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Green, Acid Aldehyde

Tobacco leaf has a complicated chemical composition including a variety of polymers and small molecules. The small molecules from tobacco belong to numerous classes of compounds such as hydrocarbons, terpenes, alcohols, phenols, acids, aldehydes, ketones, quinones, esters, nitriles, sulfur compounds, carbohydrates, amino acids, alkaloids, sterols, isoprenoids [48], Amadori compounds, etc. Some of these compounds were studied by pyrolysis techniques. One example of pyrolytic study is that of cuticular wax of tobacco leaf (green and aged), which was studied by Py-GC/MS [49]. By pyrolysis, some portion of cuticular wax may remain undecomposed. The undecomposed waxes consist of eicosyl tetradecanoate, docosyl octadecanoate, etc. The molecules detected in the wax pyrolysates include hydrocarbons (Cz to C34 with a maximum of occurrence of iso-Czi, normal C31 and anti-iso-C32), alcohols (docosanol, eicosanol), acids (hexadecanoic, hexadecenoic, octadecanoic, etc ). The cuticular wax also contains terpenoids such as a- and p-8,13-duvatriene-1,3-diols. By pyrolysis, some of these compounds are not decomposed and others generate closely related products such as seco-cembranoids (5-isopropyl-8,12-dimethyl-3E,8E,12E,14-pentadecatrien-2-one, 3,7,13-trimethyl-10-isopropyl-2,6,11,13-tetradecatrien-1al) and manols. By pyrolysis, c/s-abienol, (12-Z)- -12,14-dien-8a-ol, generates mainly frans-neo-abienol. [Pg.445]

The central carbon atom is derived from an aromatic aldehyde or a substance capable of generating an aldehyde during the course of the condensation. Malachite green is prepared by heating benzaldehyde under reflux with a slight excess of dimethyl aniline in aqueous acid (Fig. 2). The reaction mass is made alkaline and the excess dimethylaniline is removed by steam distillation. The resulting leuco base is oxidized with freshly prepared lead dioxide to the carbinol base, and the lead is removed by precipitation as the sulfate. Subsequent treatment of the carbinol base with acid produces the dye, which can be isolated as the chloride, the oxalate [2437-29-8] or the zinc chloride double salt [79118-82-4]. [Pg.270]

Malachite green (0.0...2.0) uracil derivatives, triazine herbicides [163] polar lipids [246, 247] phospholipids [248, 249] fatty acids, fatty aldehydes, phospholipids and glycolipids [250] microbiocidal isothiazolones [251]... [Pg.45]

BerL Ber., abbrev. (Berliner Berichte) Berickte der deutscken chemiachen Gesellscka/t. Berliner-blau, n. Berlin blue, Prussian blue, -blaus ure, /. hydrocyanic acid, -braun, n. Prussian brown, -griin, n. Prussian green, -rot, n. Berlin red (a red lake color), -saure,/. prussic acid, -weiss, n. a kind of white lead. Bernstein, m. amber. — schwarzer —, jet. Bernstein-, amber succinic, succinyl, succino-. -alaun, m. aluminous amber, -aldehyd, n. succinaldehyde. bemateinartig, a. amber-like. [Pg.66]

Other than energy considerations, on which there is little comparative data, the most important green role for photochemistry is in improving atom economy. Although only a preliminary research result, an excellent example of this is the avoidance of the need for stoichiometric amounts of Lewis acid catalysts in the synthesis of some acylated aromatic compounds. Benzoquinone can be reacted with an aldehyde under a sunlamp to yield an acylhydroquinone in up to 88% yield. The alternative procedure would involve reaction of an acyl chloride with hydroquinone and a... [Pg.219]

Model systems indicate that aldehydes may also be produced by the action of polyphenoloxidases on amino acids in the presence of catechin, all of which are present in coffee beans at some stage between green and roasted. For example, valine yields isobutanal, leucine yields isopentanal, and isoleucine yields 2-methyl-butanal.14 Some of these aldehydes probably undergo condensation reactions in the acidic medium of the roasted bean when moisture is present.15 Some dienals in green coffee beans have recently been identified as (E,E)-2,4- and (E,Z)-2,4-nonadienal and (E,E)-2,4- and (E,Z)-2,4-decadienal.18... [Pg.109]

Lewis acids as water-stable catalysts have been developed. Metal salts, such as rare earth metal triflates, can be used in aldol reactions of aldehydes with silyl enolates in aqueous media. These salts can be recovered after the reactions and reused. Furthermore, surfactant-aided Lewis acid catalysis, which can be used for aldol reactions in water without using any organic solvents, has been also developed. These reaction systems have been applied successfully to catalytic asymmetric aldol reactions in aqueous media. In addition, the surfactant-aided Lewis acid catalysis for Mannich-type reactions in water has been disclosed. These investigations are expected to contribute to the decrease of the use of harmful organic solvents in chemical processes, leading to environmentally friendly green chemistry. [Pg.4]

The nucleophilic displacement of suitable para substituents in analogues of malachite green is used as a means of synthesis of some important acid dyes. For example, Cl Acid Blue 83 (6.176 R = H) is made by the aldehyde method, using 4-chlorobenzaldehyde and N-ethyl-N-(3-sulphobenzyl)aniline. The resulting leuco base is oxidised to the colour salt,... [Pg.337]

In some cases special synthetic methodologies were applied to increase reactions yields or to satisfy green chemistry requirements. For example, Yao and co-authors [41] successfully carried out solvent-free three-component reaction of 5-ammotetrazole, aromatic aldehydes, and acetoacetic acid in the presence of inexpensive and commercially available sulfamic acid as catalyst. The yields of the MCRs were rather low but the whole procedure was facile, economic, and eco-friendly. [Pg.47]

To carry out MCRs of aminoazoles with aldehydes and cyclic CH-acids, the methods of green chemistry were also applied. For example, treatments of 3-methylisoxazol-5-amine and aromatic aldehydes with 1,3-cyclohexanedione, dimedone, 1,3-indanedione, or titronic acid were proceeded in water under micro-wave irradiation at 120°C [100] (Scheme 31). As a result, clean, efficient, and convenient procedures for the generation of polycyclic-fused isoxazolo[5,4-b] pyridines 71 were developed. An interesting fact is that, in the case of 1,3-cyclohexanedione, dihydropyridine s were obtained while in aU other cases only hetero-aromatized derivatives were isolated. No reason for this experimental fact was discussed in the article. [Pg.62]

The first positive results in the synthesis of these heterocyclic compounds by MCR of aminoazoles, aldehydes, and barbituric acids were published in 2008 by Shi et al. [111]. They also used green chemistry methodology and carried out treatment of the starting materials in water under microwave irradiation. The temperature optimization procedure and search for the best catalytic system allowed selecting one equivalent of p-TSA and 140°C as optimum conditions for the synthesis. With application of the procedure elaborated 24 novel pyrazolopyr-idopyrimidines 76 were generated (Scheme 33). [Pg.63]

Partially hydrogenated quinoline cores are also present in some important bioactive compounds. For example, the 4-aza-analogs of Podophyllotoxin, a plant lignan that inhibits microtubule assembly, revealed to be more potent and less toxic anticancer agents. In 2006, Ji s group reported a green multicomponent approach to a new series of these derivatives, consisting of the reaction of either tetronic acid or 1,3-indanedione with various aldehydes and substituted anilines in water under microwave irradiation conditions (Scheme 26) [107]. For this efficient and eco-friendly transformation, the authors proposed a mechanism quite similar to the one that was postulated for the synthesis of tetrahydroquinolines in the precedent section. [Pg.243]

The volatiles produced by the LOX pathway and autoxidation are typically volatile aldehydes and alcohols responsible for fresh and green sensorial notes. In the LOX pathway these volatile compounds are produced in response to stress, during ripening or after damage of the plant tissue. The pathway is illustrated in Scheme 7.2. Precursors of the LOX (EC 1.13.11.12) catalysed reactions are Cis-polyunsaturated fatty acids with a (Z,Z)-l,4-pentadiene moiety such as linoleic and a-linolenic acids that are typically oxidised into 9-, 10- or 13-hydro-peroxides depending on the specificity of the LOX catalyst. These compounds are then cleaved by hydroperoxide lyase (HPL) into mainly C, C9 and Cio aldehydes, which can then be reduced into the corresponding alcohols by alcohol dehydrogenase (ADH EC 1.1.1.1) (Scheme 7.2) [21, 22]. The production of volatile compounds by the LOX pathway depends, however, on the plants as they have different sets of enzymes, pH in the cells, fatty acid composition of cell walls, etc. [Pg.137]

Scheme 233 Formation of aliphatic flavour aldehydes and alcohols, a Biotechnological reaction sequence mimicking plant biosynthesis of C6 compounds (green notes ), b HomologoiK reaction sequence in fimgi leading to mushroom-like C8 compounds. The stoichiometric formation of w-oxo-carboxylic acids during hydroperoxide lyase cleavage is not depicted... Scheme 233 Formation of aliphatic flavour aldehydes and alcohols, a Biotechnological reaction sequence mimicking plant biosynthesis of C6 compounds (green notes ), b HomologoiK reaction sequence in fimgi leading to mushroom-like C8 compounds. The stoichiometric formation of w-oxo-carboxylic acids during hydroperoxide lyase cleavage is not depicted...
Surface lipids of plants. The thick cuticle (Fig. 1-6) that covers the outer surfaces of green plants consists largely of waxes and other lipids but also contains a complex polymeric matrix of cutin (stems and leaves) or suberin (roots and wound surfaces).135/135a Plant waxes commonly have C10 - C30 chains in both acid and alcohol components. Methyl branches are frequently present. A major function of the waxes is to inhibit evaporation of water and to protect the outer cell layer. In addition, the methyl branched components may inhibit enzymatic breakdown by microbes. Free fatty acids, free alcohols, aldehydes, ketones, 13-dike tones, and alkanes are also present in plant surface waxes. Chain lengths are usually C20 - C35.136 Hydrocarbon formation can occur in other parts of a plant as well as in the cuticle. Thus, normal heptane constitutes up to 98% of the volatile portion of the turpentine of Pin us jeffreyi.81... [Pg.1196]

Carboxylates and other negatively charged functional groups can be detected by treatment with a positively charged dye, such as malachite green [71]. Polystyrene-bound aldehydes can be visualized by treatment with 4-methoxybenzaldehyde under acidic conditions [72]. Quantification of resin-bound carbonyl compounds has been achieved by conversion into dansyl hydrazones [73],... [Pg.10]


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See also in sourсe #XX -- [ Pg.128 ]




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