Confusion principle

Glass formation or the absence of crystallite nucleation and growth is also dependent on the confusion principle . This is an empirical observation which suggests that, in a multicomponent melt, several crystalline forms are in competition in the crystallization process the confused situation that results acts as a barrier to microcrystal growth and enhances the formation of the vitreous state. 

Evidently in such multi-component glasses of simple halides, significant lowering of the eutectic temperatures and of course, the confusion principle, together assist formation of glasses. 

Section BT1.2 provides a brief summary of experimental methods and instmmentation, including definitions of some of the standard measured spectroscopic quantities. Section BT1.3 reviews some of the theory of spectroscopic transitions, especially the relationships between transition moments calculated from wavefiinctions and integrated absorption intensities or radiative rate constants. Because units can be so confusing, numerical factors with their units are included in some of the equations to make them easier to use. Vibrational effects, die Franck-Condon principle and selection mles are also discussed briefly. In the final section, BT1.4. a few applications are mentioned to particular aspects of electronic spectroscopy. 

A code of principles accepted by 71 countries has been developed for consumer protection and fair practice in the trade of milk and milk products. Mainly the precise usage of the term milk and terms for different milk products is ensured. Confusion arising from the substitution of milk and milk products with nonmilk fats and/or nonmilk proteins is thus avoided. The use of misleading names and information for products that are not milk products is prohibited. Essentially, any product that resembles a dairy product is an imitation or substitute (synthetic) product. 

Although I have defined terms such as quality control and quality assurance in this chapter, what is important is not the definition but the deeds which it imbues. Whether we call the set of principles I have listed under the heading Quality assurance, Quality Assurance, Quality Improvement or Quality Control makes no difference since it does not change the set of principles. We often seem to invent a term then decide what it means rather than invent or discover a set of principles and think of a suitable name which conveys exactly what we intend without confusing people. Instead of saying Quality control is. .. or TQM is. .. to which there will be many propositions, we should be asking What should we call this group of principles so that we can communicate with each other more efficiently As Shakespeare once said That which we call a rose/By any other name would smell as sweet. ... 

Don t confuse the state wavefunction with a molecular orbital we might well want to build the state wavefunction, which describes all the 16 electrons, from molecular orbitals each of which describe a single electron. But the two are not the same. We would have to find some suitable one-electron wavefunctions and then combine them into a slater determinant in order to take account of the Pauli principle. 

Now consider the hypothetical problem of trying to teach the physics of space flight during the period in time between the formulation of Kepler s laws and the publication of Newton s laws. Such a course would introduce Kepler s laws to explain why all spacecraft proceed on elliptical orbits around a nearby heavenly body with the center of mass of that heavenly body in one of the focal points. It would further introduce a second principle to describe course corrections, and define the orbital jump to go from one ellipse to another. It would present a table for each type of known spacecraft with the bum time for its rockets to go from one tabulated course to another reachable tabulated course. Students completing this course could run mission control, but they would be confused about what is going on during the orbital jump and how it follows from Kepler s laws. 

The principles of Kepler s laws and orbital jumps in isolation would leave students confused. Alternatively suppose students were taught that only free-falling space flight can be understood from Kepler s laws, and that the tables for course corrections had been constructed from careful experimentations and observations. In this case, students would not be confused either. The confusion comes from stating that everything will be explained theoretically and then only explaining half. 

The third problem is like the confusion caused in MT by maintaining the concept of the Ether. Most practitioners of QM think about microscopic systems in terms of the principles of QM probability distributions, superposition principle, uncertainty relations, complementarity principle, correspondence principle, wave function collapse. These principles are an approximate summary of what QM really is, and following them without checking whether the Schrddinger equation actually confirms them does lead to error. 

Cometabolism merits, however, careful analysis since important metabolic principles underlie most of the experiments, even though confusion may have arisen as a result of ambiguous terminology. An attempt is therefore made to ignore semantic implications and to adopt a broad perspective in discussing this enviromnentally important issue. A pragmatic point of view has been adopted, and the following examples attempt to illustrate the kinds of experiments, which have been carried out under various conditions. 

Since two electrons of the same spin have a zero probability of occupying the same position in space simultaneously, and since t / is continuous, there is only a small probability of finding two electrons of the same spin close to each other in space, and an increasing probability of finding them an increasingly far apart. In other words the Pauli principle requires electrons with the same spin to keep apart. So the motions of two electrons of the same spin are not independent, but rather are correlated, a phenomenon known as Fermi correlation. Fermi correlation is not to be confused with the Coulombic correlation sometimes referred to without its qualifier simply as correlation . Coulombic correlation results from the Coulombic repulsion between any two electrons, regardless of spin, with the consequent loss of independence of their motion. The Fermi correlation is in most cases much more important than the Coulomb correlation in determining the electron density. 

McFarland et al. recently [1] published the results of studies carried out on 22 crystalline compounds. Their water solubilities were determined using pSOL [21], an automated instrument employing the pH-metric method described by Avdeef and coworkers [22]. This technique assures that it is the thermodynamic equilibrium solubility that is measured. While only ionizable compounds can be determined by this method, their solubilities are expressed as the molarity of the unionized molecular species, the intrinsic solubility, SQ. This avoids confusion about a compound s overall solubility dependence on pH. Thus, S0, is analogous to P, the octanol/water partition coefficient in both situations, the ionized species are implicitly factored out. In order to use pSOL, one must have knowledge of the various pKas involved therefore, in principle, one can compute the total solubility of a compound over an entire pH range. However, the intrinsic solubility will be our focus here. There was one zwitterionic compound in this dataset. To obtain best results, this compound was formulated as the zwitterion rather than the neutral form in the HYBOT [23] calculations. 

The use of the term ab initio in the context of protein folding should not be confused with its use to describe ab initio quantum chemistry calculations. In both cases, ab initio is meant to convey the idea of from first principles, but die starting point and theoretical framework are different for each. 

Note that good laboratory practice (glp) should not be confused with Good Laboratory Practice (GLP). The latter is the name given to a set of principles governing the organizational process and the condition under which non-clinical health and environmental safety studies are planned, performed, monitored, recorded, archived and reported, and was put forward initially by the Organization for Economic Co-operation and Development (OECD) (see Chapters 2 and 9). 

The minute concentration of ions has gained some credence amongst those who are unaware of all the facts to be explained a contributory source of confusion is that unfortunately many chemists have not been taught to distinguish between a reaction intermediate of finite lifetime, in principle detectable, and a transition state with a lifetime of one molecular vibration, i.e., 10 13s. 

This was the first international organisation working at the government level in the food sector that laid down principles for the establishment of its methods. That it was necessary for such guidelines and principles to be laid down reflects the confused and unsatisfactory situation in the development of legislative methods of analysis that existed until the early 1980s in the food sector. 

If the relevant literature is surveyed for the keywords etch stops and silicon, a confusing multiplicity of methods is found using different electrolytes, different bias and differently doped silicon substrates. This section does not aim to be a comprehensive review of all these techniques [Co2], but an introduction to the basic principles of electrochemical etch stops, which will be illustrated by a few typical examples. 

Both resonance and damping can cause some confusion and the explanations of the underlying physics can become muddled in a viva situation. Although the deeper mathematics of the topic are complex, a basic understanding of the underlying principles is all the examiners will want to see. 

There is often some confusion between the terms standards and reference materials. Primary standards represent the top-tier of chemical standards and, in principle, provide a means of establishing the traceability of analytical data to the SI measurement units (e.g., the kilogram, mole, meter, and second). A limited number of pure chemicals are recognized as primary standards (and thus can constitute certified reference materials). Most certified reference materials are not of themselves primary standards rather, the property values assigned to them are traceable to primary standards where practical. 

A number of empirical relationships have been published which could be used to predict partition coefficients from solubility data [19-29, 65, 72, 78-97]. Comparisons among these relationships may be confusing since different sets of compounds and different solubility terms are used. A theoretical analysis of partition coefficient with reference to aqueous solubility is important because it illustrates the thermodynamic principles underlying the partitioning process. The objective of that relationship is its utility for both predicting and validating reported values for partition coefficients. 

---