Heavy ion

An example of siieh a measurement is shown in fignre Bl.24.20 where a A E-E deteetor teleseope was used to diseriminate between different elements. Wlren using heavy ions as ineident partieles in the analysis of surfaee layers, eare must be taken not to damage the surfaee. 

Figure Bl.24.20. An example of a heavy-ion (iodine) FRS measurement where a large A E-E deteetor...

Behrisoh R, Prozesky V M, Huber H and Assmann W 1996 Hydrogen desorption induoed by heavy-ions during surfaoe anaiysis with ERDA Nucl. Instrum. Methods B 118 262... 

The existence of element 107 was confirmed by a team of West German physicists at the Heavy Ion Research Laboratory at Darmstadt, who created and identified six nuclei of element 107. 

On August 29,1982, physicists at the Heavy Ion Research Laboratory, Darmstadt, West Germany made and identified element 109 by bombing a target of Bi-209 with accelerated nuclei of Fe-58. If the combined energy of two nuclei is sufficiently high, the repulsive forces between the nuclei can be overcome. 

The elements beyond the actinides in the Periodic Table can be termed the transactinides. These begin with the element having atomic number 104 and extend, in principle, indefinitely. Although only six such elements, numbers 104—109, were definitely known in 1991, there are good prospects for the discovery of a number of additional elements just beyond number 109 or in the region of larger atomic numbers. They are synthesized by the bombardment of heavy nucHdes with heavy ions. 

Radiation Damage. It has been known for many years that bombardment of a crystal with energetic (keV to MeV) heavy ions produces regions of lattice disorder. An implanted ion entering a soHd with an initial kinetic energy of 100 keV comes to rest in the time scale of about 10 due to both electronic and nuclear coUisions. As an ion slows down and comes to rest in a crystal, it makes a number of coUisions with the lattice atoms. In these coUisions, sufficient energy may be transferred from the ion to displace an atom from its lattice site. Lattice atoms which are displaced by an incident ion are caUed primary knock-on atoms (PKA). A PKA can in turn displace other atoms, secondary knock-ons, etc. This process creates a cascade of atomic coUisions and is coUectively referred to as the coUision, or displacement, cascade. The disorder can be directiy observed by techniques sensitive to lattice stmcture, such as electron-transmission microscopy, MeV-particle channeling, and electron diffraction. 

As earlier discussed, the dominant factor in the near-surface region is the particle detection system. For a typical silicon surface barrier detector (15-keV FWHM resolution for Fle ions), this translates to a few hundred A for protons and 100— 150 A for Fle in most targets. When y rays induced by incident heavy ions are the detected species (as in FI profiling), resolutions in the near-surface region may be on order of tens of A. The exact value for depth resolution in a particular material depends on the rate of energy loss of incident ions in that material and therefore upon its composition and density. 

The total energy, E, is obtained from the total charge accumulated in both sections of the anode. The second part of the ionization chamber, which measures the energy E - AE, can be replaced by an SBD [3.167], and the first part, which measures the energy loss AE, by a transmission SBD [3.168, 3.169]. When SBDs are used to measure heavy ions, radiation damage of the detector by the ions must be taken into account. 

Elements beyond 103 are expected to be 6d elements forming a fourth transition series, and attempts to synthesize them have continued during the past thirty years. All 10 (including, of course, actinium) are now known and are discussed in the section on transactinide elements on p. 1280. The work has required the dedicated commitment of extensive national facilities and has been carried out at the Lawrence-Berkeley Laboratories, the Joint Institute for Nuclear Research at Dubna, and the Heavy-Ion Research Centre (GSI) at Darmstadt, Germany. 

Since the radioactive half-lives of the known transuranium elements and their resistance to spontaneous fission decrease with increase in atomic number, the outlook for the synthesis of further elements might appear increasingly bleak. However, theoretical calculations of nuclear stabilities, based on the concept of closed nucleon shells (p. 13) suggest the existence of an island of stability around Z= 114 and N= 184. Attention has therefore been directed towards the synthesis of element 114 (a congenor of Pb in Group 14 and adjacent superheavy elements, by bombardment of heavy nuclides with a wide range of heavy ions, but so far without success. 

Thermal properties of several chlorinated phenols and derivatives were studied by differential thermal analysis and mass spectrometry and in bulk reactions. Conditions which might facilitate the formation of stable dioxins were emphasized. No two chlorinated phenols behaved alike. For a given compound the decomposition temperature and rate as well as the product distribution varied considerably with reaction conditions. The phenols themselves seem to pyro-lyze under equilibrium conditions slowly above 250°C. For their alkali salts the onset of decomposition is sharp and around 350°C. The reaction itself is exothermic. Preliminary results indicate that heavy ions such as cupric ion may decrease the decomposition temperature. 

Heavy ion backscattering spectrometry (HIBS) using ions heavier than He++ with accelerators and detectors similar to those for RBS. 

HIBS is the same as RBS, except that heavy ions are used instead of He++. It is an ion beam analysis tool patented by the Sandia Corporation of the USA, and was developed to enable the measurement of trace levels of surface contamination on silicon wafers. Metal contamination present in starting material is detrimental to devices, since it results in defects which limit wafer yields and impair circuit operation. 

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