Density sodium hydroxide

The density of fluorobenzene is about 1 -025 at room temperature it is important to use the correct strength of sodium hydroxide solution in order to obtain a clear separation of the two layers. 

Benzoyl chloride test. (This is an alternative to the acetyl chloride test.) Place I ml. of the compound, 0 5 ml. of redistilled benzoyl chloride CAUTION in handling) and 2-5 ml. of 10 per cent, aqueous sodium hydroxide in a small test-tube, cork the tube and shake vigorously until the odour of benzoyl chloride has disappeared. Observe the odour, density and other obvious properties of the product. 

The distillate may contain volatile neutral compounds as well as volatile acids and phenols. Add a slight excess of 10-20 per cent, sodium hydroxide solution to this distillate and distil until the liquid passes over clear or has the density of pure water. The presence of a volatile, water-soluble neutral compound is detected by a periodic determination of the density (see Section XI,2) if the density is definitely less than unity, the presence of a neutral compound may be assumed. Keep this solution Si) for Step 4. 

Methylene iodide [75-11-6], CH2I2, also known as diio dome thane, mol wt 267.87, 94.76% I, mp 6.0°C, and bp 181°C, is a very heavy colorless Hquid. It has a density of 3.325 g/mL at 20°C and a refractive index of 1.7538 at 4°C. It darkens in contact with air, moisture, and light. Its solubiHty in water is 1.42 g/100 g H2O at 20°C it is soluble in alcohol, chloroform, ben2ene, and ether. Methylene iodide is prepared by reaction of sodium arsenite and iodoform with sodium hydroxide reaction of iodine, sodium ethoxide, and hydroiodic acid on iodoform the oxidation of iodoacetic acid with potassium persulfate and by reaction of potassium iodide and methylene chloride (124,125). Diiodoform is used for determining the density and refractive index of minerals. It is also used as a starting material in the manufacture of x-ray contrast media and other synthetic pharmaceuticals (qv). 

Other processes have been developed in which the impregnation is accompHshed in one or two steps the most promising is electro deposition directiy from nitrate solutions having pH controlled at 4—5. After electro deposition, the plaques are either cathodicaHy polarized in sodium hydroxide solution or electrochemically formed in sodium hydroxide to eliminate all traces of nitrate. The latter steps must proceed at low current densities to avoid blistering and shedding of the loaded plaques. 

Coppet(II) oxide [1317-38-0] CuO, is found in nature as the black triclinic tenorite [1317-92-6] or the cubic or tetrahedral paramelaconite [71276-37 ]. Commercially available copper(II) oxide is generally black and dense although a brown material of low bulk density can be prepared by decomposition of the carbonate or hydroxide at around 300°C, or by the hydrolysis of hot copper salt solutions with sodium hydroxide. The black product of commerce is most often prepared by evaporation of Cu(NH2)4C02 solutions (35) or by precipitation of copper(II) oxide from hot ammonia solutions by addition of sodium hydroxide. An extremely fine (10—20 nm) copper(II) oxide has been prepared for use as a precursor in superconductors (36). 

Sodium staimate and sodium hydroxide have been used, but at less efficiency, less conductivity, less current density, and more sludge. 

In a copper or iron kettle of 4-I. capacity is placed a solution of 200 g. of d-tartaric acid and 700 g. of sodium hydroxide in 1400 cc. of water. A 12-I. flask through which cold water is run is placed in the mouth of the kettle in order to prevent loss of water vapor, and the mixture is boiled gently over an open flame for four hours. The solution is now transferred to a 12-I. flask or crock and partially neutralized with 1400 cc. of commercial hydrochloric acid (density 1.19). To the still alkaline solution is now added just enough sodium sulfide to precipitate all the iron or copper which has been dissolved from the kettle (Note i). The filtered solution is then just acidified with hydrochloric acid, boiled to expel all hydrogen sulfide, and made very faintly alkaline to phenolphthalein with sodium hydroxide solution. To the hot solution is then added a concentrated solution of 300 g. of anhydrous calcium chloride which causes an immediate precipitation of calcium tff-tartrate and mesotartrate. 

A 0.61 N solution (90 cc) of 1-chloro-2-methyl-3-dimethylaminopropane in xylene is then added over 50 minutes and heating with reflux is continued for 20 hours. After cooling, the mixture is treated with water (40 cc) and N methanesulfonic acid (70 cc). The aqueous layer is washed with ether, treated with aqueous sodium hydroxide (density = 1.33 ... 

Similar curves determined in 50 Vo sodium hydroxide solution at 60°C show (Fig. 3.46) that the austenitic irons exhibit more noble active dissolution and also lower current densities in the active and passive regions than the ferritic irons the current densities in both regions decrease markedly with increasing nickel content (Fig. 3.47). 

Fig. 3.46 Potential-current density curves in 50% sodium hydroxide solution at 60°C...

The acidic crude alkylbenzene flows over the head of the separator LSI (Fig. 17) through a mixer where alkali of a suitable concentration is fed into a separator (ST5) in which the high specific density alkali settles out (Fig. 18). The alkali is again fed into the mixing process. The crude LAB is pumped into an intermediate tank (T) and from there over a sodium hydroxide-containing column (DC) where it is dried before proceeding to the distillation stage. 

A solution of sodium hydroxide of density 1650 kg/m3 and viscosity 50 mN s/m2 is agitated by a propeller mixer of 0.5 m diameter in a tank of 2.28 m diameter, and the liquid depth is 2.28 m. The propeller is situated 0,5 m above the bottom of the tank. What is the power which the propeller must impart to the liquid for a rotational speed of 2 Hz ... 

The conformations adopted by polyelectrolytes under different conditions in aqueous solution have been the subject of much study. It is known, for example, that at low charge densities or at high ionic strengths polyelectrolytes have more or less randomly coiled conformations. As neutralization proceeds, with concomitant increase in charge density, so the polyelectrolyte chain uncoils due to electrostatic repulsion. Eventually at full neutralization such molecules have conformations that are essentially rod-like (Kitano et al., 1980). This rod-like conformation for poly(acrylic acid) neutralized with sodium hydroxide in aqueous solution is not due to an increase in stiffness of the polymer, but to an increase in the so-called excluded volume, i.e. that region around an individual polymer molecule that cannot be entered by another molecule. The excluded volume itself increases due to an increase in electrostatic charge density (Kitano et al., 1980). 

A bucket containing 25% sodium hydroxide solution was used to catch and neutralise bromine dripping from a leak. Lack of stirring allowed a layer of unreacted bromine to form below the alkali. Many hours later, a violent eruption occurred when the layers were disturbed dining disposal operations. Continuous stirring is essential to prevent stratification of slowly reacting mutually insoluble liquids, especially of such differing densities. 

RECOMMENDED FIELD PROCEDURES Spills must be contained by covering with vermiculite, diatomaceous earth clay, fine sand, sponges, and paper or cloth towels. Decontaminate with copious amounts of aqueous Sodium Hydroxide solution (a minimum 10 wt percent). Scoop up all material and place in a fully removable head drum with a high density polyethylene liner. Cover the contents of the drum with decontaminating solution as above before affixing the drum head. 

Scenario A student prepared ASA starting with 2.00 g of salicylic acid and 5.00 mL of acetic anhydride (density = 1.08 g mL-1). After the product was dried, it weighed 1.90 grams. The student then hydrolyzed the ASA with sodium hydroxide and heated the mixture to produce the salicylate dianion ... 

What s the density of sodium hydroxide You ve just done a wash with 5-10% sodium hydroxide solution, you ve just read something about finding various layers in the funnel by their densities, and, by this question, you ve just shown that you ve missed the point. Most wash solutions are 5 to 10% active ingredient dissolved in water. This means they are 90 to 95% water. Looking up the density of the solid reagents then, is a waste of time. The density of these solutions is very close to that of water. (10% NaOH has a specific gravity of 1.1089.)... 

Newer and more complex humus extractions have been developed. These typically involve more steps such as both physical separation on the basis of density and particle size (related to the size of soil inorganic components), and chemical separation based on extractions and washings with hydrofluoric acid (HF), hydrochloric acid (HC1), and sodium hydroxide (NaOH). The products of such separations are then subjected to spectroscopic analysis and interpretation [22,23],... 

Area 200 control uses a batch controller. Each reactor is monitored and controlled separately. Level sensors and control valves meter the agent, energetics, or propellant along with sodium hydroxide into the empty reactor vessel. Fluid density is used to monitor and control the caustic concentration in the reactor vessel. 

Sears 189) and Heston et al. 190) used the adsorption of sodium hydroxide for the determination of the surface area of colloidal silica. An empirical factor was used for the conversion of alkali consumption into surface area. This is permissible provided the packing density of surface silanols is constant. The determination was performed in concentrated sodium chloride solution in order to keep down the dissolution of silica. Using the same technique, it was found in my laboratory that all surface silanol groups as determined by other methods are neutralized at pH 9.0. At higher pH, siloxane bonds in the surface were opened. A maximum in the sorption of Na+ ions occurred usually at pH 10.5-10.6 which corresponded to a packing density of ca. 5 OH/100 A. On further addition of alkali, silicate ions H3Si04 went into solution. 

Very few direct measurements of the reaction of surface silanol groups on quartz have been reported. This is apparently caused by the small effects due to the limited surface areas available. Adsorption of sodium ions on quartz was measured by radioactive tracer techniques by Gaudin et al. (293). Saturation was achieved at high pH (>10) and sodium ion concentrations above 0.07 Jlf. The calculated packing density of silanol groups was 4.25/100 A. Goates and Anderson (294) titrated quartz with aqueous sodium hydroxide and alcoholic sodium ethylate. The occurrence of two types of acidic groups was reported. 

Electrolysis of fused sodium hydroxide has heen achieved successfully with a Castner cell. The Castner cell was used in commercial production prior to introduction of Downs cell. The cell is operated at a bath temperature 320 10°C, at 9.0 0.5 amp current and a voltage of 4.3 to 5.0 V. The cathode current density is about 10.9 kA/m2. The cell consists of a copper cathode and a nickel anode and a cylindrical iron-gauge diaphragm placed between the electrodes. The cell reactions are as follows ... 

Silvery needles refractive index 1.470 density 0.92 g/cm decomposes at 800°C decomposes explosively in water reacts violently with lower alco-hols dissolves in molten sodium and molten sodium hydroxide insoluble in liquid ammonia, benzene, carbon tetrachloride and carbon disulfide. 

Grayish-white metal hody-centered cubic crystalline structure density 19.3 g/cm3 melts at 3,422°C vaporizes at 5,555°C vapor pressure 1 torr at 3,990°C electrical resistivity 5.5 microhm-cm at 20°C modulus of elasticity about 50 to 57 x lO psi (single crystal) Poisson s ratio 0.17 magnetic sus-ceptibilty +59 x 10-6 thermal neutron absorption cross section 19.2 + 1.0 barns (2,200m/sec) velocity of sound, about 13,000 ft/sec insoluble in water practically insoluble in most acids and alkabes dissolves slowly in hot concentrated nitric acid dissolves in saturated aqueous solution of sodium chlorate and basic solution of potassium ferricyanide also solubibzed by fusion with sodium hydroxide or sodium carbonate in the presence of potassium nitrate followed by treatment with water... 

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