Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Particle aqueous

This equation is based on the assumption that pseudoplastic (shear-thinning) behaviour is associated with the formation and rupture of structural linkages. It is based on an experimental study of a wide range of fluids-including aqueous suspensions of flocculated inorganic particles, aqueous polymer solutions and non-aqueous suspensions and solutions-over a wide range of shear rates (y) ( 10 to 104 s 1). [Pg.111]

Each concentration can be evaluated assuming no mass transport limitation and the usual priorities for the distribution of the emulsifier polymer particles > aqueous phase > micelles (12). The... [Pg.386]

Explanation may be related to the heterogeneity of the reaction medium polymerization location is mostly limited to within the polymer particles, so the copolymer composition is dependent on the composition of the monomer mixture inside the particles, which may be different from that of the whole reactor, monitored by the apparatus. So, compositions of various phases, monomer droplets, polymer particles, aqueous phase, were measured using gas chromatographic (GC) analysis, after they were separated by ultracentrifugation (33,000 rpm). [Pg.413]

Organic solvent methyl ethyl ketone -> Diatomaceous earth particle - Aqueous plasma layer... [Pg.74]

When micronic or submicronic particles are produced, particle collection and harvesting is certainly the most acute issue Based on the considerable experience gathered in dust collection at any scale (83), different particle collection systems can be proposed depending on the final form desired by the operator dry powder, dry mixture of active substance and excipient particles, aqueous or solvent suspension. [Pg.634]

The theoretical developments described in the remainder of this section follow those reported by German, Maxwell and co-workers [20-25], though there are differences in the nomenclature used. In order to eliminate the complicating effects of particle number concentration, the assumptions are made that particle nucleation is complete and that only the partitioning of monomer between the latex particle, aqueous and monomer droplet phases need be considered. To define the thermodynamic conditions for equilibrium, the chemical potential of each monomer in each of these phases is required. The following equations were employed ... [Pg.543]

Hydrophobic substances such as hydrocarbons will prefer to be within the polymer particle these are described as A Group coalescents. These tend to be inefficient coalescing agents. Molecules, which are more hydrophilic than hydrocarbons tend to be preferentially sited at the particle - aqueous interface, along with the surfactant system. These are described as AB Group coalescents. These exhibit the best efficiency as coalescing solvents. [Pg.972]

Although styrene monotier condensed with water in the condensing liquid, it was assumed that the contribution of styrene was negligible to calculate z in (1). Also, it was assumed that densities of the SBR particles, aqueous phase and condensate were all equal to 1 gr/ml. [Pg.915]

Affinity (AC) Covalently immobilized affinity lig d on particles Aqueous buffers Good choice for capture of target molecule at low concentrations in sample... [Pg.246]

Conventional emulsion polymerization occurs in a three-phase system (polymer particles, aqueous phase, and monomer droplets) and polymerization may, in principle, occur in any phase. However, the concentrations of both monomer and radicals in the polymer particles are much higher than those in the aqueous phase (see below), and hence the extent of the polymerization in the aqueous phase is in most cases negligible. On the other hand, the concentration of the radicals in the monomer droplets is very low because the monomer droplets are not efficient at capturing the radicals formed in the aqueous phase. The polymerization in the polymer particles follows the same mechanisms as in bulk polymerization and the rate of polymerization per polymer particle Rpp is given by Eq. (1), where kp is the propagation rate constant [m mol s ], [M] the concentration of monomer in the polymer particles [mol m ], h the average number of radicals per particle and Na Avogadro s number. [Pg.258]

The polymer particle/aqueous phase interfacial area can be obtained from the particle size measurements, but the total transfer area between the aqueous and... [Pg.983]

Tab. 18.1. Polymer particle/aqueous phase coefficients under devolatilization conditions calculated by R. Salazar [100]. Tab. 18.1. Polymer particle/aqueous phase coefficients under devolatilization conditions calculated by R. Salazar [100].
The polymer particles/aqueous phase mass-transfer coefficient can be determined through the Frossling equation [73], where Sh is the Sherwood number. Re the Reynolds number, and Sc the Schmidt number. [Pg.984]

As an alternative, closed fuel cycles with MOX or hybrid U-Th fuel are considered for the GT-MHR. An option to apply fuel reprocessing is mentioned for the HTR-PM and the GTHTR-300 for the latter it has already been investigated. In case of TRISO coated particles, aqueous reprocessing methods (e.g., PUREX) cannot be applied directly. Specifically, the problem is with the SiC coating layers, which are not dissolved in mixtures of acids and, therefore, require a mechanical treatment to be removed. [Pg.32]

A major and at first sight perhaps a surprising application of silicone oil is as a lubricant for wax. The methyl oils do not dissolve in wax but become adsorbed on the surface of wax particles. Aqueous suspensions of wax containing 4-10% silicone can be rubbed out, e.g. on floor, furniture, or motor car, with much less effort than would be needed without the silicone lubricant. [Pg.140]

A number of methods for the preparation of spherical silver nanoparticles have been developed. Organic-based procedures involving the steric stabilization of such nanomaterials with molecules such as alkanethiols have provided an excellent route for the preparation of highly monodisperse, well-ordered nanoparticles, although one weakness of this method lies in the difficulty in producing larger (>25 nm) particles. Aqueous methods, such as citrate reduction, can produce larger nanomaterials, but the control over the distribution of particle size is limited. [Pg.138]


See other pages where Particle aqueous is mentioned: [Pg.246]    [Pg.208]    [Pg.159]    [Pg.869]    [Pg.60]    [Pg.406]    [Pg.76]    [Pg.242]    [Pg.79]    [Pg.738]    [Pg.229]    [Pg.40]    [Pg.985]   
See also in sourсe #XX -- [ Pg.306 , Pg.308 , Pg.309 ]




SEARCH



© 2024 chempedia.info