effects of nucleophilic aromatic substitution

Substituent effects on nucleophilic aromatic substitution

Substitution reactions aromatic nucleophilic (addition-elimination

Substitution reactions nucleophilic aromatic

Substitution, allylic nucleophilic aromatic

Sulfites aromatic nucleophilic substitution

Sulfur nucleophiles aromatic nucleophilic substitution

Synthesis continued) nucleophilic aromatic substitution

Tellurium nucleophiles aromatic nucleophilic substitution

The Addition-Elimination Mechanism of Nucleophilic Aromatic Substitution

The Elimination-Addition Mechanism of Nucleophilic Aromatic Substitution Benzyne

Thio anions aromatic nucleophilic substitution

Thioalkoxides aromatic nucleophilic substitution

Thiocyanates aromatic nucleophilic substitution

Thioiminium salts aromatic nucleophilic substitution

Ugi-4CR and Nucleophilic Aromatic Substitution

Vicarious nucleophilic aromatic substitution

Vicarious nucleophilic substitutions , aromatic hydrogens

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