Organic fluorine compounds pyrolysis

Thermal Plasma Pyrolysis of Organic Fluorine Compounds... 

Pyrolysis of Organic Fluorine Compounds in Thermal Plasma of Nitrogen Synthesis of Nitrogen-Containing Fluorocarbons... 

In addition to metabolism, chemical reactions, such as pyrolysis, can convert a nontoxic fluorine compounds to a toxic one. Pyrolysis of some organic fluorine compounds can produce perfluoroisobutylene, (CF3)2C==CF2, probably one of the most highly toxic fluorocompounds known [3]. 

Like the hydrocarbon analogues, highly fluorinated azo compounds break down on photolysis and pyrolysis to give nitrogen and corresponding organic radicals [315] (Figure 8.119). 

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