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Continuous Analysis

Spices are natural agricultural products and exhibit a range of variations of many specific characteristics. The most important quaUty assessment is the subjective physical observation of the whole or ground spice by an expert. The macroscopic and microscopic examination of spice is the criterion for the continued analysis of the product to determine adherance to specifications. [Pg.27]

At this stage a prototype product is produced, and its performance in the market is assessed. If this is satisfactory, full-scale production is established. But the designer s role does not end at this point. Continuous analysis of the performance of a component usually reveals weaknesses or ways in which it could be improved or made more cheaply. And there is always scope for further innovation for a radically new design, or for a radical change in the material which the component is made from. Successful designs evolve continuously, and only in this way does the product retain a competitive position in the market place. [Pg.293]

The quality of combustion can be measured with suitable instrumentation, on either a periodic or a continual basis. If continuous analysis is practiced then there may be feedback to continuously adjust the air/gas ratio and/or ratio and/or record the data derived. [Pg.276]

The mass spectrometer sampling capillary or the dispersive infra-red analyzers used for continuous analysis and monitoring of the gas phase composition are situated between the reactor and the sampling valve, as close to the reactor as possible, in order to avoid any delay in the recording of changes in the composition of reactants or products. This delay should be taken into account when plotting simultaneously the time dependence of catalyst potential or current and gas phase concentration of the reactants or products. [Pg.553]

Figure 4. Continuous analysis by fluorescence polarization of FLPEP binding and dissociation to permeabilized neutrophils. Each curve represents the average of two determinations. The descending curves represent the effect of the addition of receptor antagonist after FLPEP had bound to the receptors. Upper panel, in the absence of GTPyS, receptor antagonist added at t = 60 s lower panel, in the presence of GTPyS, antagonist added at t =... Figure 4. Continuous analysis by fluorescence polarization of FLPEP binding and dissociation to permeabilized neutrophils. Each curve represents the average of two determinations. The descending curves represent the effect of the addition of receptor antagonist after FLPEP had bound to the receptors. Upper panel, in the absence of GTPyS, receptor antagonist added at t = 60 s lower panel, in the presence of GTPyS, antagonist added at t =...
Finally, hydrodynamic electrodes remain of much interest especially in continuous analysis the equations concerned, although complex, show that the ix values are linearly proportional to the analyte concentration. [Pg.210]

Continuous analysis offers another very useful possibility of completely automated chemical control, especially in manufacturing processes, but also in analytical processes such as separational flow techniques where the analytical measurement proper acts as a sensor, usually called the detector. As long as a physical or physico-chemical constant yields a sufficiently accurate and specific... [Pg.326]

The character and the degree of automation in chemical control may have been covered in the above treatment of semi-automatic or completely automatic, and of discontinuous or continuous analysis, but something more should be said about the means by which automation proper has been performed in recent times. Whereas in the past automated analysis involved the use of merely, mechanical robots, to-day s automation is preferably based on computerization in a way which can best be explained with a few specific examples. Adjustment knobs have been increasingly replaced with push-buttons that activate an enclosed fully dedicated microcomputer or microprocessor in line with the measuring instrument the term microcomputer is applicable if, apart from the microprocessor as the central processing unit (CPU), it contains additional, albeit limited, memory (e.g., 4K), control logics and input and output lines, by means of which it can act as satellite of a larger computer system (e.g., in laboratory computerization) if not enclosed, the microcomputer is called on-line. [Pg.327]

Earlier in this chapter we considered the nature of chemical control (Section 5.1), the character and degree of automation (Section 5.2) with the choice between discontinuous and continuous analysis, the role of electroanalysis in automated chemical control (Section 5.3) and automated electroanalysis in laboratory control (Section 5.4). [Pg.372]

H. L. Kies, Continuous Analysis based on Electrochemistry, International Quarterly Review Journal, Scientific Publications Division, Freund Publishing House, Tel-Aviv, 1973. [Pg.380]

Flow injection analysis has been used for the automated determination of hydrogen sulfide in seawater [20]. A low-sensitivity flow injection analysis manifold for concentrations up to 200 imol/l hydrogen sulfide had a detection limit of 0.12 xmol/l. Sulfide standards were calibrated by colorimetric measurement of the excess tri-iodide ion remaining after reaction of sulfide with iodine. The coefficient of variation was less than 1% at concentrations greater than 10 imol/l. The method was fast, accurate, sensitive enough for most natural waters, and could be used both for discrete and continuous analysis. [Pg.126]

Flow sensors were also used coupled with microdialysis probe [236], providing several advantages the reaction took place in few minutes allowing continuous analysis the sensitivity was in the order of pmoles the microdialysis probe allowed biological specimens to be drawn without proteins or macromolecules. This technique can be extended to the analysis of analytes that need to be detected continuously such as during therapy monitoring, or in emergency care units. [Pg.270]

Chemical analysis finds important applications in the quality control of industrial processes. In an ideal situation a continuous analysis of the process stream is made and some aspects of this are discussed in Chapter 12. However, such continuous analysis is by no means always possible, and it is common to find a process being monitored by the analysis of separate samples taken at regular intervals. The analytical data thus obtained need to be capable of quick and simple interpretation, so that rapid warning is available if a process is going out of control and effective corrective action can be taken. [Pg.14]

K.L. Vikse, M.P. Woods, J.S. Mclndoe, Pressurized sample infusion for the continuous analysis of air- and moisture-sensitive reactions using electrospray ionization mass spectrometry, Organometallics 29 (2010) 6615-6618. [Pg.6]

Wilhamson, P., Bevers, E.M., Smeets, E.F., Comfurius, P., Schlegel, R.A. and Zwaal, R.F., 1995, Continuous analysis of the mechanism of activated transbilayer hpid movement in... [Pg.60]

The sequencing of the human genome has been widely touted as a critical scientific milestone that will revolutionize the process of drug discovery. The continuing analysis of the human genetic code will provide the scientific framework on which... [Pg.22]

Intersociety Committee. Tentative method for the continuous analysis of atmospheric oxidants (colorimetric), pp. 356-364. In Methods of Air Sampling and Analysis. Washington, D.C. American Public Health Association, 1972. [Pg.277]

Standard method of test for continuous analysis and automatic recording of the oxidant content of the atmosphere. Designation D 2011-65 (Reapproved 1972), pp. 924-928. In 1973 Annual Book of ASTM Standards. Part 23. Water Atmospheric Analysis. Philadelphia American Society for Testing and Materials, 1973. [Pg.278]

Al-formyl peptides rapidly bind to neutrophils (1-4). The association rate may be monitored by sampling a reaction mixture at selected times (4) or by continuous analysis of the reaction (3). [Pg.304]

Continuous analysis requires flexible tubes which are not attacked by the materials under examination, and this places certain limitations on the scope of the method. Certain reactive and corrosive materials cannot he satisfactorily pumped, although advances have been made in the development of inert plastics and other synthetic materials. Displacement pumping with the aid of a liquid compatible with sample and reagents provides an alternative, though generally inconvenient, approach. No such limitations arise in discrete analysers because there is no restriction on the choice of materials for sample and reagent containment. [Pg.28]

Continuous analysis of highly fluorinated materials can present problems, primarily caused by the corrosiveness of hydrogen fluoride which is liberated from all of them during combustion. Hydrogen fluoride will react with the permanently bound hydroxy groups on the surface of the cooler parts of combustion tube walls and catalysts. The effect can lead to erratic hydrogen values and so the installation of some type of oxide [magnesium oxide, alumina, or cerium (IV) oxide] trap in the combustion tube to prevent its escape is recommended. 11... [Pg.27]

Infrared analyses are conducted on dispersive (scanning) and Fourier transform spectrometers. Non-dispersive industrial infrared analysers are also available. These are used to conduct specialised analyses on predetermined compounds (e.g. gases) and also for process control allowing continuous analysis on production lines. The use of Fourier transform has significantly enhanced the possibilities of conventional infrared by allowing spectral treatment and analysis of microsamples (infrared microanalysis). Although the near infrared does not contain any specific absorption that yields structural information on the compound studied, it is an important method for quantitative applications. One of the key factors in its present use is the sensitivity of the detectors. Use of the far infrared is still confined to the research laboratory. [Pg.161]

Continued analysis of Sasanian silver objects will be directed towards (1) a detailed statistical study of the data, (2) analysis of Sasanian and Umayyad coins, (3) determination of isotope ratios of lead extracted from the silver, (4) correlation between the analytical data and stylistic information obtained from an art historical and archaeological study and with information on methods of manufacture, toolmark, etc. [Pg.39]

The following section is a review of instruments and techniques that have been used and/or specifically developed for aircraft measurement of trace species. To limit the scope, focus is restricted to species that we have identified to be of interest to a large segment of the atmospheric chemical community. The objective is to give the reader a starting point from which to either choose or develop an instrument or technique for aircraft sampling. This section is divided into two parts the first covers techniques that are used for batch sampling or analysis of atmospheric constituents the second is a review of continuous analysis methods. [Pg.125]

The most conclusive evidence for reaction (16) was recently given by Kohout and Lampe.264 They studied the mercury-sensitized decomposition of H2 and D2 in the presence of a small amount of NO. The products of the reaction were bled through a pinhole into a mass spectrometer for continual analysis. Results are shown in Figure 8-6 for the D2-NO system. They observed mass spectral peaks for DNO, DzO, and N20, but not for (DNO)2. Initially, DNO is produced, but it subsequently decays to form NsO (and D20). The minimum rate constant reported by them for DNO disproportionation was 3.4 x 106 M 1 sec-1. However, more recently Kohout263 in his doctoral dissertation has reported that DaO and N20 are the products of the bimolecular encounter of two DNO molecules. The rate constant is 4.0 x 105 Af-1 sec-1 independent of pressure over the limited pressure range of 30-70 torr. An increase in surface-to-volume ratio of about 50 had no effect on the results. [Pg.308]

The transition from laboratory7 to automated instrument to achieve highspeed continuous analysis of diy ol wet materials primarily involves the sample-handling and presentation hardware. [Pg.1761]

The use of a tubular carbon electrode (TCE) for the electrochemical oxidative determination of ascorbic acid [159], L-dopa [160], and methyldopa [161] in dosage forms has been described. The flow system, electrode assembly, and electrochemical instrumentation required for these assays are shown in Figure 26.11. The method is based on continuous analysis in flowing streams... [Pg.795]


See other pages where Continuous Analysis is mentioned: [Pg.499]    [Pg.546]    [Pg.39]    [Pg.8]    [Pg.203]    [Pg.322]    [Pg.367]    [Pg.48]    [Pg.394]    [Pg.26]    [Pg.27]    [Pg.28]    [Pg.603]    [Pg.106]    [Pg.53]    [Pg.78]    [Pg.796]    [Pg.1363]    [Pg.252]    [Pg.269]   
See also in sourсe #XX -- [ Pg.41 , Pg.179 ]




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