Cobalt sampling

What is the number of 60Co atoms produced in a 10-mg sample of cobalt metal exposed for 2 min to a thermal neutron flux of 2 x 1013 n/cm2-s in a reactor The cross section for producing 10.5-min 60Com is 16 bams, while the cross section for producing 5.3 y 60Co is 20 bams. What is the disintegration rate of the cobalt sample 4 h after the end of the irradiation ... 

Cobalt Samples. RUSS LAPPA/ SCIENCE SOURCE, NATIONAL AUDUBON SOCIETY COLLECTION/PHOTO RESEARCHERS, INC. 

Platinum markers, applied to the cobalt samples before oxidation, were found at the metal-scale interface after reaction over the whole range of oxygen pressures... 

Figure 7 Powder x-ray diffraction patterns of cobalt samples. , (CoO)OH peaks.

BackTitrations. In the performance of aback titration, a known, but excess quantity of EDTA or other chelon is added, the pH is now properly adjusted, and the excess of the chelon is titrated with a suitable standard metal salt solution. Back titration procedures are especially useful when the metal ion to be determined cannot be kept in solution under the titration conditions or where the reaction of the metal ion with the chelon occurs too slowly to permit a direct titration, as in the titration of chromium(III) with EDTA. Back titration procedures sometimes permit a metal ion to be determined by the use of a metal indicator that is blocked by that ion in a direct titration. Eor example, nickel, cobalt, or aluminum form such stable complexes with Eriochrome Black T that the direct titration would fail. However, if an excess of EDTA is added before the indicator, no blocking occurs in the back titration with a magnesium or zinc salt solution. These metal ion titrants are chosen because they form EDTA complexes of relatively low stability, thereby avoiding the possible titration of EDTA bound by the sample metal ion. 

Cobalt difluoride [10026-17-2] C0F2, is a pink solid having a magnetic moment of 4, 266 x 10 J/T (4.6 Bohr magneton) (1) and closely resembling the ferrous (Fep2) compounds. Physical properties are Hsted in Table 1. Cobalt(II) fluoride is highly stable. No decomposition or hydrolysis has been observed in samples stored in plastic containers for over three years. 

Chromium (ITT) can be analy2ed to a lower limit of 5 x 10 ° M by luminol—hydrogen peroxide without separating from other metals. Ethylenediaminetetraacetic acid (EDTA) is added to deactivate most interferences. Chromium (ITT) itself is deactivated slowly by complexation with EDTA measurement of the sample after Cr(III) deactivation is complete provides a blank which can be subtracted to eliminate interference from such ions as iron(II), inon(III), and cobalt(II), which are not sufficiently deactivated by EDTA (275). 

Ocean Basins. Known consohdated mineral deposits in the deep ocean basins are limited to high cobalt metalliferous oxide cmsts precipitated from seawater and hydrothermal deposits of sulfide minerals which are being formed in the vicinity of ocean plate boundaries. Technology for drilling at depth in the seabeds is not advanced, and most deposits identified have been sampled only within a few centimeters of the surface. 

Spectrophotometric deterrnination at 550 nm is relatively insensitive and is useful for the deterrnination of vitamin B 2 in high potency products such as premixes. Thin-layer chromatography and open-column chromatography have been appHed to both the direct assay of cobalamins and to the fractionation and removal of interfering substances from sample extracts prior to microbiological or radioassay. Atomic absorption spectrophotometry of cobalt has been proposed for the deterrnination of vitamin B 2 in dry feeds. Chemical methods based on the estimation of cyanide or the presence of 5,6-dimethylben2irnida2ole in the vitamin B 2 molecule have not been widely used. 

Color. Many water samples have a yellow to brownish-yeUow color which is caused by natural substances, eg, leaves, bark, humus, and peat material. Turbidity in a sample can make the measurement of color uncertain and is usually removed by centrifiigation prior to analysis. The color is usually measured by comparison of the sample with known concentrations of colored solutions. A platinum—cobalt solution is used as the standard, and the unit of color is that produced by 1 mg/L platinum as chloroplatinate ion. The standard is prepared from potassium chloroplatinate (K PtCl ) and cobalt chloride (C0CI26H2O). The sample may also be compared to suitably caUbrated special glass color disks. 

Assay of beryUium metal and beryUium compounds is usuaUy accompHshed by titration. The sample is dissolved in sulfuric acid. Solution pH is adjusted to 8.5 using sodium hydroxide. The beryUium hydroxide precipitate is redissolved by addition of excess sodium fluoride. Liberated hydroxide is titrated with sulfuric acid. The beryUium content of the sample is calculated from the titration volume. Standards containing known beryUium concentrations must be analyzed along with the samples, as complexation of beryUium by fluoride is not quantitative. Titration rate and hold times ate critical therefore use of an automatic titrator is recommended. Other fluotide-complexing elements such as aluminum, sUicon, zirconium, hafnium, uranium, thorium, and rate earth elements must be absent, or must be corrected for if present in smaU amounts. Copper-beryUium and nickel—beryUium aUoys can be analyzed by titration if the beryUium is first separated from copper, nickel, and cobalt by ammonium hydroxide precipitation (15,16). 

Thermal Properties. The thermal stabiUty of cellulose esters is deterrnined by heating a known amount of ester in a test tube at a specific temperature a specified length of time, after which the sample is dissolved in a given amount of solvent and its intrinsic viscosity and solution color are deterrnined. Solution color is deterrnined spectroscopically and is compared to platinum—cobalt standards. Differential thermal analysis (dta) has also been reported as a method for determining the relative heat stabiUty of cellulose esters (127). 

The influence of flow rates of eluent and sample solution, amount of ligand, types and least amount of eluent for elution of Cobalt ion from column were investigated. 

The effects of vaiious cationic interferences on percent recovery of Cobalt were studied. The method was successfully applied for the determinations of Cobalt ion from synthetic and water samples. 

Except for arsenic, chromium, and cobalt where the number of samples was 1245. 

Samples Analyzed by Inductively Coupled Plasma (ICP) Metals — Where two or more of the following analytes are requested on the same filter, an ICP analysis may be conducted. However, the Industrial Hygienist should specify the metals of interest in the event samples cannot be analyzed by the ICP method. A computer print-out of the following 13 analytes may be typically reported Antimony, Beryllium, Cadmium, Chromium, Cobalt, Copper, Iron, Lead, Manganese, Molybdenum, Nickel, Vanadium, Zinc. Arsenic — Lead, cadmium, copper, and iron can be analyzed on the same filter with arsenic. 

Figure 3 Non-local layer dependent conductivity for one spin channel for antiparallel alignment of the cobalt moments. This spin channel is locally the majority in the cobalt on the left side of the sample.

Edwards e/a/. carried out controlled potential, slow strain-rate tests on Zimaloy (a cobalt-chromium-molybdenum implant alloy) in Ringer s solution at 37°C and showed that hydrogen absorption may degrade the mechanical properties of the alloy. Potentials were controlled so that the tensile sample was either cathodic or anodic with respect to the metal s free corrosion potential. Hydrogen was generated on the sample surface when the specimen was cathodic, and dissolution of the sample was encouraged when the sample was anodic. The results of these controlled potential tests showed no susceptibility of this alloy to SCC at anodic potentials. 

Theory. Conventional anion and cation exchange resins appear to be of limited use for concentrating trace metals from saline solutions such as sea water. The introduction of chelating resins, particularly those based on iminodiacetic acid, makes it possible to concentrate trace metals from brine solutions and separate them from the major components of the solution. Thus the elements cadmium, copper, cobalt, nickel and zinc are selectively retained by the resin Chelex-100 and can be recovered subsequently for determination by atomic absorption spectrophotometry.45 To enhance the sensitivity of the AAS procedure the eluate is evaporated to dryness and the residue dissolved in 90 per cent aqueous acetone. The use of the chelating resin offers the advantage over concentration by solvent extraction that, in principle, there is no limit to the volume of sample which can be used. 

Sample Number Molyb- denum Nickel Cobalt Iron Chro- mium Total >... 

Sample Number Molybdenum Nickel 1 Cobalt Iron Chromium ... 

The potential usefulness of x-ray emission spectrography for trace analysis is implicit in the results of approximate calculations presented in Chapter 4. Thus, it was estimated that the intensity of cobalt Ka generated under practicable conditions in a monolayer (area, 1 sq cm) of cobalt atoms might give 133 counts per second (4.16). Such a sample weighs 0.2 pg. 

Because it is desirable to see whether the calculated results in Table 10-3 are realistic, measurements were accordingly made in the authors laboratory on a General Electric XRD-5 D/S spectrograph (9.5) under conditions that minimized all errors except the counting error. Instead of comparing standard and unknown, as in Table 10-1, analytical lines for two elements, cobalt and iron, were compared because this could be done on a single sample. 

Thickness gaging, of steel strip, 69-71 use of cobalt-60 for, 291 Thick-target x-ray spectra, 6, 7, 99-101 Thin films, thickness determined by characteristic line intensity, 153 Thin samples, analysis by x-ray emission spectrography, 167... 

Color. Det color in accordance with ASTM D1209. The sample is comparedspectro-photometrically against platinum-cobalt standard solns... 

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