Condensation surface water

For this preparation, which must be performed in the fume-cupboard, assemble the apparatus shown in Fig. 67(A). C is a 150 ml. distilling-flask, to the neck of which is fitted a reflux single-surface water-condenser D, closed at the top E by a calcium chloride tube. The side-arm of C carries a cork F which fits the end E of the condenser for subsequent distillation. The side-arm of C is meanwhile plugged by a small rubber cork, or by a short length of glass rod. (Alternatively, use the ground-glass flask and condenser (Fig. 22 (a) and (c), p. 43), and... 

The reaction is carried out in a 2-litre long-necked round-bottomed flask, to which is fitted an efficient reflux water-condenser, capable of condensing a sudden rush of vapour without choking. For this purpose, a long bulb-condenser, similar to that shown in Fig. 3(A) (p. 9) is best, but the inner tube must be of wide bore (at least 12 mm.). Alternatively, an air-condenser of wide bore may be used, an.d a short double-surface water-condenser fitted to its top. A steam-distillation fitting for the flask should also be prepared in advance, so that the crude product can subsequently be steam-distilled directly from the flask. The glj cerol used in the preparation must be anhydrous, and should therefore be dehydrated by the method described on p. 113. 

Compounds having low vapor pressures at room temperature are treated in water-cooled or air-cooled condensers, but more volatile materials often requite two-stage condensation, usually water cooling followed by refrigeration. Minimising noncondensable gases reduces the need to cool to extremely low dew points. Partial condensation may suffice if the carrier gas can be recycled to the process. Condensation can be especially helpful for primary recovery before another method such as adsorption or gas incineration. Both surface condensers, often of the finned coil type, and direct-contact condensers are used. Direct-contact condensers usually atomize a cooled, recirculated, low vapor pressure Hquid such as water into the gas. The recycle hquid is often cooled in an external exchanger. 

The condenser design, surface area, and condenser cooling water quantity should be based on the highest cooling water temperature likely to be encountered, if the inlet cooling water temperature becomes hotter then the design, the primaiy booster (ejector) may cease functioning because of the increase in condenser pressure. 

Condensers The vapor from the last effect of an evaporator is usually removed by a condenser. Surface condensers are employed when mixing of condensate with condenser coohng water is not desired. They are for the most part shell-and-tube condensers with vapor on the shell side and a multipass flow of cooling water on the... 

The other mechanism appears in scrubbers. When water vapor diffuses from a gas stream to a cold surface and condenses, there is a net hydrodynamic flow of the noncondensable gas directed toward the surface. This flow, termed the Stefan flow, carries aerosol particles to the condensing surface (Goldsmith and May, in Davies, Aero.sol Science, Academic, New York, 1966) and can substantially improve the performance of a scrubber. However, there is a corresponding Stefan flow directed away from a surface at which water is evaporating, and this will tend to repel aerosol particles from the surface. 

Condensation Scrubbing The collection efficiency of scrubbing can be increased by the simultaneous condensation of water vapor from the gas stream. Water-vapor condensation assists in particle removal by two entirely different mechanisms. One is the deposition of particles on cold-water droplets or other surfaces as the result of... 

When a liquid or solid substance is emitted to the air as particulate matter, its properties and effects may be changed. As a substance is broken up into smaller and smaller particles, more of its surface area is exposed to the air. Under these circumstances, the substance, whatever its chemical composition, tends to combine physically or chemically with other particles or gases in the atmosphere. The resulting combinations are frequently unpredictable. Very small aerosol particles (from 0.001 to 0.1 Im) can act as condensation nuclei to facilitate the condensation of water vapor, thus promoting the formation of fog and ground mist. Particles less than 2 or 3 [Lm in size (about half by weight of the particles suspended in urban air) can penetrate the mucous membrane and attract and convey harmful chemicals such as sulfur dioxide. In order to address the special concerns related to the effects of very fine, iuhalable particulates, EPA replaced its ambient air standards for total suspended particulates (TSP) with standards for particlute matter less than 10 [Lm in size (PM, ). 

Surface Condensers Surface condensers (indirect-contact condensers) are used extensively in the chemical-process industiy. They are employed in the air-poUution-equipment industry for recoveiy, control, and/or removal of trace impurities or contaminants. In the surface type, coolant does not contact the vapor condensate. There are various types of surface condensers including the shell-and-tube, fin-fan, finned-hairpin, finned-tube-section, ana tubular. The use of surface condensers has several advantages. Salable condensate can be recovered. If water is used for coolant, it can be reused, or the condenser may be air-cooled when water is not available. Also, surface condensers require less water and produce 10 to 20 times less condensate. Their disadvantage is that they are usually more expensive and require more maintenance than the contac t type. 

One form of solar heat does offer interesting possibilities and is refeiTcd to as OTEC (Ocean-Thermal Energy Conversion). The OTEC power plant principle uses the solar heat of ocean surface water to vaporize ammonia as a working fluid in a Rankine cycle. After the fluid is expanded in the turbine, it is condensed by the 22°C colder... 

The real atmosphere is more than a dry mixture of permanent gases. It has other constituents—vapor of both water and organic liquids, and particulate matter held in suspension. Above their temperature of condensation, vapor molecules act just like permanent gas molecules in the air. The predominant vapor in the air is water vapor. Below its condensation temperature, if the air is saturated, water changes from vapor to liquid. We are all familiar with this phenomenon because it appears as fog or mist in the air and as condensed liquid water on windows and other cold surfaces exposed to air. The quantity of water vapor in the air varies greatly from almost complete dryness to supersaturation, i.e., between 0% and 4% by weight. If Table 2-1 is compiled on a wet air basis at a time when the water vapor concentration is 31,200 parts by volume per million parts by volume of wet air (Table 2-2), the concentration of condensable organic vapors is seen to be so low compared to that of water vapor that for all practical purposes the difference between wet air and dry air is its water vapor content. 

Cooling water cost is reduced and total heat exchanger plus condenser surface may be reduced. 

Acidic smuts Solid and liquid conglomerates formed by the condensation of water vapor and sulfur trioxide on a cold surface. A typical case is combustion products in a flue, which come into contact with surfaces at temperatures below the flue gas dew point temperature. These products contain metallic sulfate and carbon aqueous particles approximately 1-3 mm in size. 

Condensation of water on cool indoor surfaces (e.g., windows) may damage materials and promote the growth of microorganisms. The presence of humidifiers in commercial building HVAC systems has been associated with an increase in various respiratory health symptoms. 

There are three potential types of OTEC power plants opcii-cyclc, closed-cycle, and hybrid systems. Open-cycle OTEC systems exploit the fact that water boils at temperatures below its normal boiling point when it is under lower than normal pressures. Open-cycle systems convert warm surface water into steam in a partial vacuum, and then use this steam to drive a large turbine connected to an electrical generator. Cold water piped up from deep below the oceans surface condenses the steam. Unlike the initial ocean water, the condensed steam is desalinated (free of salt) and may be collected and used for drinking or irrigation. 

Secondly, absorbent particles such as charcoal and soot are intrinsically inert but have surfaces or infrastructures that adsorb SO, and by either coadsorption of water vapour or condensation of water within the structure, catalyse the formation of a corrosive acid electrolyte solution. Dirt with soot assists the formation of patinae on copper and its alloys by retaining soluble corrosion products long enough for them to be converted to protective, insoluble basic salts. 

A similar effect occurs if the air is brought into contact with a solid surface, maintained at a temperature below its dew point. Sensible heat will be transferred to the surface by convection and condensation of water vapour will take place at the same time. Both the sensible and latent heats must be conducted through the solid and removed. The simplest form is a metal tube, and the heat is carried away by refrigerant or a chilled fluid within the pipes. This coolant must be colder than the tube surface to transfer the heat inwards through the metal. 

Figure 11.2 Surface activity on the waterside of a condensate line, showing filmwise condensation of water on an unprotected area (a) and dropwise condensation on an area protected by a closely packed arrangement of filming amine molecules (b).

The presence of PSCs also leads to the removal of nitrogen oxides (NO and NO2) from the gas phase. As long as there are significant amounts of NO2 it will react with chlorine monoxide (CIO) to produce chlorine nitrate (reaction 11). This species subsequently reacts with HQ on PSC surfaces to produce nitric acid (reaction 13), which remains in the condensed phase. Also, nitric acid directly condenses with water to form nitric acid trihydrate particles, hence it is not available to regenerate NO2 by photochemical processes, as it does when it is in the gas phase. 

Frozen product 2, vial or the end of a shelf 3, open surface (FI) for the water vapor flow between 2 and 4 4, chamber wall 5, valve with an open area F2 6, condenser chamber 7, cooling and condensing surface in the condenser chamber having a surface of F3 8, vacuum pipe with the diameter d 9, stop valve 10, vacuum pipe with the length 1 (from 8 to II) 11, vacuum pump pjce, water vapor pressure at the sublimation front of the ice /, pressure in the vial pco, pressure in the condenser. 

The flow of water vapor should deviate as little as possible before the first condenser surface. The condenser design has to ensure that the water vapor is completely frozen and the remaining water vapor pressure is practically equal to the vapor pressure at the ice surface. This can only be achieved if the vapor passes over several condenser surfaces in series. 

A, free diameter of the connection to the chamber B, cylindrical opening by the movement of D C, opening between condenser wall and valve plate D, valve plate, hydraulic valve drive E, condensation surface of the refrigerated coils F, in- and outlet of the refrigerant G, tube connection to the vacuum pump H, water drain during defrosting of the condenser pch and pm pressure in the chamber and in the condenser, respectively. 

The conditions of water vapor transport between the chamber and condenser, the condenser surface, the capacity of the refrigerant compressors and the vacuum pumping capacity, must all be the same (pro rata) for the product dried in the laboratory as in the plant to which the process will be transferred. 

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