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Diffusion studies reactor system

If a fluid is placed between two concentric cylinders, and the inner cylinder rotated, a complex fluid dynamical motion known as Taylor-Couette flow is established. Mass transport is then by exchange between eddy vortices which can, under some conditions, be imagmed as a substantially enlranced diflfiisivity (typically with effective diflfiision coefficients several orders of magnitude above molecular difhision coefficients) that can be altered by varying the rotation rate, and with all species having the same diffusivity. Studies of the BZ and CIMA/CDIMA systems in such a Couette reactor [45] have revealed bifiircation tlirough a complex sequence of front patterns, see figure A3.14.16. [Pg.1112]

In this paper we will first describe a fast-response infrared reactor system which is capable of operating at high temperatures and pressures. We will discuss the reactor cell, the feed system which allows concentration step changes or cycling, and the modifications necessary for converting a commercial infrared spectrophotometer to a high-speed instrument. This modified infrared spectroscopic reactor system was then used to study the dynamics of CO adsorption and desorption over a Pt-alumina catalyst at 723 K (450°C). The measured step responses were analyzed using a transient model which accounts for the kinetics of CO adsorption and desorption, extra- and intrapellet diffusion resistances, surface accumulation of CO, and the dynamics of the infrared cell. Finally, we will briefly discuss some of the transient response (i.e., step and cycled) characteristics of the catalyst under reaction conditions (i.e.,... [Pg.80]

Permselective Reactor Model. This model was developed to size an experimental reactor system. Even though, some of our initial assun tions are being refined in our continuing efforts, some in ortant conclusions can be drawn from our early work. The first approach used was to idealize the permselectivity, and assume that only hydrogen diffuses through the membrane. This assun tion cannot be justified for the characteristics of the membranes studied experimentally. It does, however, permit one to place an upper limit on the expected performance of the system. [Pg.208]

This is a different kind of heterogeneous reaction—a gas-solid noncatalytic one. Let us examine the process at initial conditions (t 0), so that there has been no opportunity for a layer of UF4.(5) to be formed around the UO pellet The process is much like that for gas-solid catalytic reactions. Hydrogen fluoride gas is transferred from the bulk gas to the surface of the UO2 pellets and reacts at the pellet-gas interface, and H2O diffuses out into the bulk gas. If the pellet is nonporous, all the reaction occurs at the outer surface of the UO2 pellet, and only an external transport process is possible. Costa studied this system by suspending spherical pellets 2 cm in diameter in a stirred-tank reactor. In one run, at a bulk-gas temperature of 377°C, the surface temperature was 462°C and the observed rate was — Tuo = 6.9 x 10 mole U02/(sec) (cm reaction surface). At these conditions the concentrations of... [Pg.278]

Figure 1. Flow diagram of reactor system for diffusion studies... Figure 1. Flow diagram of reactor system for diffusion studies...
A fundamental Issue In immobilized catalyst studies is the extent to which substrate transport influences the observed reaction rate. The issue can be resolved by making use of the mathematical formalism which has been developed for heterogeneously catalyzed reactions (13,14,15). This formalism will be presented below for both the batch reactor and the fixed-bed reactor systems. The treatment assumes that the concentration of substrate in the bulk phase is equal to the concentration immediately outside a polymer particle and that the substrate s diffusion coefficient is not a function of concentration or position in the particle. The polymer... [Pg.70]

Therefore, in FTS reaction system, there are a lot of factors, crossing several scales, including molecular reaction (element scale), internal and external diffusion (system scale), as well as type of reactor (system scale). And the combined effects of those factors significantly influence the product distribution. It is considered that the mesoscale study of FTS, which cross two or several scales, is the key point of controlling the product distribution in FTS reaction. [Pg.342]

Post et al. (1989) prepared a series of iron and cobalt-base catalysts. The studies were performed in a fixed-bed micro reactor system at temperatures in the range 473—523 K. Variation of catalyst particle size in the range 0.2-2.6 mm showed that the conversion of synthesis gas decreases considerably when the average particle size was increased. Under reaction conditions, the major part of the hydrocarbon product would be the liquid. The liquid would fill the pores of the catalyst so that transport of hydrogen and carbon monoxide to the reactive sites occurred by diffusion of these reactants through this Hquid medium inside the pores. The apparent effective diffusivity D, can be related to the molecular diffusivity, (H2) and solubility, H (H2) of hydrogen in the paraffinic liquid by Eq. (49) ... [Pg.374]

Finally, it should be mentioned that calculations of the diffusion length for systems with holes formed as interstices between random arrangements of solid bodies in point or line contact have also been carried out by Behrens and are reported in the reference paper. These results may be applied in the study of reactor core designs utilizing pebble beds and other similar configurations. [Pg.701]

A potential application of the WGS reaction carried out in an MR is represented by the tritium recovery process from tritiated water from breeder blanket fluids in fusion reactor systems. The hydrogen isotopes separation at low concentration in gaseous mixtures is a typical problem of the fusion reactor fuel cycle. In fact, the tritium produced in the breeder needs a proper extraction process to reach the required purity level. Yoshida et al. (1984) carried out experimental and theoretical studies of a catalytic reduction method which allows tritium recovery from tritiated water with a high conversion value (> 99.99%) at a relatively low temperature, while Hsu and Buxbaum (1986) studied a palladium-catalysed oxidative diffusion... [Pg.50]

The search for Turing patterns led to the introduction of several new types of chemical reactor for studying reaction-diffusion events in feedback systems. Coupled with huge advances in imaging and data analysis capabilities, it is now possible to make detailed quantitative measurements on complex spatiotemporal behaviour. A few of the reactor configurations of interest will be mentioned here. [Pg.1111]

Validation and Application. VaUdated CFD examples are emerging (30) as are examples of limitations and misappHcations (31). ReaUsm depends on the adequacy of the physical and chemical representations, the scale of resolution for the appHcation, numerical accuracy of the solution algorithms, and skills appHed in execution. Data are available on performance characteristics of industrial furnaces and gas turbines systems operating with turbulent diffusion flames have been studied for simple two-dimensional geometries and selected conditions (32). Turbulent diffusion flames are produced when fuel and air are injected separately into the reactor. Second-order and infinitely fast reactions coupled with mixing have been analyzed with the k—Z model to describe the macromixing process. [Pg.513]

Work in the area of simultaneous heat and mass transfer has centered on the solution of equations such as 1—18 for cases where the stmcture and properties of a soHd phase must also be considered, as in drying (qv) or adsorption (qv), or where a chemical reaction takes place. Drying simulation (45—47) and drying of foods (48,49) have been particularly active subjects. In the adsorption area the separation of multicomponent fluid mixtures is influenced by comparative rates of diffusion and by interface temperatures (50,51). In the area of reactor studies there has been much interest in monolithic and honeycomb catalytic reactions (52,53) (see Exhaust control, industrial). Eor these kinds of appHcations psychrometric charts for systems other than air—water would be useful. The constmction of such has been considered (54). [Pg.106]

Table 4-4 summarizes the ratings of the various reactors. The CFSTR and the recirculating transport reactor are the best choices because they are satisfactory in every category except for construction. The stirred batch and contained solid reactors are satisfactory if the catalyst under study does not decay. If the system is not limited by internal diffusion in the catalyst pellet, larger pellets could be used and the stirred-contained solids reactor is the better choice. However,... [Pg.252]

The solution procedure to this equation is the same as described for the temporal isothermal species equations described above. In addition, the associated temperature sensitivity equation can be simply obtained by taking the derivative of Eq. (2.87) with respect to each of the input parameters to the model. The governing equations for similar types of homogeneous reaction systems can be developed for constant volume systems, and stirred and plug flow reactors as described in Chapters 3 and 4 and elsewhere [31-37], The solution to homogeneous systems described by Eq. (2.81) and Eq. (2.87) are often used to study reaction mechanisms in the absence of mass diffusion. These equations (or very similar ones) can approximate the chemical kinetics in flow reactor and shock tube experiments, which are frequently used for developing hydrocarbon combustion reaction mechanisms. [Pg.68]

For premixed fuel-air systems, results are reported in various terms that can be related to a critical equivalence ratio at which the onset of some yellow flame luminosity is observed. Premixed combustion studies have been performed primarily with Bunsen-type flames [52, 53], flat flames [54], and stirred reactors [55, 56], The earliest work [57, 58] on diffusion flames dealt mainly with axisymmetric coflow (coannular) systems in which the smoke height or the volumetric or mass flow rate of the fuel at this height was used as the correlating parameter. The smoke height is considered to be a measure of the fuel s particulate formation and growth rates but is controlled by the soot particle bumup. The specific references to this early work and that mentioned in subsequent paragraphs can be found in Ref. [50],... [Pg.460]

However, in at least one intercomparison study using diffusion denuders and transition flow reactors, different results were obtained for some important atmospheric gases such as S02, HNO-, and H+, where the TFR values were about 30, 80, and 85% higher, respectively, than those from the denuder system (Sickles et al., 1989) the researchers attributed these differences to biases in the TFR measurements. [Pg.568]

In these types of laboratory reactor, the flow of the liquid is very carefully controlled so that, although the mass transfer step is coupled with the chemical reaction, the mass transfer characteristics can be disentangled from the reaction kinetics. For some reaction systems, absorption of the gas concerned may be studied as a purely physical mass transfer process in circumstances such that no reaction occurs. Thus, the rate of absorption of C02 in water, or in non-reactive electrolyte solutions, can be measured in the same laboratory contactor as that used when the absorption is accompanied by the reaction between C02 and OH ions from an NaOH solution. The experiments with purely physical absorption enable the diffusivity of the gas in the liquid phase DL to be calculated from the average rate of absorption per unit area of gas-liquid interface NA and the contact time te. As shown in Volume 1, Chapter 10, for the case where the incoming liquid contains none of the dissolved gas, the relationship is ... [Pg.224]


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See also in sourсe #XX -- [ Pg.177 ]




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