Factors influencing control

D. V. Doane, in M. E. Finn, ed.. Factors Influencing Machining and Their Controls, Proceedings of an International Conference and Workshop, ASM International, 1990. 

Hydrolysis of TEOS in various solvents is such that for a particular system increases directiy with the concentration of H" or H O" in acidic media and with the concentration of OH in basic media. The dominant factor in controlling the hydrolysis rate is pH (21). However, the nature of the acid plays an important role, so that a small addition of HCl induces a 1500-fold increase in whereas acetic acid has Httie effect. Hydrolysis is also temperature-dependent. The reaction rate increases 10-fold when the temperature is varied from 20 to 45°C. Nmr experiments show that varies in different solvents as foUows acetonitrile > methanol > dimethylformamide > dioxane > formamide, where the k in acetonitrile is about 20 times larger than the k in formamide. The nature of the alkoxy groups on the siHcon atom also influences the rate constant. The longer and the bulkier the alkoxide group, the lower the (3). 

The influence of the composition of asphalt has been recognized, for many years, as being an important factor in controlling the performance of such materials. Furthermore, rheological properties have always been associated with composition but, in order to utilize compositional data effectively, more definitive correlations between composition and properties are needed (46—48). 

Cost-effective control of dust problems arising from bulk materials handling requires an initial examination of the overall handling operations. Factors influencing dust generation and dispersion must be understood in order to achieve a proper design. 

In the selection of control equipment, the most important waste-gas characteristics are volumetric flow rate, concentration and composition of organic compounds in the waste-gas, waste-gas temperature and humidity, and rbe content of particulate matter, chlorinated hydrocarbons, and toxic pollutants. Other factors influencing the equipment selection are the required removal efficiency, recovery requirements, investment and operating costs, ease of installation, and considerations of operation and maintenance. The selection of a suitable control method is based on the fundamental selection criteria presented as well as the special characteristics of the project. 

The positions of substitution, orientation, and configuration of the stable form are determined by a balance between opposing steric and dipole ef-fects. There is less agreement regarding the factors influencing kinetically controlled reaction (see below). Essentially neutral conditions, such as provided by an acetate or pyridine buffer, are required to avoid isomerization. Frequently, however, bromination will not proceed under these conditions, and a compromise has been used in which a small amount of acid is added to start and maintain reaction, while the accumulation of hydrogen bromide is prevented by adding exactly one equivalent of acetate... 

Non-Newtonian fluids vary significantly in their properties that control flow and pressure loss during flow from the properties of Newtonian fluids. The key factors influencing non-Newtonian fluids are their shear thinning or thickening characteristics and time dependency of viscosity on the stress in the fluid. 

Corrosion Theory 1259. Forms of Corrosion Attack 1268. Factors Influencing Corrosion Rate 1292. Corrodents in Drilling Fluids 1300. Corrosion Monitoring and Equipment Inspections 1312. Corrosion Control 1323. Recommended Practices 1340. 

In Ugi four-component reactions (for mechanism, see Section 1.4.4.1.) all four components may potentially serve as the stereodifferentiating tool65. However, neither the isocyanide component nor the carboxylic acid have pronounced effects on the overall stereodiscrimination60 66. As a consequence, the factors influencing the stereochemical course of Ugi reactions arc similar to those in Strecker syntheses. The use of chiral aldehydes is commonly found in substrate-controlled syntheses whereas the asymmetric synthesis of new enantiomerically pure compounds via Ugi s method is restricted to the application of optically active amines as the chiral auxiliary group. 

The starburst point occurs at a well-defined limit for each dendrimer system, and its occurrence is dependent mainly on (a) the functionality of the core, (b) the multiplicity of the branches and (c) the branch length. However, the volume of the core itself, and the length of the monomer branches also have an influence. The end groups may occupy the outer surface of the dendrimer, or the branches may fold inwards, thus distributing the end-groups within the dendrimer. The factors that control this behaviour of the branches are not fully understood, but include the nature of the solvent and the detailed chemistry of the dendrimer branches. 

FIGURE 7.1.1 Typical technological and managerial factors influencing performance of quality control activities... 

Synthetic-based muds are mineral oil muds in which the oil phase has been replaced with a synthetic fluid, such as ether, ester, PAO, or linear alkylbenzene, and are available from major mud companies. The mud selection process is based on the mud s technical performance, environmental impact, and financial impact. Synthetic muds are expensive. Two factors influence the direct cost unit or per-barrel cost and mud losses. Synthetic muds are the technical equivalent of oil-based muds when drilling intermediate hole sections. They are technically superior to all water-based systems when drilling reactive shales in directional wells. However, with efficient solids-control equipment, optimized drilling, and good housekeeping practices, the cost of the synthetic mud can be brought to a level comparable with oil-based mud [1308]. 

Important factors influencing the analyte volatilisation process are related to diffusion, porosity, and surface area (for solids). To obtain reproducible results it is necessary to control storage temperature and time strictly. The temperature of the sample is very important because of the specific boiling points of the various analytes. The partition coefficient, K, at equilibrium, is... 

D. Bodmer, T. Kissel, and E. Traechslin, Factors influencing the release of peptides and proteins from biodegradable parenteral depot systems, J. Controlled Release, 21, 129 (1992). 

Addiction A primary chronic neurobiologic disease, with genetic, psychosocial, and environmental factors influencing its development and manifestations. It is characterized by behaviors that include one or more of the following 5Cs chronicity, impaired control over drug use, compulsive use, continued use despite harm, and craving. 

The primary pathway of Hg to aquatic systems is considered to be atmospheric transport and subsequent deposition, which has caused an accumulation of Hg in watershed soils (Mason, et al., 1994). Recent work has shown that watershed disturbance such as clear cutting results in the increased export of Hg from the watershed to aquatic systems (Porvari, et al., 2003) and others have found agricultural and urbanized land use to be important factors influencing Hg export (Fitzgibbon, et al., 2008 Mason Sullivan, 1998). Thus the recovery of aquatic systems from anthropogenic Hg may depend on watershed characteristics which will differ among watersheds. Therefore we compared time to recovery to watershed attributes (e.g., %urban, susceptibility to erosion, watershed to lake area ratio, etc...) to test the hypothesis that the rate of recovery from Hg enrichment is influenced by watershed controlled pathways and stressors. 

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