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Fluorine compound

Apart from the free-radical mode of decomposition, many halogen compounds decompose by unimolecular mechanisms, the most common of these being the direct unimolecular elimination of hydrogen halide. There is evidence that these types of unimolecular reactions involve charge separation of the carbon-halogen bond in the transition state, and they have received considerable attention in recent years. [Pg.149]

In this chapter the emphasis has been placed on the kinetic aspects of decomposition behaviour and their bearing upon possible mechanisms for chemical change. Information based on product formation without rate data has been treated only briefly or omitted from the review. [Pg.149]

The author is grateful to Mr. J. D. Rock for assistance in the preparation of the section on the radiolysis of halogen compounds. [Pg.149]

The relatively high thermal stability of fluorine compounds is largely attributable to the carbon-fluorine bond strength which is much greater than that of carbon-hydrogen or of carbon-carbon. Thus Coomber and Whittle s have estimated [Pg.149]

Early observations on the stability of fluorine compounds were made by Mil-ler. Cady et a/.9 . 532,603 reported on the pyrolysis of some [Pg.150]

Though materials containing fluorine atoms can act as oxidizers, most fluorine compounds are gases or Hquids at ambient temperatures and hence cannot be used as oxidizers in pyrolants. However, some solid fluorine compounds are utilized as oxidizer components of energetic pyrolants. [Pg.293]

SFg is a crystalHne material that acts as an oxidizer of metallic fuels. Since both sulfur and fluorine atoms act as oxidizer components, the oxidizing potential of S Fg is high. Mixtures of SFs and Li generate significant heat as a result of the reaction  [Pg.293]

Polytetrafluoroethylene (Tf) is a polymeric fluorine compound that consists of a -C2F4- molecular structure,ini which contains a mass fraction of fluorine of 0.75. Tf is insoluble in water and its specific mass is in the range 3550-4200 kg nr in peUe- [Pg.293]

The selechon of fuel components to be mixed with oxidizer components is also an important issue in the development of pyrolants for various applications. Metal particles are used as fuel components to develop small-scale pyrolant charges as deployed in igniters, flares, and fireworks. Non-metal particles such as boron and carbon are used to formulate energetic pyrolants. Polymeric materials are commonly used as fuel components to develop relatively large-scale pyrolant charges, such as gas generators and fuel-rich propellants. [Pg.294]


One hypothesis says that fluorine can be substituted for hydrogen wherever it occurs in organic compounds, which could lead to an astronomical number of new fluorine compounds. Compounds of fluorine with rare gases have now been confirmed in fluorides of xenon, radon, and krypton. [Pg.24]

Semiempirical, DFT, and ah initio methods also work well. Correlation effects are sometimes included for the sake of increased accuracy, but are not always necessary. One particular case for which correlation is often necessary is fluorine compounds. [Pg.285]

VF copolymers [FLUORINE COMPOUNDS, ORGANIC - POLY(VINYL FLUORIDE)] (Vol 11)... [Pg.13]

HFinprdnof [FLUORINE COMPOUNDS, INORGANIC - HYDROGEN] (Volll) -pharmacodynamics of [PHARMIACODYNAMICS] (Vol 18)... [Pg.55]


See other pages where Fluorine compound is mentioned: [Pg.178]    [Pg.1447]    [Pg.346]    [Pg.54]    [Pg.59]    [Pg.124]    [Pg.28]    [Pg.33]    [Pg.34]    [Pg.60]    [Pg.62]    [Pg.64]    [Pg.68]    [Pg.71]    [Pg.71]    [Pg.79]    [Pg.87]    [Pg.100]    [Pg.100]    [Pg.100]    [Pg.108]    [Pg.112]    [Pg.159]    [Pg.170]    [Pg.173]    [Pg.174]    [Pg.188]    [Pg.190]    [Pg.191]    [Pg.199]    [Pg.199]    [Pg.199]    [Pg.199]    [Pg.204]    [Pg.221]    [Pg.226]    [Pg.237]    [Pg.245]    [Pg.261]    [Pg.271]    [Pg.283]    [Pg.286]    [Pg.289]    [Pg.299]    [Pg.313]   
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See also in sourсe #XX -- [ Pg.247 ]

See also in sourсe #XX -- [ Pg.293 ]

See also in sourсe #XX -- [ Pg.42 ]

See also in sourсe #XX -- [ Pg.582 , Pg.583 , Pg.589 , Pg.590 , Pg.735 , Pg.736 , Pg.737 , Pg.738 ]

See also in sourсe #XX -- [ Pg.80 ]

See also in sourсe #XX -- [ Pg.64 ]

See also in sourсe #XX -- [ Pg.179 ]

See also in sourсe #XX -- [ Pg.29 , Pg.248 ]

See also in sourсe #XX -- [ Pg.379 , Pg.380 ]

See also in sourсe #XX -- [ Pg.13 , Pg.30 , Pg.64 , Pg.72 , Pg.124 , Pg.130 , Pg.132 , Pg.146 , Pg.198 , Pg.218 , Pg.225 , Pg.230 , Pg.244 , Pg.249 , Pg.303 ]




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Aromatic compounds direct fluorinations

Aromatic compounds fluorinated amino acids

Aromatic fluorine compounds

Aromatic fluorine compounds preparation

Barium fluorinated compounds

Binary Fluorine-Nitrogen Compounds

Bismuth compounds elemental fluorine

Boron-fluorine compounds

Bromine, atomic weight fluorine compounds

Calcium fluorinated compounds

Carbon fluorinated oxygen compounds

Carbon fluorine intercalation compound

Carbon-fluorine compounds

Carbonyl compounds electrophilic fluorination

Carbonyl compounds fluorination

Carboxylates fluorinated compounds

Chemical vapor deposition fluorinated compounds

Chemistry of Organic Fluorine Compounds

Chemistry of Organic Fluorine Compounds perfluoroalkyl halides with

Compounds of Fluorine, Chlorine, Bromine and Iodine

Covalent compounds fluorine

Determination of fluorine in organic compounds

Dicarbonyl compounds fluorination

Electrochemical fluorination of heterocyclic compounds

Electrolytic Fluorination of Heterocyclic Compounds in Trialkylamine Complexes with Anhydrous Hydrogen Fluoride

Electrophilic fluorination aromatic compound

FLUORINATED ALIPHATIC COMPOUNDS

FLUORINATED ORGANOLITHIUM COMPOUNDS

FLUORINE COMPOUNDS, INORGANIC

Five FLUORINE COMPOUNDS

Fluorin , reaction with organic compounds

Fluorinated Heterocyclic Compounds: Synthesis, Chemistry, and Applications, Edited by Viacheslav A. Petrov

Fluorinated aromatic compounds

Fluorinated compounds

Fluorinated compounds 4-fluorothreonine

Fluorinated compounds Gauche effect

Fluorinated compounds chemical synthesis

Fluorinated compounds fluoroacetate

Fluorinated compounds reactions

Fluorinated compounds reactions atmosphere

Fluorinated compounds, as catalyst phases

Fluorinated compounds, enol

Fluorinated compounds, fragmentation

Fluorinated compounds, hydrolysis

Fluorinated compounds. See

Fluorinated organic substances compounds

Fluorinated organoboron compounds

Fluorinated organosilicon compounds

Fluorinated peroxo compounds

Fluorinated vinyl compounds

Fluorinated-graphite-intercalation compound

Fluorination aromatic compounds

Fluorination compounds

Fluorination compounds

Fluorination nitro compounds

Fluorination of Volatile Inorganic Compounds

Fluorination of aromatic compounds

Fluorination of carbonyl compounds

Fluorination of heterocyclic compounds

Fluorination of organic compounds

Fluorination, apparatus for of volatile inorganic compounds

Fluorinations electron rich aromatic compounds

Fluorine 18 atom reactions with organometallic compounds

Fluorine bromine compounds

Fluorine chlorine compounds

Fluorine compounds (pesticides)

Fluorine compounds Freon

Fluorine compounds Teflon

Fluorine compounds and complexes

Fluorine compounds bond polarity

Fluorine compounds carbon tetrafluoride

Fluorine compounds chlorofluorocarbons

Fluorine compounds hydrochlorofluorocarbons

Fluorine compounds ionic bonds

Fluorine compounds molecular shape

Fluorine compounds phosphorus pentafluoride

Fluorine compounds, aliphatic

Fluorine compounds, aliphatic tables

Fluorine compounds, derivatives

Fluorine compounds, general

Fluorine compounds, organic

Fluorine compounds, research

Fluorine halogen oxide compounds

Fluorine introduction into organic compounds

Fluorine organic compounds Asymmetric fluorination

Fluorine oxygen compounds with

Fluorine test for, in compounds

Fluorine with iodine compounds

Fluorine with sulfur compounds

Fluorine, volatile inorganic compounds

Fluorine-18, and compounds labeled

Fluorine-Containing Compounds

Fluorine-Containing Compounds George H. Cady

Fluorine-Containing Polymerizable Cyclic Olefin Compound

Fluorine-containing compounds agrochemicals

Fluorine-graphite compounds

Fluorine-sulfur compounds with antimony

Fluorine-sulfur compounds with nitrogen

Graphite intercalation compounds fluorine

Halogenated Compounds (Other Than Fluorinated)

Heterocyclic compounds fluorination

Heteroleptic compounds the molecular structures of fluorinated methanes and methylsilanes

Iodine acetate fluorine compounds

Ionic bonding fluorine compounds

Natural fluorinated compounds

Nitrogen-fluorine compounds

Optically active fluorinated compounds

Organic compounds selective fluorination

Organic fluorine compounds pyrolysis

Organic fluorine compounds, combustion

Organofluoro Compounds by Electrochemical Fluorination

Organolithium compounds fluorinations

Organometallic compounds fluorinations

Other Inorganic Compounds Containing Sulfur and Fluorine

Overview on the Preparation of Fluorinated Compounds

Oxygen halogen compounds fluorinated peroxides

Partially fluorinated compounds

Peacock, R. D., Some Fluorine Compounds of the Transition Metals

Platinum, decomposition fluorine compounds

Polymeric fluorine compound

Pyrex reaction fluorine compounds

REACTIONS OF FLUORINE COMPOUNDS

Reaction vessels fluorine compounds

Replacement of NH2 in aromatic or heterocyclic compounds by fluorine (Schiemann reaction)

Rocket propellants with fluorine compounds

Section 4. Fluorine Compounds

Selective anodic fluorination compounds

Some physical properties of organic fluorine compounds

Strontium fluorinated compounds

Sulfur Nitrogen Fluorine Compounds

Sulfur fluorine compounds

Sulfur fluorine-chlorine compounds

Sulfur fluorine-containing compounds

Sulfur trioxide reaction with fluorinated compounds

Synthetic fluorinated compounds

Tellurium compounds, fluorination

Thermochemistry of inorganic fluorine compounds

Trichloro FLUORINECOMPOUNDS,ORGANIC - FLUORINATED ALIPHATIC COMPOUNDS] (Vol

Tris FLUORINECOMPOUNDS,ORGANIC - FLUORINATED AROMATIC COMPOUNDS]

Unsaturated compounds, fluorination

Unsaturated fluorinated compounds, reduction

Vinyltin compounds fluorination

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