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Post-polymerization functionalization has also been applied to the synthesis of terpyridine-modified polymers [ 126]. In a recent approach, Schubert and colleagues employed this method to prepare poly(pentafluorostyrene) with terpyridines in the side chains [127]. First, poly(pentafluorostyrene) with a narrow polydispersity index of just 1.08 was synthesized by nitroxide-mediated polymerization. In a second step, this polymer was converted with amine-functionalized terpyridine under microwave heating, selectively substituting the para-fluorines. Addition of iron(II) sulfate to a solution of the terpyridine-functionalized polymer in a mixture of chloroform and methanol leads to gelation at a polymer concentration of 33 g In another work, Schubert and coworkers prepared metal-cross-Iinked polymer networks from linear and tri-arm PEG precursors, both functionalized with terpyridine at their OH-termini [128]. Quantitative functionalization of these precursors was achieved by conversion of the hydroxy-functionalized PEG derivatives with 4-chloro-2,2 6, 2"-terpyridine under basic conditions. However, quantitative cross-linking with iron(II) chloride was not observed in methanol solutions, neither at room temperature nor at elevated temperature, but only a small quantity of cross-linked material precipitated from the solution. This observation was attributed to a strong tendency of the tri-arm PEG to form intramolecular complexes, acting as a chain stopper rather than as a cross-linker. [Pg.14]

Campos et al. (2012) present a heuristic algorithm that can be applied for defining some independent routes for developing the evacuation plans. The basic idea is to use interactively an algorithm for finding the two independent paths in the network from the disaster area to each destination, with the least travel time, associating to each path an index of capacity/time that facilitates the evaluation of each route in comparison to the others. [Pg.63]

The TRC THERMODYNAMIC TABLES Database contains the evaluated data published in the TRC Thermodynamic Tables - Hydrocarbons and Non-Hydrocarbons. The contents of this database are updated quarterly in conjunction with the publication of the hard-copy supplements. The database is accessible on-line through TRCTHERMO module on the STN international network. From 1994, a version of this database developed using B-tree index files will be available for IBM PC or compatible computers on a yearly lease basis with a subscription to the hard copy of the TRC Thermodynamic Tables. Multiple copies will be available with a single hard-copy subscription. Its features include search for compound by name, formula or CASRN, with flexible name and formula searching capabilities. Data for a selected series of compounds can be retrieved and saved to external files for later analysis. [Pg.460]

In order to reflect these lead times, the concept of a timestamp is introduced. Timestamp is used in computer science documenting the system time when a certain event or transaction occurs e.g. for logging events (N.N. 2007). In the context of future inventory value planning, the time-stamp marks the period, when the first raw material has reached a certain stage in the value chain network included into a specific product. In the example illustrated in fig. 57, the raw material is processed in the same period to be converted into product 1. Therefore, all four value chain steps indexed from one to four occur in the same period and have the same time-stamp one. Conversion into product 2, however, requires additional time caused by production lead times, safety inventory and/or transportation time, that the steps indexed with five and six have a time stamp of two. The timestamp reflects that the inventory value of product 2 is not based on the raw material costs from the same period but based on the raw material costs from the previous period in order to reflect the lead time. Consequently, value chain indices and timestamps are defined for all steps and can cover multiple periods reflecting that raw materials in a global complex multi-stage value chain network can take several months, until they are sold as part of a finished product to the market. [Pg.152]

Several explosive salts including the acetylide, azide, borate, bromate, chlorate, chromate, iodate (and ammonium iodate double salt), nitrite, perchlorate (and ammonium perchlorate double salt), periodate, permanganate, picrate and trinitrobenzoate were prepared. The 3 latter salts and the acetylide, azide and bromate are impact-sensitive detonators [1], It appears probable that many of the explosively unstable compounds [2], formed in various ways from interaction of mercury or its compounds with ammonia or its salts, may have the common polymeric structure now recognised for Millon s base [3], This is a silica-like network of N+ and Hg in 4- and 2-coordination, respectively, with OH and water in the interstitial spaces. Individually indexed compounds are Poly(dimercuryimmonium acetylide)... [Pg.342]

Fig. 18. Dependence of the stress-optica] coefficient C on the refractive index of swollen polyacrylamide gel n (O) nonionized network, ( ) ionized network. Taken from [31]... Fig. 18. Dependence of the stress-optica] coefficient C on the refractive index of swollen polyacrylamide gel n (O) nonionized network, ( ) ionized network. Taken from [31]...
Research articles of interest to biochemists may appear in many types of research journals. Research libraries do not have the funds necessary to subscribe to every journal, nor do scientists have the time to survey every current journal copy for articles of interest. Two publications that help scientists to keep up with published articles are Chemical Titles (published every 2 weeks by the American Chemical Society) and the weekly Current Contents available in hard copy and computer disks (published by the Institute of Science Information). The Life Science edition of Current Contents is the most useful for biochemists. The computer revolution has reached into the chemical and biochemical literature, and most college and university libraries now subscribe to computer bibliographic search services. One such service is STN International, the scientific and technical information network. This on-line system allows direct access to some of the world s largest scientific databases. The STN databases of most value to life scientists include BIOSIS Pre-views/RN (produced by Bio Sciences Information Service covers original research reports, reviews, and U.S. patents in biology and biomedicine), CA (produced by Chemical Abstracts service covers research reports in all areas of chemistry), MEDLINE, and MEDLARS (produced by the U.S. National Library of Medicine and Index Medicus, respectively cover all areas of biomedicine). These networks provide on-line service and their databases can be accessed from personal computers in the office, laboratory, or library. Some... [Pg.218]


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