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Polymer-supported thionating reagent

The microwave-assisted thionation of amides has been studied by Ley and coworkers using a polymer-supported thionating reagent [115]. This polymer-supported amino thiophosphate serves as a convenient substitute for its homogeneous analogue in the microwave-induced rapid conversion of amides to thioamides. Under microwave conditions, the reaction is complete within 15 min, as opposed to 30 h by conventional reflux in toluene (Scheme 7.95). The reaction has been studied for a range of secondary and tertiary amides and GC-MS monitoring showed that it proceeded almost quantitatively. More importantly, this work was the first incidence of the use of the ionic liquid l-ethyl-3-methylimidazolium hexafluorophosphate... [Pg.362]

See other pages where Polymer-supported thionating reagent is mentioned: [Pg.58]    [Pg.42]    [Pg.174]    [Pg.354]    [Pg.253]    [Pg.160]    [Pg.58]    [Pg.42]    [Pg.174]    [Pg.354]    [Pg.253]    [Pg.160]    [Pg.98]    [Pg.600]   
See also in sourсe #XX -- [ Pg.771 ]



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Polymer reagents

Polymer-supported reagents

Supported reagents

Thionating reagents

Thionation

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