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Crack initiation prevention

Times to failure for various stainless steels tested in MgClj have been shown to increase with increasing proportions of martensite present Perhaps the role of martensite under anodic dissolution conditions is comparable to that of ferrite in duplex stainless steels where the enhanced dissolution of one phase prevents crack initiation in the other. There is, of course, another aspect of martensitic transformation that should be mentioned, i.e. the transformation of austenite to martensite either in the bulk material or at a growing crack tip that can give increased susceptibility to... [Pg.1217]

In neutral solutions the application of cathodic polarisation prevents crack initiation and this could be taken to indicate that hydrogen embrittlement is not the operative mechanism, since the discharge and entry of hydrogen might be expected to fracture the specimen more readily. The beneficial effect of cathodic polarisation has been interpreted , however, to result from more rapid film repair in the alkaline catholyte generated by the cathode reaction. The film serves as a barrier to rapid hydrogen entry. Consistent with this is the observation that in an environment of low pH (e.g. 10 N HCl) where film formation would not be expected, cathodic polarisation has no effect upon crack propagation. [Pg.1263]

When chemicals are weak solvents for polystyrene, stress cracks are formed in the products. Chemical resistances to practical chemicals are compared in Table 18.5. HIPS-SPS blend exhibits better resistance to chemicals which are used in the kitchen and bathroom. In HIPS/SPS blend, SPS may work to prevent the formation of crazes and their propagation to cracks initiated from contact with chemicals. [Pg.407]

Different adhesives were checked and "Bison" has been found the strongest. Nevertheless in testing the tabbed 3D carbon-fiber specimens, the separation of the tabs from the specimen surface before the crack initiation was observed in all initial experiments. To prevent this, side-grooved specimens were used. The 1 mm wide side grooves were machined by milling cutter. The depth of grooves equal to 4 mm was chosen to cut the side lines of transverse yams leaving intact only 2 transverse yarn lines. [Pg.517]

Stress corrosion cracking is a form of localized corrosion, where the simultaneous presence of tensile stresses and a specific corrosive environment prodnces metal cracks [157, 168]. Stress corrosion cracking generally occnrs only in alloys (e.g., Cn-Zn, Cu-Al, Cu-Si, austenitic stainless steels, titaninm alloys, and zirconinm alloys) and only when the alloy is exposed to a specific environment (e.g., brass in ammonia or a titaninm alloy in chloride solutions). Removal of either the stress on the metal (which must have a surface tensile component) or the corrosive environment will prevent crack initiation or cause the arrest of cracks that have already propagated. Stress corrosion cracking often occurs where the protective passive film breaks down. The continual plastic deformation of the metal at the tip of the crack prevents repassivation of the metal surface and allows for continued localized metal corrosion. [Pg.1815]

What is the nature of brittleness The chains of amorphous polymers are entangled. At low temperatures most degrees of freedom are frozen the chains, therefore, become stiff. This is the situation where steric hindrance prevents chain movement relative to one another. When an external load is applied, stress concentration occurs at some points. If no plastic flow is possible to equalize the stress distribution within the material, crack initiation and brittle fracture may occur. [Pg.33]

A fatigue assessment is conducted in the design phase in order to prevent any crack initiation. This assessment is made by using the cyclic stresses and number of cycles given in the RPVI design report. These values are determined using the estimates of the type and number of transients provided by the NSSS vendors. [Pg.102]

The molecular weight of the reactive polymers, thus of the constitutive blocks of the compatibilizer, is also critical for efficient entanglements with the phases to be compa-tibilized. Indeed, good interfacial adhesion is essential for stress transfer from one phase to the other one to be efficient and for cracks initiated at the interface to be prevented from growth until catastrophic failure occurs. Kramer et al. studied the fracture mechanism of the polystyrene/poly(2-vinylpyridine) interface modified by the parent di-block copolymer. They found that the minimum degree of polymerization of PVP for entanglement (Npvp) was 255, below which the PVP block was pulled out in slow crack opening experiment [93, 94]. [Pg.96]

Hardening is therefore of paramount importance in the radiation embrittlement of a metal. It exhibits plastic relaxation at the stage of crack initiation and prevents the crack from blunting during the growth process. The shift in Tt upon increasing the yield stress is also implied by the Ioffe scheme. [Pg.60]

This ability to control crack initiation and crack growth is utilised in fuselage construction to resist catastrophic decompression, which could result from a crack initiated by the cyclic pressurisation loads, which are applied during flight. The bonded doublers have the ability to turn the tip of any crack which might have been formed hence preventing catastrophic crack growth which can and, in the case of the de Havilland Comet 1, has led to uncontrolled decompression. [Pg.324]

Brittle fracture is also called a cleavage fracture. The reason is that the fractured surface looks like a cleaved surface. Fracture is the result of two processes crack initiation and its propagation. Initially, a microcrack is produced, and it propagates xmtil a time is reached when there is a sudden fracture. To prevent this failure, therefore, there is a need to control either one of the processes, or both. [Pg.97]


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