Hydrocarbons using

Arosolvan process A process for the extraction of benzene and toluene from a mixture of aromatic and saturated hydrocarbons using a mixture of water and N-methylpyrrolidone. The process is used when naphtha is cracked to produce alkenes. To prevent extraction of alkenes these are saturated by hydrogenation prior to extraction. 

Mobil MTG and MTO Process. Methanol from any source can be converted to gasoline range hydrocarbons using the Mobil MTG process. This process takes advantage of the shape selective activity of ZSM-5 zeoHte catalyst to limit the size of hydrocarbons in the product. The pore size and cavity dimensions favor the production of C-5—C-10 hydrocarbons. The first step in the conversion is the acid-catalyzed dehydration of methanol to form dimethyl ether. The ether subsequendy is converted to light olefins, then heavier olefins, paraffins, and aromatics. In practice the ether formation and hydrocarbon formation reactions may be performed in separate stages to faciHtate heat removal. 

Aliphatic Chemicals. The primary aliphatic hydrocarbons used in chemical manufacture are ethylene (qv), propjiene (qv), butadiene (qv), acetylene, and / -paraffins (see Hydrocarbons, acetylene). In order to be useflil as an intermediate, a hydrocarbon must have some reactivity. In practice, this means that those paraffins lighter than hexane have Httle use as intermediates. Table 5 gives 1991 production and sales from petroleum and natural gas. Information on uses of the C —C saturated hydrocarbons are available in the Hterature (see Hydrocarbons, C —C ). 

Hydrocarbons from Synthesis Gas and Methanol. Two very important catalytic processes in which hydrocarbons are formed from synthesis gas are the Sasol Eischer-Tropsch process, in which carbon monoxide and hydrogen obtained from coal gasification are converted to gasoline and other products over an iron catalyst, and the Mobil MTG process, which converts methanol to gasoline range hydrocarbons using ZSM-5-type 2eohte catalysts. 

The production of hydrocarbons using traditional Fischer-Tropsch catalysts is governed by chain growth or polymerization kinetics. The equation describing the production of hydrocarbons, commonly referred to as the Anderson-Schulz-Flory equation, is ... 

Hence if a laboratory measurement at 25°C yields a conductivity of 100 pS/m the same liquid at -10°C will have a conductivity of about 30 pS/m. The effects of low temperature combined with the elevated dielectric constants of many nonconductive chemicals support use of the 100 pS/m demarcation for nonconductive liquids (5-2.5) rather than the 50 pS/m demarcation used since the 1950s by the petroleum industry. For most hydrocarbons used as fuels, the dielectric constant is roughly 2 and a demarcation of 50 pS/m is adequate, provided the conductivity is determined at the lowest probable handling temperature. 

Figure 8-151. Graphical correlation of sieve tray ultimate capacity for hydrocarbons. Used by permission, Capps, R. W., The American Institute of Chemical Engineers, Chem. Eng. Prog. V. 89, No. 3 (1993), p. 35, all rights reserved.

Paraffinic hydrocarbons used for producing petrochemicals range from the simplest hydrocarbon, methane, to heavier hydrocarbon gases and liquid mixtures present in crude oil fractions and residues. 

The relation between c and / and X (defined by equation 5.1) is shown in Figure 5.4, where it is seen that separate curves are given according to the nature of the flow of the two phases. This relation was developed from studies on the flow in small tubes of up to 25 mm diameter with water, oils, and hydrocarbons using air at a pressure of up to 400 kN/m . For mass flowrates per unit area of U and G for the liquid and gas, respectively, Reynolds numbers Rei L d/fii ) and Rec(G d/fia) may be used as criteria for defining the flow regime values less than 1000 to 2000, however, do not necessarily imply that the fluid is in truly laminar flow. Later experimental work showed that the total pressure has an influence and data presented by Gr1H ITH(i9) may be consulted where... 

TEF Values for Polyhalogenated Aromatic Hydrocarbons Used in a Study of Residues in Fish... 

Selective Conversion of Methane to Ci Hydrocarbons using Carbon Dioxide as an Oxidant over CaO-MnO/CeOi Catalyst... 

Low energy pulsed (LEP) discharge is a simple hydrogen production process. This novel technique requires neither high temperature nor pressure die reaction takes place at room temperature and atmospheric pressure. We have successftilly reformed hydrocarbons using this LEP dischai e [1-6]. 

Oxidation of hydrocarbons using tetranitromethane is extremely dangerous. For instance, when 10 g of this compound are mixed with toluene this led to a detonation that caused the death of ten people and twenty people to be seriously injured. 

R. Tauler, A.K. Smilde, J.M. Henshaw, L.W. Burgess and B.R. Kowalski, Multicomponent determination of chlorinated hydrocarbons using a reaction-based chemical sensor. 2 Chemical speciation using multivariate curve resolution. Anal. Chem., 66 (1994) 3337-3344. 

Heat transfer operations. Heat transfer fluids other than steam and cooling water utilities are sometimes introduced into the design of the heat exchange system. These heat transfer media are sometimes liquid hydrocarbons used at high pressure. When possible, higher boiling liquids should be used. Better still, the flammable material should be substituted with a nonflammable medium such as water or molten salt. 

Considering the current knowledge (see above), one may assume that 43, as well as 44 or 45, are capable of forming crystal inclusions only with low-voluminous hydrocarbons using weak van der Waals forces. Contrary to all expectations, polar... 

Subczynski, W. K. and J. S. Hyde. 1984. Diffusion of oxygen in water and hydrocarbons using an electron spin resonance spin-label technique. Biophys. J. 45 743-748. 

Hirano, K., Inoue, K., and Yatsu, T. (1992) Photocatalysed reduction of C02 in aqueous Ti02 suspension mixed with copper powder. Journal of Photochemistry and Photobiology A Chemistry, 64 (2), 255-258. Adachi, K., Ohta, K., and Mizuno, T. (1994) Photocatalytic reduction of carbon dioxide to hydrocarbon using copper-loaded titanium dioxide. Solar Energy,... 

HBCD is a brominated aliphatic cyclic hydrocarbon used as a flame retardant in thermal insulation building materials, upholstery textiles, and electronics. In 2001, the world market demand for HBCD was 16,700 tons, from which 9,500 tons was sold in the EU. These figures make HBCD the second highest volume BFR used in Europe [29], HBCD may be used as an alternative for PBDEs in some applications. To date, there are no restrictions on the production or use of HBCD. As a result of their widespread use and their physical and chemical properties, HBCD are now ubiquitous contaminants in the environment and humans [30, 31]. 

Tauler R., Smilde A.K., Hemshaw J.M., Burgess L.W., Kowalski B.R., Multicomponent Determination of Chlorinated Hydrocarbons Using a Reaction-based Chemical Sensor. Part 2. Chemical Speciation Using Multivariate Curve Resolution, Anal. Chem. 1994 66 3337-3344. 

Hashimoto et al. [82] reported the photocatalytic production of hydrogen from aliphatic and aromatic hydrocarbons using a powdered Pt/Ti02 photocatalyst suspended in deaerated water. The hydrocarbon-water-photocatalyst system was exposed to UV irradiation... 

In a number of model studies it has been demonstrated that synthetic porphyrin complexes are able to be oxidized to oxo-metalloporphyrin complexes which will, in turn, oxidize organic substrates of the type mentioned previously. Thus, in an early investigation it was shown that a synthetic Fe(m) porphyrin will catalyze oxygenation of hydrocarbons using iodosylbenzene as the reduced-oxygen source (Groves, Nemo Myers, 1979). Following this report, a number of related cytochrome... 

Steynberg, A. P., Nel, W. U., and Desmet, M. A. 2004. Large scale production of high value hydrocarbons using Fischer-Tropsch technology. Stud. Surf. Sci. Catal. 147 37—42. 

---