Diphenyl methyl phosphate

Diphenylethynylanthracene, 13 Af,Af-Diphenylformamide, 223 Diphenylguanidine, 143, 144 Diphenyl methyl phosphate, 223... 

Ammonium thiocyanate Anisoyl chloride Benzhydry bromide (diphenyl methyl bromide) Benzoyl chloride Benzyl bromide Benzyl chloride Benzyl chloroformate (benzyl chlorocarbonate) Butyl acid phosphate Chloracetyl chloride... 

The effectiveness is particularly dependent on the content of phosphor. Whereas pentaerythritol diphenyl diphosphate bums even at a loading of 35%, pentaerythritol bis(phenyl phosphate) reaches a V-0 rating at this loading, pentaerythritol bis(methyl phosphate) needs only a loading of 15% to reach a V-0 rating (69). 

O-phenyl-0-methyl phosphate (9) [16] (Scheme 1) while neither 8 nor 0,0-diphenyl phosphate undergo methanolysis under applied conditions. 

K. D. Collins (28), whereby diphenyl (carbomethoxymethyl) phosphate was prepared from the reaction of diphenyl phosphorochlorldate with methyl glycolate in the presence of a tertiary amine, such as pyridine or lutldlne. This is shown in Eq. 3. 

Reactions of Phosphoric Acids and their Derivatives. - The rearrangement of [(trimethylsilyl)methyl] phosphates to their ethyldimethylsilyl isomers is already known the mechanism of the process has now been examined in more detail and is thought to involve attack by phosphoryl oxygen at the silicon atom with migration of an alkyl group as indicated in Scheme 2. Diphenyl... 

DPIOP. See Diphenyl isooctyl phosphite DPM DPMG. See PPG-2 methyl ether DPOF. See Diphenyl octyl phosphate DPP. SeeBisphenolA Dracylic acid. See Benzoic acid... 

Reofos 1884 Triaryl phosphate plasticizer, textile coalings Diphenyl oryi phosphate Plasihal DOP Sandcizei 141 Ucon 50-HB-55 Ucon 50-HB-100 Ucon 50-HB-170 Ucon 50-HB-260 Ucon 50-HB-400 Ucon 50-HB-660 Ucon 50-HB-2000 Ucon 50-HB-3520 Ucon 50-HB-5100 Ucon 75-H-450 Ucon LB-65 Ucon LB-135 Ucon LB-165 Ucon LB-2 5 Ucon LB-385 Ucon LB-525 Ucon LB-625 Ucon LB-1145 Ucon LB-1715 Ucon LB-3000 plasticizer, textile finishes Polymyl methyl etter plasticizer, textured decorative coatings HostapurOSB... 

Tetrabromobisphenol A di-2-hydroxyethyl ether Tetradecabromodiphenoxybenzene Tetrakis (2-chloroethyl) ethylene diphosphate Tris (2,3-dichloropropyl) phosphate flame retardant, EPS Tribromophenyl allyl ether flame retardant, ethyl cellulose Diphenyl octyl phosphate flame retardant, ethylene copolymers Ethylenebis (tetrabromophthalimide) flame retardant, expandable PS Dibromoethyidibromocyclohexane Tetrabromobisphenol A bis (allyl ether) Tetrabromocyclooctane flame retardant, extruded PS Tetrabromocyclooctane flame retardant, fabrics Antimony pentoxide Methylphosphonic acid, (5-ethyl-2-methyl-2-oxido-1,3,2-dioxaphosphorinan-5-yl) methyl methyl ester flame retardant, fibers Antimony pentoxide Tetrabromoethane flame retardant, filament winding Epoxy resin, brominated flame retardant, film Tetrabromobis (2-ethylhexyl) phthalate flame retardant, fire-retardant material Chlorinated paraffins (C12, 60% chlorine) Chlorinated paraffins (C23, 43% chlorine) flame retardant, flexible PU foam bedding Tetrakis (2-chloroethyl) ethylene diphosphate flame retardant, flexible PU foam furniture Tetrakis (2-chloroethyl) ethylene diphosphate flame retardant, flexible PU foam transportation Tetrakis (2-chloroethyl) ethylene diphosphate flame retardant, flexible PU foams furniture, automobile seating... 

Butyl myristate Methyl cocoate Oleyl alcohol PEG-300 oleate PEG-300 stearate Propylene glycol myristate plasticizer, delayed tack latex 1,4-Cyclohexanedimethanol dibenzoate plasticizer, dental adhesives n-Butyl phthalyl-n-butyl glycolate plasticizer, dental compounds Carnauba (Copemica cerifera) wax plasticizer, dental impression compounds Japan (Rhus succedanea) wax plasticizer, deodorants Hexyldecyl benzoate plasticizer, depilatories Oxidized beeswax plasticizer, detergents PPG-20 lanolin alcohol ether plasticizer, dip parts Diphenyl octyl phosphate plasticizer, dopes Di butyl tartrate plasticizer, dry cleaning PEG-8 cocoate PEG-20 hydrogenated castor oil PEG-60 hydrogenated tallowate PEG-12 ricinoleate PEG-2 stearate PEG-2 tallowate plasticizer, elastomers Butyl acetyl ricinoleate Butyl cyclohexyl phthalate Dibutyl phthalate Dibutyl tartrate n-Dioctyl phthalate... 

Epoxidized linseed oil Epoxidized soybean oil Tris (2,3-dichloropropyl) phosphate plasticizer, ester gums Methyl abietate plasticizer, ethylcellulose Acetyl triethyl citrate Dicyclohexyl phthalate Diisooctyl sebacate Diphenyl octyl phosphate... 

Acetylated hydrogenated lard glyceride plasticizer, textile back coatings Triaryl phosphate plasticizer, textile coatings Diphenyl octyl phosphate plasticizer, textile finishes Polyvinyl methyl ether plasticizer, textile finishing Oleyl alcohol... 

The Miller group was the first to report catalytic asymmetric phosphorylation of alcohols, in 2001 [81]. They reported that D-myo-inositol-l-phosphate 82 could be prepared with high levels of enantiomeric purity by the ASD of 2,4,6-tribenzyl-myo-inositol (81) using diphenyl(chloro)phosphate and triethylamine in toluene at 0°C catalyzed by 2mol% of pentapeptide 79, which contains an N-terminal TT-methyl histidine residue as the nucleophile (Scheme 41.29). 

Stereochemistry. - There has been a far infra-red spectroscopic study of ethyl phosphine,130 and in combination with X-ray fluorescence, further work completed on the conformational analysis of dialkylphenyl phosphines.131 The influence of water on the conformational equilibria of trimethyl phosphate has received attention.132 There has been a low temperature solid state and matrix isolation study of methyl phosphorodichi oridate,133 and a conformational study of polymorphic modifications of diphenyl-phosphinyl acetic acid hydrazide. 34... 

Reaction of both methyl phenyl sulphone and diphenyl sulphone with potasium in liquid ammonia [24] leads to the formation of a dianion, which cleaves to give CfiHs, isolated as benzene. The initial electron transfer cannot be dissociative, as was the case for diethyl phenyl phosphate (p. 163), since the phenyl c-radical is not detected. The radical-anions from these sulphones have sufficiently long lifetime in liquid annmonia to allow reaction with a further electron. 

TTP = Tritolyl phosphate TCXP = Tritolyl(xylenyl) phosphate TXP = Trixylenyl phosphate TDP = Tolyl diphenyl phosphate TEPP = Tri(ethylphenyl) phosphate TPP = Triphenyl phosphate TBC = Tributyl citrate BAR = Butyl acetyl ricinoleate MAR = Methyl acetyl ricinoleate... 

When methyl 4,6-benzylidene-2-desoxy-a-D-galactoside (LXXXVI)126 was treated with phosphorus oxychloride in pyridine at —40°, followed by barium hydroxide,236 it gave amorphous barium methyl 4,6-benzyli-dene-2-desoxy-a-D-galactoside 3-phosphate (LXXXVII). If diphenyl-phosphoryl chloride [diphenylchlorophosphonate, (PhO)2POCl]236 240 in pyridine was used as the phosphorylating agent, then crystalline (methyl... 

Wu, J.L., Fu, Y.X., Wang, W.Q. 1984. Energy transfer kinetics in irradiated tributyl phosphate to diphenyl sulfoxide and methyl isobutyl ketone. Radiat. Phys. Chem. 23(5) 601-606. 

Potentiometry was used to investigate the speciation of La(ni) in methanolic methox-ide solutions, with and without diphenyl phosphate or methyl 4-nitrophenyl phosphate (98), substrates which are very efficiently methanolysed by such solutions.2 La(III)-catalysed methanolysis is thus regarded as a good model for the metal-containing RNAses and DNases which cleave phosphate diester linkages. In the high [La(III)] domain, the data fitted, as one possibility among several, a spontaneous decomposition... 

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