Chromated copper arsenate

A major concern when remediating wood-treatment sites is that pentachlorophenol was often used in combination with metal salts, and these compounds, such as chromated copper—arsenate, are potent inhibitors of at least some pentachlorophenol degrading organisms (49). Sites with significant levels of such inorganics may not be suitable candidates for bioremediation. 

The commercial uses of arsenic compounds in 1988, measured in terms of elemental arsenic, are wood (qv) preservatives, 69% agricultural products (herbicides (qv) and desiccants (qv)), 23% glass (qv), 4% nonferrous alloys and electronics, 2% and animal feed additives and pharmaceuticals (qv), 2% (see Feeds AND feed additives). Chromated copper arsenate (CCA) [11125-95-4] is the most widely used arsenic-based wood preservative. The Environmental Protection Agency has, however, restricted the use of arsenical wood preservatives to certified appHcators. 

Wood Preservation. The use of chromium compounds ia wood preservation is largely because of the excellent results achieved by chromated copper arsenate (CCA), available ia three modifications under a variety of trade names. The treated wood (qv) is free from bleeding, has an attractive ohve-green color, and is paintable. CCA is widely used, especially ia treating utility poles, bull ding lumber, and wood foundations. About 62% of all the chromic acid produced ia the United States is consumed by the wood preservation industry (77,167) (see Building materials, survey). 

From a canal lined with chromated-copper-arsenate wood vs. reference site 150-200 FW vs. 10 FW elevated concentrations were associated with greenish color and higher frequency of histopathology of digestive gland diverticula 29... 

Transfer of copper from wood treated with chromated copper arsenate (CCA) occurs in estuarine algae (Ulva, Enteromorpha), American oysters, mud snails (Nassarius obsoletus), and fiddler crabs (IJca spp. Weis and Weis 1992). Algae, barnacles, andmussels from CCA-treated lumber show elevated concentrations of copper when compared to reference sites. The epibiotic estuarine community that... 

Weis, J.S. and P. Weis. 1993. Trophic transfer of contaminants from organisms living by chromated-copper-arsenate (CCA)-treated wood to their predators. Jour. Exp. Mar. Biol. Ecol. 168 25-34. 

Weis, P., J.S. Weis, and J. Couch. 1993a. Histopathology and bioaccumulation in oysters Crassostrea virginica living on wood preserved with chromated copper arsenate. Dis. Aquat. Organ. 17 41 -46. 

Chondroitin 6-sulfate, 4 706 Chondroitin sulfates, 20 456 Chopped strand mat (CSM), 26 751 Chopper pumps, 21 78 Chop-stx number, for boron hydrides, 4 183 Chorinated trisodium phosphate, 4 52 Christmas tree module design, 15 835 Chromacity diagrams, 7 313-315 Chromaphores, 19 379 Chromate coatings, 9 827 Chromate conversion coatings, 16 218 Chromated copper arsenate, 3 276 ... 

Imagine that a friend has asked you to review the title and abstract of a paper that is being written with other researchers on chromated copper arsenate (CCA), a compound used to preserve wood. The research team examined the chemical structure of arsenic (As) and chromium (Cr) in CCA to determine if the oxidation state of As and Cr changed over time due to weathering. 

By far the largest use of arsenic is in treating wood to prevent decay or insect damage. Several compounds are used, but the vast majority of wood is treated with a pesticide called chromated copper arsenate (CCA). CCA is a water-based mixture of inorganic salts of chromium, copper, and arsenic that is forced into the wood... 

T0322 G.E.M., Inc., Treatment of Chromated Copper Arsenate (CCA) in Wood Products... 

Chromated copper arsenate (CCA) is used as a wood preservative. According to the technology developer, CCA-treated wood products resist decay and deterioration and are immune to moisture... 

New Zealand pasture contaminated by runoff from chromated copper arsenate timber preservation facility 1991 control surface soils contained an average of 19 mg Cu/kg DW, low contamination 109 mg/kg, medium contamination 425 mg/kg, and high contamination 835 mg/kg DW soil Vegetation... 

A series of complexometric extractions were performed to optimize the mobUiza-tion/purging of metallic ions from samples of processing condensate of chromated copper arsenate (CCA). Whereas Cr(VI) and Cu(II) were rapidly mobilized into isobu-tylmethyl ketone-amended SCCO2 after reaction with dithiocarbamate or alkylxan-... 

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