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Carbon/carbonic

Carbon-Carbon. Carbon-carbon composites consist of a carbon fiber substrate, either in the form of woven fabric or random felt, and a carbon matrix. The matrix is produced by the pyrolysis of a polymer,... [Pg.479]

Hydrogenolysis is analogous to hydrolysis and ammonolysis, which involve the cleavage of a bond induced by the action of water and ammonia, respectively. Chemical bonds that are broken by hydrogenolysis reactions include carbon—carbon, carbon—oxygen, carbon—sulfur, and carbon—nitrogen bonds. An example of hydrogenolysis is the hydrodealkylation of toluene to form benzene and methane ... [Pg.206]

Thermal Properties. Thermodynamic stabiUty of the chemical bonds comprising the PPS backbone is quite high. The bond dissociation energies (at 25°C) for the carbon—carbon, carbon—hydrogen, and carbon—sulfur bonds found in PPS are as follows C—C, 477 kj/mol (114 kcal/mol) ... [Pg.445]

Nitriles. Nitriles can be prepared by a number of methods, including ( /) the reaction of alkyl haHdes with alkaH metal cyanides, (2) addition of hydrogen cyanide to a carbon—carbon, carbon—oxygen, or carbon—nitrogen multiple bond, (2) reaction of hydrogen cyanide with a carboxyHc acid over a dehydration catalyst, and (4) ammoxidation of hydrocarbons containing an activated methyl group. For reviews on the preparation of nitriles see references 14 and 15. [Pg.258]

Vitahium FHS ahoy is a cobalt—chromium—molybdenum ahoy having a high modulus of elasticity. This ahoy is also a preferred material. When combiaed with a properly designed stem, the properties of this ahoy provide protection for the cement mantle by decreasing proximal cement stress. This ahoy also exhibits high yields and tensile strength, is corrosion resistant, and biocompatible. Composites used ia orthopedics include carbon—carbon, carbon—epoxy, hydroxyapatite, ceramics, etc. [Pg.190]

The Diels-Alder cycloaddition is the best-known organic reaction that is widely used to construct, in a regio- and stereo-controlled way, a six-membered ring with up to four stereogenic centers. With the potential of forming carbon-carbon, carbon-heteroatom and heteroatom-heteroatom bonds, the reaction is a versatile synthetic tool for constructing simple and complex molecules [1], Scheme 1.1 illustrates two examples the synthesis of a small molecule such as the tricyclic compound 1 by intermolecular Diels-Alder reaction [2] and the construction of a complex compound, like 2, which is the key intermediate in the synthesis of (-)chlorothricolide 3, by a combination of an intermolecular and an intramolecular Diels-Alder cycloaddition [3]. [Pg.1]

The Diels-Alder reaction is the most widely used carbon-carbon, carbon-heteroatom and heteroatom-heteroatom bond-forming reaction for the construction of six-membered rings therefore it is not surprising that many methods have been used to accelerate the reaction and to improve its selectivity. Chapters 2, 3 and 5 illustrate the effects of temperature, Lewis acids and pressure, respectively this chapter provides a survey of other physical and chemical methods by which the Diels-Alder reaction can be profitably carried out. [Pg.143]

Fibres, nature Glass Carbon Carbon Carbon... [Pg.816]

According to the type of unsaturated bond to be lithiated, carbon-carbon, carbon-oxygen and carbon-nitrogen bonds will be considered. [Pg.736]

Carbonate carbon carbon content present in the carbonate in the mineral matter which is noncombustible (ASTM D-6316). [Pg.197]

Organic compounds An organic compound is any member of a large class of chemical compounds whose molecules contain carbon carbonates, carbon oxides, and cyanides. Most organic compounds today are artificially produced chemical industry, waste combustion, and different fuels. [Pg.10]

Stereoregularity. The addition of monomer fixes the tacticity of the previous monomer unit. Syndiotactic structure has the adjacent chlorine atoms oriented to opposite sides of the carbon—carbon—carbon plane, whereas isotactic structure has the adjacent chlorine atoms oriented to same side of the carbon—carbon—carbon plane. The potential energy for syndiotactic conformation is 4.2—8.4 kj/mol (1—2 kcal/mol) lower than for isotactic conformation (74,75). Thus the ratio of propagation rates for syndiotactic to isotactic, kjk, must increase with decreasing temperature. Consequently, with decreasing polymerization temperature, the degree of syndiotacticity in PVC should increase. Measured amounts of syndiotacticity are illustrated in Figure 8... [Pg.500]


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