Formulation classification

Earlier studies at the ITRI have demonstrated the effectiveness of tin(IV) oxide, both in its anhydrous and hydrous forms, as a flame- and smoke-retardant additive for laboratory-prepared polyester resin formulations (J5j. In a recent study, carried out in collaboration with a major U.K. company, a number of inorganic tin additives have been incorporated into a commercial brominated polyester resin. Although this resin, which contains 28% by weight bromine, is intrinsically flame-retardant, giving samples with an 01 of ca. 41 and which meet the UL94-VO classification, formulations with improved flame and smoke properties are sought. 

During the formulation of an oil, blending of all these components gives an extremely wide variety of products described in the classification. Nevertheless, the lubricating greases make up a special product category among them. 

Flame-Resistant Grades. Grade FR-1, paper-based laminates with a phenoHc resin binder, are similar in all properties to Grade XP, but so formulated to have at least a UL94 V-1 classification when tested according to UL94. 

The physical properties of finish removers vary considerably due to the diverse uses and requirements of the removers. Finish removers can be grouped by the principal ingredient of the formula, method of appHcation, method of removal, chemical base, viscosity, or hazardous classification. Except for method of apphcation, a paint remover formulation usually has one aspect of each group, by which it can be used for one or more appHcations. A Hst of the most common organic solvents used in finish removers has been compiled (3). Many are mentioned throughout this article others include ethyl lactate [97-64-3] propylene carbonate [108-32-7] furfural alcohol [98-01-1/, dimethyl formamide [68-12-2] tetrahydrofuran [109-99-9] methyl amyl ketone [110-43-0] dipropylene glycol methyl ether [34590-94-8] and Exxate 600, a trade name of Exxon Chemicals. 

A classification by chemical type is given ia Table 1. It does not attempt to be either rigorous or complete. Clearly, some materials could appear ia more than one of these classifications, eg, polyethylene waxes [9002-88 ] can be classified ia both synthetic waxes and polyolefins, and fiuorosihcones ia sihcones and fiuoropolymers. The broad classes of release materials available are given ia the chemical class column, the principal types ia the chemical subdivision column, and one or two important selections ia the specific examples column. Many commercial products are difficult to place ia any classification scheme. Some are of proprietary composition and many are mixtures. For example, metallic soaps are often used ia combination with hydrocarbon waxes to produce finely dispersed suspensions. Many products also contain formulating aids such as solvents, emulsifiers, and biocides. 

Unfortunately, Flynn s classification, although commonly used, is quite restrictive when discussing parallel-architecture computers. There have been several attempts to formulate more detailed classification schemes for the great variety of parallel computers now available. None of these efforts have been entirely successful, and none appear to be in general use. A discussion of representative machines from some of the more common classes follows. 

Labeling. The typical labeling classification for frit may be followed by precautionary labeling for formulations containing lead oxide, free siUca, or cadmium oxide. Special labeling for shipment to specific locaUties may also be necessary to meet local and state requirements. 

Classification Process simulation refers to the activity in which mathematical models of chemical processes and refineries are modeled with equations, usually on the computer. The usual distinction must be made between steady-state models and transient models, following the ideas presented in the introduction to this sec tion. In a chemical process, of course, the process is nearly always in a transient mode, at some level of precision, but when the time-dependent fluctuations are below some value, a steady-state model can be formulated. This subsection presents briefly the ideas behind steady-state process simulation (also called flowsheeting), which are embodied in commercial codes. The transient simulations are important for designing startup of plants and are especially useful for the operating of chemical plants. 

The PLS calibration set was built mixing in an agate mortar different amounts of Mancozeb standard with kaolin, a coadjuvant usually formulated in agrochemicals. Cluster analysis was employed for sample classification and to select the adequate PLS model acording with the characteristics of the sample matrix and the presence of other components. 

A difficulty arises in describing the precise chemical nature of many inhibitor formulations that are actually used in practice. With the advancing technology of inhibitor applications there are an increasing number of formulations that are marketed under trade names. The compositions of these are, for various reasons, frequently not disclosed. A similar problem arises in describing the composition of many inhibitor formulations used in the former Soviet Union. Here the practice is to use an abbreviated classification system and it is often difficult to trace the actual composition, although in many cases a judicious literature search will provide the required information. 

The basis of the ciystal chemical classification of tantalum and niobium fluoride compounds was first formulated by Kuznetzov and Rogachov [232]. The main tenets of the classification are as follows ... 

More developed principals of classification were formulated in [278]. The central point of the classification can be formulated as follows ... 

Thus, the formulated classification allows for the definition of the compound s crystal structure type based on its composition. In this process, the most important stage is the correct definition of the X Me ratio. 

To date there is no diagnostic test specific for rheumatoid arthritis. Revised classification criteria for the diagnosis of RA were formulated by the American College of Rheumatology [1] based on a hospital... 

This account of the kinetics of reactions between (inorganic) solids commences with a consideration of the reactant mixture (Sect. 1), since composition, particle sizes, method of mixing and other pretreatments exert important influences on rate characteristics. Some comments on experimental methods are included here. Section 2 is concerned with reaction mechanisms formulated to account for observed behaviour, including references to rate processes which involve diffusion across a barrier layer. This section also includes a consideration of the application of mechanistic criteria to the classification of the kinetic characteristics of solid-solid reactions. Section 3 surveys rate processes identified as the decomposition of a solid catalyzed by a solid. Section 4 reviews other types of solid + solid reactions, which may be conveniently subdivided further into the classes... 

Ciolino, L.A., Determination and classification of added caramel color in adulterated acerola juice formulations, J. Agric. Food Chem., 48, 1746, 1998. 

Pouton, C. Formulation of poorly water-soluble drugs for oral administration Physicochemical and physiological issues and the lipid formulation classification system. Eur. J. Pharm. Sci. 2006, 29, 278-287. 

Drilling fluids used in the upper hole sections are referred to as dispersed noninhibited systems. They are formulated from freshwater and may contain bentonite. The classification of bentonite-based muds is shown in Table 1-2. 

Defoamer formulations currently contain numerous ingredients to meet the diverse requirements for which they are formulated. Various classification approaches are possible, including classification by application, physical form of the defoamer, and the chemical type of the defoamer. In general, defoamers contain a variety of active ingredients, both in solid and in liquid states, and a number of ancillary agents such as emulsifiers, spreading agents, thickeners, preservatives, carrier oils, compatibilizers, solvents, and water. 

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