Corrosion process industries

Fontana, M.G., The Eight Forms of Corrosion, Process Industries Corrosion, NACE International, Houston, TX, USA, pp. 1-39, 1975. 

R. D. Cooks, Materials of Construction for Nitric Mcid, Process Industries Corrosion, National Association of Corrosion Engineers, 1986, pp. 259—263. 

Zirconium is used as a containment material for the uranium oxide fuel pellets in nuclear power reactors (see Nuclearreactors). Zirconium is particularly usehil for this appHcation because of its ready availabiUty, good ductiUty, resistance to radiation damage, low thermal-neutron absorption cross section 18 x 10 ° ra (0.18 bams), and excellent corrosion resistance in pressurized hot water up to 350°C. Zirconium is used as an alloy strengthening agent in aluminum and magnesium, and as the burning component in flash bulbs. It is employed as a corrosion-resistant metal in the chemical process industry, and as pressure-vessel material of constmction in the ASME Boiler and Pressure Vessel Codes. 

Fracture Mechanics Methods These have proved very usebd for defining the minimum stress intensity K[scc. t which stress corrosion cracking of high-strength, low-ductihty alloys occurs. They have so far been less successful when apphed to high-ductility alloys, which are extensively used in the chemicm-process industries. 

Stainless Steel There are more than 70 standard types of stainless steel and many special alloys. These steels are produced in the wrought form (AISI types) and as cast alloys [Alloy Casting Institute (ACI) types]. Gener y, all are iron-based, with 12 to 30 percent chromium, 0 to 22 percent nickel, and minor amounts of carbon, niobium (columbium), copper, molybdenum, selenium, tantalum, and titanium. These alloys are veiy popular in the process industries. They are heat- and corrosion-resistant, noncontaminating, and easily fabricated into complex shapes. 

Bronzes are somewhat similar to brasses in mechanical properties and to high-zinc brasses in corrosion resistance (except that bronzes are not affected by stress cracking). Aluminum and silicon bronzes are very popiilar in the process industries because they combine good strength with corrosion resistance. 

Galvanic corrosion in typical industrial cooling water systems is the net result of the interplay of these factors. Some factors may accelerate the corrosion process others may retard it. In their approximate order of importance, the more influential factors are discussed below. 

Many sources contain scattered information concerning cooling water system corrosion and defects, and many literature studies describe corrosion processes and mechanisms from a predominantly theoretical viewpoint. Until now, however, no source discusses cooling water system corrosion with emphasis on identification and elimination of specific problems. Much of the information in this book is unique every significant form of attack is thoroughly detailed. Color photos illustrate each failure mechanism, and case histories further describe industrial problems. 

Dillon, C. P., 1986. Corrosion Control in the Chemical Process Industries, McGraw-Hill. 

This type of seal has the rotary component and face mounted outside the seal chamber. The springs and drive elements are outside the pumped liquid. This reduces the problems associated with corrosion and the accumulation of pumped product clogging the springs. This seal is popular in the food processing industry. The pumped liquid arrives to the inside diameter of the faces and seals toward the outside diameter. The environment outside the pump approaches the OD of the face union. Pressures are limited to about 35 psig. Sometimes this. seal can be mounted either inside or outside the pump. This seal is easy to install, adjust, and maintain. It permits easy access and cleaning of the pump internal parts, often required in the food processing industry. 

Paints based on phenolic resins are oil modified to permit drying at ambient temperatures. They are very suitable for most industrial atmospheres. Paints with a higher standard of chemical resistance are required for equipment that is splashed by corrosive process liquors. 

As will have become apparent, nickel and corrosion-resistant nickel alloys have wide ranges of application, particularly in industries where strongly acidic, strongly alkaline or strongly saline environments are encountered. Table 4.29 lists some of the more important applications in those industries where these conditions most frequently arise, i.e. in the chemical, petrochemical, oil and gas, nuclear and conventional power generating, textile, paper, marine, desalination and food processing industries. The list is by no means exhaustive and there are many other applications of a similar nature in these and other industries. The table should, nevertheless, serve... 

Some industries, notably the fine chemicals and parts of the food processing industry, cannot tolerate the pick-up of even small quantities of metal ions in their products. To avoid corrosion, plants often have to incorporate lined pipework and reaction vessels, while in a slightly less demanding situation whole plants are made of an appropriate grade of stainless steel. The capital investment in these industries is thus considerably increased due to the necessity to avoid corrosion. 

Laboratory corrosion testing of metals for the process industries... 

Richardson, J. A., Innovations in Techniques for Corrosion Monitoring , Conf. Advances in Materials Technology for Process Industries Needs, Atlanta (1984)... 

Hladky, K. and John, D.G., Corrosion Monitoring Using Electrochemical Noise , 2nd. Int. Conf. on Corrosion Monitoring and Inspection in the Oil, Petrochem. and Process Industries, London, Oyez Scientific and Technical Services Ltd., London (1984)... 

Corrosion Monitoring and Inspection in the Oil, Petrochemical and Process Industries , Proc. 

Conference, February 1984, Oyez Scientific and Technical Services, London Corrosion Monitoring in the Oil, Petrochemical and Process Industries , J. Wanklyn, (ed.), Proc. Conference, Oyez Scientific and Technical Services, London (1982)... 

Chlorinated polyether They are corrosion and chemical resistant whose prime use has been to fabricate products and equipment for the chemical and its processing industries. Uses also include pumps, water meters, bearing surfaces, etc. 

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