Copper industrial production

A conservative estimate of the total value of the products from the mineral industry is ca 3.9 trillion ia terms of 1992 dollars (4). This estimate does not include the value of products derived from secondary sources such as recycling (qv) or reclamation. Secondary recovery is significant for certain commodities. For example, in 1992 ca 30% of the world steel (qv) production, 46% of the world refined lead output, 15% of the world refined copper (qv) production, and ca 30% of the aluminum (see Aluminumand ALUMINUM alloys) output from the Western world were clearly identified as being derived from scrap. The value of the world mineral commodity export trade in 1992 was ca 616,698 million ia 1992 dollars. This accounted for ca 18% of all commodities exported (4). 

Industrial production of copper phthalocyanine usually favors either the phthaUc anhydride—urea process (United States, United Kingdom) (1,52,53) or the (9-phthalodinitrile process (Germany, Japan) (54,55). Both can be carried out continuously or batchwise in a solvent or bake process of the soHd reactants (56). 

Japan, Canada, and the United States accounted for 70% of the 1995 estimated world production of 2000 t (Table 5). At least 100 t of selenium was also available to Western markets from the former Soviet bloc. Selenium production is expected to rise in South America, particularly Chile, as the copper industry continues rapid expansion. A considerable amount of unrefined selenium is also shipped to Chile and the Philippines for conversion to final commercial product by either hydrometaHurgical or distillation processes. 

The United States is largely self-sufficient with respect to copper, meeting any shortfall by imports. AustraHa and the CIS consume most of their production on the domestic market. Japan and Western Europe import substantial quantities of copper in the form of concentrates, bHster, and refined copper. World mine, smelter, and refining capacities in 1989 are given in Table 6. Copper industries in Chile, Pern, Zaire, and Zambia are nationalized. 

In 1988, a comprehensive report on the technology and competitiveness of the U.S. copper industry was issued (54). This report concludes that the revitalized U.S. copper industry could compete in all but the worst foreseeable markets and that the industry s turnaround came entirely from its own efforts, with Httie governmental assistance. The U.S. copper industry is a world leader in smelter and refinery production, applying modem technology and measures to improve productivity. 

Industrial production media must also contain sources of potassium, phosphorous and magnesium. Trace elements may also have to be added. The water used for medium preparation will be from the public water supply or other readily available source. The quality of the water is carefully monitored because the presence of certain metal salts, for example, calcium, copper and iron, can have adverse effects on both the growth of the oiganism and the rheological properties of the exopolysaccharides. 

A number of electrolytic processes are used for the industrial production of metals. Some metals such as zinc, copper, manganese, gallium, chromium, etc. are electrowon from aqueous baths. Another common electrolytic process used is molten salt electrolysis. The most important application of molten salt electrolysis till now has been in the electrowinning of metals. Today aluminum, magnesium, lithium, sodium, calcium, boron, cerium, tantalum, and mischmetal are produced in tonnage quantities by molten salt electrolysis. As a representative example, the electrowinning process for aluminum is taken up. 

Of recycled, or secondary copper, 56% is derived from new scrap, while 44% comes from old scrap. Domestically, the secondary copper smelting industry is led by four producers. Like the secondary aluminum industry, these producers buy the scrap they recycle on the open market, in addition to using scrap generated in their own downstream productions. The secondary copper industry is concentrated in Georgia, South Carolina, Illinois, and Missouri. 

Asymmetric synthesis of 2,5-dimethyl-2,4-hexadiene (28) and /-menthyl diazoacetate (29) with chiral copper complexes (30) was successfully conducted by Aratani et al. [13] to afford the (1 A)-chrysanthem ic acid /-menthyl ester (31) in high optical and chemical yield. Since this finding, a lot of chiral copper complexes have been reported and applied to the asymmetric synthesis of (IR)-chrysanthemate. However, these copper complexes required more than 1 mol% of the catalyst and the cis/trans ratio still remains unsatisfactory. Moreover, /-menthyl ester was crucial for the high enantioselectivity. Given an industrial production of... 

The oxidative carbonylation of alcohols and phenols to carbonates can be catalyzed by palladium or copper species [154-213]. This reaction is of particular practical importance, since it can be developed into an industrial process for the phosgene-free synthesis of dimethyl carbonate (DMC) and diphenyl carbonate (DPC), which are important industrial intermediates for the production of polycarbonates. Moreover, DMC can be used as an eco-friendly methylation and carbonylation agent [214,215]. The industrial production of DMC by oxidative carbonylation of methanol has been achieved by Enichem [216] and Ube [217]. 

Other industrial uses of aluminum flake include the building industry (production of aerated concrete) and the chemical industry (e.g., production of titanium dioxide, pyrotechnics, and explosives). Copper powder in flake form is used in the chemical industry (e.g., for phthalocyanine production, for lubricants). 

Lead (Pb) ranks fifth behind iron, copper, aluminum, and zinc in industrial production of metals. About half of the lead used in the U.S. goes for the manufacture of lead storage batteries. Other uses include solders, bearings, cable covers, ammunition, plumbing, pigments, and caulking. 

Humans have been exposed more and more to metallic contaminants in the environment, mostly from the products of industry. There are three main sources of metals in the environment. The most obvious are the processes of extraction and purification mining, smelting, and refining. Another is the release of metals from fossil fuels (e.g., coal, oil), when these are burned. Cadmium, lead, mercury, nickel, vanadium, chromium, and copper are all present in these fuels, and considerable amounts enter the air or are deposited in ash. The third and most diverse source is the production and use of industrial products containing metals, which is increasing as new applications are found. The modem chemical industry, for example, uses many metals or metal compounds as catalysts metal compounds are used as stabilizers in the production of many plastics, and metals are added to lubricants, which then find their way into the environment.21... 

Thallium — Metal (atomic weight 204.383 gmol-1) found in nature mostly associated with minerals of copper, zinc, lead, and iron. Industrial production is based on electrolytic reduction from solutions of thallium in sulfuric acid obtained by dissolution of dust and cementation residues generated during lead and zinc production. 

The main anthropogenic sources of arsine include its accidental formation, particularly in the chemical and nonfer-rous (like zinc, copper, and cadmium) metallurgical industries, production or use of the gas itself during manufacture of semiconductors as a doping agent (Aposhian, 1997 Winski et al, 1997) and in battery production as an alloy with lead (Wald and Becker, 1986). 

Besides the industrial production of PCNs there is also a release of PCNs to the environment via polychlorinated biphenyl (PCB) commercial products, in which PCNs are present as minor contaminants [3], PCNs are also formed in various incineration processes [4, 5] and industrial processes such as the production of magnesium [6], copper [7] and in chloroalkali production [8,9]. PCNs are currently widespread in the environment and are to be regarded as an environmental problem [4]. In general, PCNs are present in biota at ng g 1 levels (on lipid weight basis). High levels (2.4 pgg J) have been reported in e. g., whitetailed sea eagle from Poland [5]. 

Among the best-known nonderivatizing solvent systems is a combination between copper, alkali, and ammonia termed Schweizer s reagent. Solutions of cuprammonium hydroxide have been used for both analytical and industrial cellulose dissolution. Regenerated fibers with silk-like appearance and dialysis membrane have been (and partially continue to be) industrial products on the basis of cellulose dissolution in cuprammonium hydroxide. The success of this solvent is based on the ability of copper and ammonia to complex with the glycol functionality of cellulose as shown inO Fig. 11. Because of the potential side reactions (oxidation and crosslinking, Norman compound formation), alternatives to both ammonia as well as copper have been developed. Cuen and cadoxen are related formulations based on the use of ethylene diamine and cadmium, respectively. The various combinations of alkali, ammonia. 

United States was used for this purpose. The most common compound used for this purpose was chromated copper arsenate (CCA). Wood preserved with CCA is referred to as pressure-treated wood. Wood treated with CCA is now recognized as a health hazard. Many authorities believe that humans and other animals exposed to pressure-treated wood may develop health problems because of arsenic present in the wood. For this reason, the U.S. Environmental Protection Agency (EPA) issued a ban on the use of CCA for treating wood, effective December 31, 2003. Pressure-treated wood may no longer be used for residential construction, although its use for industrial production is still permitted. 

Tin is also used in the manufacture of other alloys. Bronze, for example, is an alloy of tin and copper. It is used in a wide variety of industrial products, such as spark-resistant tools, springs, wire, electrical devices, water gauges, and valves. 

The BDSA conducts industrial economic studies, on a world-wide basis, of the production, uses, trends, and outlook for the major commodities and products. Some of the publications which are used to make this information available to the public are Chemical and Rubber Industry Report Copper Industry Report Pulp, Paper, and Board Industry Report Industry Trend Series and the Outlook Studies. Copies of the latest list of BDSA publications may be obtained from any Department of Commerce field ofifice or from the Publications Officer, BDSA, U.S. Department of Commerce, Washington 25, D.C. 

---