COMPOUND INDEX

This Formula Index consists of over 28 000 compounds that occur in the 6562 text pages of Volumes 1-6. Indexed compounds may appear in the text, equations, Schemes, Figures or Tables. Only specific compounds and not general classes of compound have been indexed the counter ion has been excluded. Limitations of space do not permit every coordination compound to be indexed each time it is mentioned, therefore compounds are only indexed when considered to be important in the context of the topic under discussion. 

Such requirements are expected to assure that the dosage form is formulated and manufactured appropriately to ensure that the index or marker ingredients are uniformly distributed and will dissolve in the gastrointestinal tract and be available for absorption. No assumption is made that the marker or index compound selected for demonstration of dissolution is responsible for the purported effect. The test is valuable in that it assures that the formulation technology used is reflective of the state-of-the-art technology, provides a means to evaluate lot-to-lot performance over a product s shelf-life and that excipients used to facilitate transfer of the index or marker ingredients of the botanical to the human system are appropriate. 

A thermally unstable group of compounds, tending to violent decomposition or explosion on heating. Individually indexed compounds are ... 

Individually indexed compounds are f Butanethiol, 1712 f 2-Butanethiol, 1713 Dodecanethiol, 3567 f Ethanethiol, 0933 f Methanethiol, 0489 f 2-Methylbutane-2-thiol, 2023 f 3-Methylbutanethiol, 2024 f 2-Methylpropanethiol, 1715 f 2-Methyl-2-propanethiol, 1716... 

Individually indexed compounds of this relatively small sub-group of commercially available compounds are ... 

As with other non-metal derivatives, reactivity depends on chain-length, branching and degree of halogen substitution. Individually indexed compounds are f Chloromethylphenylsilane, 2810 f Chlorotrimethylsilane, 1304 f Cyanotrimethylsilane, 1665 f Dichlorodiethylsilane, 1683 f Dichlorodimethylsilane, 0902 f Dichloroethylsilane, 0903 f Dichloromethylsilane, 0470 f Dichloromethylvinylsilane, 1208 f Iodotrimethylsilane, 1306 f Methyltrichlorosilane, 0439 f Trichloroethylsilane, 0854 f Trichlorovinylsilane, 0746... 

Many alkyl nitrites are thermally unstable and may readily decompose or explode on heating [1], Methyl nitrite explodes more violently than ethyl nitrite [2], Lower alkyl nitrites have been known to decompose and burst the container, even in refrigerated storage [3], Individually indexed compounds are f Butyl nitrite, 1658 f fert-Butyl nitrite, 1659... 

Measurements of the autoignition temperatures for several series of mono-, di-, tri-and tetra-alkylsilanes showed that the ease of oxidation decreases with increasing substitution. In this group of easily ignited or pyrophoric compounds, individually indexed compounds are ... 

Trifluoromethanesulfonate esters ( triflates ) of allyl alcohol and its derivatives are very reactive and undiluted samples must be stored in vented containers at — 78° C. A chilled sample of allyl triflate in a sealed ampoule exploded on being allowed to warm to ambient temperature. The esters react violently with aprotic solvents such as DMF or DMSO. Individually indexed compounds are ... 

Datta, R. L. et al., J. Chem. Soc., 1919, 115, 1006-1010 Many perchlorate salts of amines explode in the range 215-310°C, and some on impact at ambient temperature. Individually indexed compounds are to be found in the group entries ... 

This group of compounds, previously described as amine perchromates , is characterised by the presence of basic nitrogen and peroxo ligands within the same coordination sphere. This creates a high tendency towards explosive decomposition, which sometimes apparently occurs spontaneously. Individually indexed compounds are ... 

Alkyl and aryl arenediazoates ( diazoethers ) are generally unstable and even explosive compounds. They are produced by interaction of alcohols with (explosive) bis(arenediazo) oxides, or of -blocked phenols with diazonium salts. The thio analogues are similar. Individually indexed compounds are ... 

This reactive group includes the individually indexed compounds ... 

Certain 2-azidocarbonyl compounds and congeners have long been known as unstable substances [1]. Some members of a group of 2,5-dialkyl-3,6-diazido-1,4-benzoquinones decompose violently on melting [2], Individually indexed compounds are ... 

Several derivatives of the highly reactive aziridine (ethylenimine) show explosive instability. Individually indexed compounds are f Aziridine, 0863 1,1-Biaziridinyl, 1593... 

Action of alkalies on diazonium solutions, or of acids on alkali diazoates to give a final pH of 5-6, causes these compounds ( diazoanhydrides ) to separate as oils or solids. Many of these are violently explosive (some exceeding nitrogen trichloride in effect), sensitive to friction and heat or contact with aromatic hydrocarbons [1,2], Individually indexed compounds are ... 

The explosive carbonylalkali-metals , previously formulated as monomeric compounds, are either dimeric acetylene derivatives of the general formula MOC=COM. or are trimers of the latter and formulated as salts of hexahydroxybenzene. Many true carbonylmetal complexes are air-sensitive and pyrophoric, not always immediately. Individually indexed compounds are Bis(dicarbonylcyclopentadienyliron)-bis(tetrahydrofuran)magnesium, 3835... 

Many of the salts which have been prepared are explosive and sensitive to heat or impact. These include chlorites of copper (violent on impact), hydrazine (monochlorite, inflames when dry), nickel (explodes at 100°C but not on impact), silver (at 105° or on impact), sodium, tetramethylammonium, mercury, thallium and lead (which shows detonator properties). Several other chlorites not isolated and unstable in solution include mono-, di- and tri-methylammonium chlorites. The metal salts are powerful oxidants [1], Chlorites are much less stable than the corresponding chlorates, and most will explode under shock or on heating to around 100°C [2], Individually indexed compounds are ... 

This group of highly reactive compounds includes several which have found extensive use in preparative chemistry [1], Properties and reactions of several covalent tetrahydroborates have been reviewed [2], Preparation and properties of several new hydrides are given which are of interest as high-energy fuels in propellant systems [3,4], Individually indexed compounds are ... 

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