Duplex material

Some applications may require alloy grades higher than the Duplex materials given in Table H.2. 

Super Duplex material grades with pitting resistance equivalency (PRE) values greater than 40 may be necessary. 

S] Gardand, P. O., Steinsmo, U., Dmgli, J. M., and Solheim, P., High, Alloyed Stainless Steels for Chlorinated Seawater Applications A Summary of Test Results for Eleven Austenitic and Duplex Materials, Paper 646 NACE CORROSION/93, NACE Nashville, TN, 1993. 

Duplex stainless steels (ca 4% nickel, 23% chrome) have been identified as having potential appHcation to nitric acid service (75). Because they have a lower nickel and higher chromium content than typical austenitic steels, they provide the ductabdity of austenitic SS and the stress—corrosion cracking resistance of ferritic SS. The higher strength and corrosion resistance of duplex steel offer potential cost advantages as a material of constmction for absorption columns (see CORROSION AND CORROSION CONTROL). 

Materials of Construction and Operational Stress. Before a centrifugal separation device is chosen, the corrosive characteristics of the Hquid and soHds as weU as the cleaning and saniti2ing solutions must be deterrnined. A wide variety of materials may be used. Most centrifuges are austenitic stainless steels however, many are made of ordinary steel, mbber or plastic coated steel. Monel, HasteUoy, titanium, duplex stainless steel, and others. The solvents present and of course the temperature environment must be considered in elastomers and plastics, including composites. 

It has been shown (16) that a stable foam possesses both a high surface dilatational viscosity and elasticity. In principle, defoamers should reduce these properties. Ideally a spread duplex film, one thick enough to have two definite surfaces enclosing a bulk phase, should eliminate dilatational effects because the surface tension of an iasoluble, one-component layer does not depend on its thickness. This effect has been verified (17). SiUcone antifoams reduce both the surface dilatational elasticity and viscosity of cmde oils as iUustrated ia Table 2 (17). The PDMS materials are Dow Coming Ltd. polydimethylsiloxane fluids, SK 3556 is a Th. Goldschmidt Ltd. siUcone oil, and FC 740 is a 3M Co. Ltd. fluorocarbon profoaming surfactant. 

The relatively long service life of the duplex tubes suggested that similar tubes be used for retubing. Because of supplier delays in securing duplex tubing, however, alternative materials, including admiralty brass, were considered. 

Plain tubes (either as solid wall or duplex) are available in carbon steel, carbon alloy steels, stainless steels, copper, brass and alloys, cupro-nickel, nickel, monel, tantalum, carbon, glass, and other special materials. Usually there is no great problem in selecting an available tube material. However, when its assembly into the tubesheet along with the resulting fabrication problems are considered, the selection of the tube alone is only part of a coordinated design. Plain-tube mechanical data and dimensions are given in Tables 10-3 and 10-4. 

If conditions are such as to require a duplex tube, it is quite likely that a plain end detail for the tube will not be satisfactory. Grooved or serrated joints are recommended for this type of tube, and the ends should be flared or beaded. Table 10-8 gives recommended flare or bell radii for copper-based alloys. Also see Table 10-8A. In service where galvanic corrosion or other corrosive action may take place on the outside material used in the tube, a ferrule of inside tube... 

Steel is the most common constructional material, and is used wherever corrosion rates are acceptable and product contamination by iron pick-up is not important. For processes at low or high pH, where iron pick-up must be avoided or where corrosive species such as dissolved gases are present, stainless steels are often employed. Stainless steels suffer various forms of corrosion, as described in Section 53.5.2. As the corrosivity of the environment increases, the more alloyed grades of stainless steel can be selected. At temperatures in excess of 60°C, in the presence of chloride ions, stress corrosion cracking presents the most serious threat to austenitic stainless steels. Duplex stainless steels, ferritic stainless steels and nickel alloys are very resistant to this form of attack. For more corrosive environments, titanium and ultimately nickel-molybdenum alloys are used. 

Times to failure for various stainless steels tested in MgClj have been shown to increase with increasing proportions of martensite present Perhaps the role of martensite under anodic dissolution conditions is comparable to that of ferrite in duplex stainless steels where the enhanced dissolution of one phase prevents crack initiation in the other. There is, of course, another aspect of martensitic transformation that should be mentioned, i.e. the transformation of austenite to martensite either in the bulk material or at a growing crack tip that can give increased susceptibility to... 

High-alloy pipeline steels (e.g. austenitic-ferritic or duplex) have been used where the product stream demands materials with better corrosion resistance than carbon steel. In practice the external corrosion resistance of these materials cannot be guaranteed, so cathodic protection is employed to protect areas which may be subject to corrosion. 

The high resistivity of Inconel 600 (11 OjtI 0 8 Dm) demanded the application of this material as a composite with a central aluminum core. The aluminum was totally enclosed in Inconel 600 so that the Inconel was only exposed to sulfur and polysulfides. In a test over more than three years, cells with a composite current collector of this kind suffered from a high capacity decline. Post-test analysis showed that Inconel sustained polysulfide attack with the formation of a duplex nickel and chromium sulfide layer on the current collector surface. 

The difficulty of obtaining pure / "-material for the electrolyte has been tackled in many production processes worked out in the past. Unless precautions are taken, sintering of a -alumina-derived / "-alumina compositions invariably results in the duplex microstructure and a low-strength ceramic. Therefore a balance has to be struck between conductivity and strength. The problem arises because the conversion from —alumina to / " -alumina is slow... 

The duplex range of stainless steels can be readily cast, wrought and machined. Problems can occur in welding, due to the need to keep the correct balance of ferrite and austenite in the weld area, but this can be overcome using the correct welding materials and procedures. 

The analogy drawn between -stacked solids and duplex DNA has provided a useful starting point for experiments to probe and understand DNA-medi-ated CT. As with the -stacked solids, the DNA base pair array can provide an effective medium for long range CT. Mechanistically, however, the differences between DNA and these solid state materials may be even more important to consider. Duplex DNA, as a molecular -stacked structure, undergoes dynamical motion in solution. The time-dependent and sequence-dependent structures that arise serve to modulate and gate CT. Indeed in probing DNA CT as a function of sequence and sequence-dependent structure, we may better understand mechanistically how CT proceeds and how DNA CT may be utilized. 

Nucleic acids, DNA and RNA, are attractive biopolymers that can be used for biomedical applications [175,176], nanostructure fabrication [177,178], computing [179,180], and materials for electron-conduction [181,182]. Immobilization of DNA and RNA in well-defined nanostructures would be one of the most unique subjects in current nanotechnology. Unfortunately, a silica surface cannot usually adsorb duplex DNA in aqueous solution due to the electrostatic repulsion between the silica surface and polyanionic DNA. However, Fujiwara et al. recently found that duplex DNA in protonated phosphoric acid form can adsorb on mesoporous silicates, even in low-salt aqueous solution [183]. The DNA adsorption behavior depended much on the pore size of the mesoporous silica. Plausible models of DNA accommodation in mesopore silica channels are depicted in Figure 4.20. Inclusion of duplex DNA in mesoporous silicates with larger pores, around 3.8 nm diameter, would be accompanied by the formation of four water monolayers on the silica surface of the mesoporous inner channel (Figure 4.20A), where sufficient quantities of Si—OH groups remained after solvent extraction of the template (not by calcination). 

The metallurgy selected for construction of a firewater pump is dependent on the properties of the water source to be used. For fresh water sources (i.e., public water mains), cast iron is normally adequate although bronze internals may be optional. Brackish or sea water utilization will require the use of highly corrosion resistance materials and possibly coatings. Typically specified metals include alloy bronze, monnel, ni-resistant, or duplex stainless steels sometime combined with a corrosion resistant paint or specialized coating. 

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