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Unsaturated carboxylic

It has been known for some time that certain carboxylic acids inhibit ceruloplasmin 109, 148). Curzon and Speyer 175) examined the inhibitory capacity of a number of types of organic substances including aromatic carboxylates, unsaturated aliphatic carboxylates, aromatic non-carboxylates, unsaturated... [Pg.49]

In cyclometalation reactions with metal compounds instead of the metal atoms discussed above, ligands such as hetero atom groups (e.g., bipyridines, phosphines, and carboxylates), unsaturated groups (e.g., aryl, allyl, Cp and Cp ), carbonyl groups, halogen atoms (F, Cl, Br, Cl), etc., also act as metal activators. [Pg.213]

Figure 4.3 Adsorption isotherms for a carboxylated unsaturated polymer on to aluminium and magnesium hydroxides. Determined by the change in toluene solution concentration method and normalised to the specific surface area of the aluminium... Figure 4.3 Adsorption isotherms for a carboxylated unsaturated polymer on to aluminium and magnesium hydroxides. Determined by the change in toluene solution concentration method and normalised to the specific surface area of the aluminium...
Important initiators and accelerators chlorinated water, conjugated carboxylic unsaturations, products of photooxidation, titanium dioxide, zinc oxide, derivatives of anthraquinone, oxyethylsulfonic red and yellow, monochlo-rotriazine red and yellow, copper compounds ... [Pg.225]

Later findings have modified the rule, especially when the carbon atoms concerned are connected with carbonyl- or carboxyl-groups, but it still holds good for monohydric unsaturated alcohols. [Pg.162]

Kolbe reaction The pre >aration of saturated or unsaturated hydrocarbons by the electrolysis of solutions of the alkali salts of aliphatic carboxylic acids. Thus, ethanoic acid gives ethane,... [Pg.232]

However, the term saturated is often applied to compounds containing double or triple bonds which do not easily undergo addition reactions. Thus ethanoic acid is termed a saturated carboxylic acid and acetonitrile a saturated nitrile, whereas a Schiff base is considered to be unsaturated. [Pg.352]

Amino-aromatic carboxylic acids Unsaturated aromatic acid... [Pg.328]

Electrolysis, under similar conditions, of a mixture of two carboxylic acids RCOOH and R COOH leads, in addition to normal coupling products R—R and R —R, to cross coupling R—R. If a mixture of a saturated carboxylic acid and a half ester of an ato-dicarboxylic acid is electrolysed, there are three main products, viz., a hydrocarbon (I), a mono-ester (II), and a di-ester (HI) and these are readily separable by distillation. Some unsaturated ester (IV) is often present in small quantity. [Pg.938]

The reductive coupling of aldehydes or ketones with 01, -unsaturated carboxylic esters by > 2 mol samarium(II) iodide (J.A. Soderquist, 1991) provides a convenient route to y-lactones (K. Otsubo, 1986). Intramolecular coupling of this type may produce trans-2-hy-droxycycloalkaneacetic esters with high stereoselectivity, if the educt is an ( )-isomer (E.J. Enholm, 1989 A, B). [Pg.69]

Another useful route to cyciopentanes is the ring contraction of 2-bromo-cydohexanones by a Favorskii rearrangement to give csrdopcntanecarboxylic acids. If a 0 dibromoketones are used, ring opening of the intermediate cydopropanone leads selectively to, y-unsaturated carboxylic acids (S.A, Achmad, 1963, 1965 J. Wolinsky, 1965). [Pg.84]

Hydrides are available in many molecular sizes and possessing different reactivities. LiAIH reduces most unsaturated groups except alkenes and alkynes. NaBH is less reactive and reduces only aldehydes and ketones, but usually no carboxylic acids or esters (N.G. Gaylord, 1956 A. Haj6s, 1979). [Pg.96]

The intramolecular reaction oF allcenes with various O and N functional groups offers useful synthetic methods for heterocycles[13,14,166]. The reaction of unsaturated carboxylic acids affords lactones by either exo- or endo-cyclization depending on the positions of the double bond. The reaction of sodium salts of the 3-alkenoic acid 143 and 4-alkenoic acid 144 with Li2PdCl4 affords mostly five-membcrcd lactones in 30-40% yields[167]. Both 5-hexe-noic acid (145) and 4-hexenoic acid (146) are converted to five- or six-mem-bered lactones depending on the solvents and bases[168]. Conjugated 2,4-pentadienoic acid (147) is cyclized with Li2PdCl4 to give 2-pyrone (148) in water[i69]. [Pg.41]

Diene carboxylates can be prepared by the reaction of alkenyl halides with acrylates[34]. For example, pellitorine (30) is prepared by the reaction of I-heptenyl iodide (29) with an acrylate[35]. Enol triflates are reactive pseudo-halides derived from carbonyl compounds, and are utilized extensively for novel transformations. The 3,5-dien-3-ol triflate 31 derived from a 4,5-unsaturated 3-keto steroid is converted into the triene 32 by the reaction of methyl acrylate[36]. [Pg.132]

Formation of carboxylic acids ami their derivatives. Aryl and alkenyl halides undergo Pd-catalyzed carbonylation under mild conditions, offering useful synthetic methods for carbonyl compounds. The facile CO insertion into aryl- or alkenylpalladium complexes, followed by the nucleophilic attack of alcohol or water affords esters or carboxylic acids. Aromatic and a,/ -unsaturated carboxylic acids or esters are prepared by the carbonylation of aryl and alkenyl halides in water or alcohols[30l-305]. [Pg.188]

Carboxylic acids are produced in water. Selection of solvents is crucial and the carbonylation of the enol triflate 480 can be carried out in aqueous DMF, and that of the aryl triflate 481 in aqueous DMSO using dppf as a ligand[328,334]. The carbonylation of the enol triflate 482 to form the a, 0. unsaturated acid 483 using dppf as a ligand in aqueous DMF has been applied in the total synthesis of multifunctionalized glycinueclepin[335]. [Pg.194]

J-unsaturated ester is formed from a terminal alkyne by the reaction of alkyl formate and oxalate. The linear a, /J-unsaturated ester 5 is obtained from the terminal alkyne using dppb as a ligand by the reaction of alkyl formate under CO pressure. On the other hand, a branehed ester, t-butyl atropate (6), is obtained exclusively by the carbonylation of phenylacetylene in t-BuOH even by using dppb[10]. Reaction of alkynes and oxalate under CO pressure also gives linear a, /J-unsaturated esters 7 and dialkynes. The use of dppb is essen-tial[l 1]. Carbonylation of 1-octyne in the presence of oxalic acid or formic acid using PhiP-dppb (2 I) and Pd on carbon affords the branched q, /J-unsatu-rated acid 8 as the main product. Formic acid is regarded as a source of H and OH in the carboxylic acids[l2]. [Pg.473]

Prostaglandins arise from unsaturated C20 carboxylic acids such as arachidonic acid (see Table 26 1) Mammals cannot biosynthesize arachidonic acid directly They obtain Imoleic acid (Table 26 1) from vegetable oils m their diet and extend the car bon chain of Imoleic acid from 18 to 20 carbons while introducing two more double bonds Lmoleic acid is said to be an essential fatty acid, forming part of the dietary requirement of mammals Animals fed on diets that are deficient m Imoleic acid grow poorly and suffer a number of other disorders some of which are reversed on feed mg them vegetable oils rich m Imoleic acid and other polyunsaturated fatty acids One function of these substances is to provide the raw materials for prostaglandin biosynthesis... [Pg.1080]

Icosanoids (Section 26 6) A group of naturally occurring com pounds derived from unsaturated C20 carboxylic acids Imide (Section 20 16) Compound of the type... [Pg.1286]

The presence of the unsaturated substituent along this polyester backbone gives this polymer crosslinking possibilities through a secondary reaction of the double bond. These polymers are used in paints, varnishes, and lacquers, where the ultimate cross-linked product results from the oxidation of the double bond as the coating cures. A cross-linked polyester could also result from reaction (5.J) without the unsaturated carboxylic acid, but the latter would produce a gel in which the entire reaction mass solidified and is not as well suited to coatings applications as the polymer that crosslinks upon drying. ... [Pg.300]

Pentenamer Ionomers. Unsaturated polypentenamer elastomers have been derivatized by post-synthesis reactions (72—74). Phosphonate, thioglycolate, sulfonate, and carboxylate derivatives have been prepared and converted into ionomers. [Pg.409]

Interest in synthetic naphthenic acid has grown as the supply of natural product has fluctuated. Oxidation of naphthene-based hydrocarbons has been studied extensively (35—37), but no commercially viable processes are known. Extensive purification schemes must be employed to maximize naphthene content in the feedstock and remove hydroxy acids and nonacidic by-products from the oxidation product. Free-radical addition of carboxylic acids to olefins (38,39) and addition of unsaturated fatty acids to cycloparaffins (40) have also been studied but have not been commercialized. [Pg.511]

Reaction conditions depend on the reactants and usually involve acid or base catalysis. Examples of X include sulfate, acid sulfate, alkane- or arenesulfonate, chloride, bromide, hydroxyl, alkoxide, perchlorate, etc. RX can also be an alkyl orthoformate or alkyl carboxylate. The reaction of cycHc alkylating agents, eg, epoxides and a2iridines, with sodium or potassium salts of alkyl hydroperoxides also promotes formation of dialkyl peroxides (44,66). Olefinic alkylating agents include acycHc and cycHc olefinic hydrocarbons, vinyl and isopropenyl ethers, enamines, A[-vinylamides, vinyl sulfonates, divinyl sulfone, and a, P-unsaturated compounds, eg, methyl acrylate, mesityl oxide, acrylamide, and acrylonitrile (44,66). [Pg.109]

Siace the mid 1950s, tall oil fatty acids (TOFA) have become available ia good quaUties and large quantities (see Carboxylic acids, fatty acids from TALL oil). Refined grades of TOFA have degrees of unsaturation rivaling that of soya acids. Siace it is a year-rouad by-product from the paper iadustry, its... [Pg.34]

Carboxylate soaps are most commonly formed through either direct or indirect reaction of aqueous caustic soda, ie, alkaH earth metal hydroxides such as NaOH, with fats and oils from natural sources, ie, triglycerides. Fats and oils are typically composed of both saturated and unsaturated fatty acid molecules containing between 8 and 20 carbons randomly linked through ester bonds to a glycerol [56-81-5] backbone. Overall, the reaction of caustic with triglyceride yields glycerol (qv) and soap in a reaction known as saponification. The reaction is shown in equation 1. [Pg.150]

The principal constituents of rosin (qv) are abietic and related acids. Tall oil (qv) is a mixture of unsaturated fatty and aHcycHc acids of the abietic family. Refined tall oil may be high in rosin acids or unsaturated acids, depending on the refining process. Ethoxylates of rosin acids, eg, dehydro abietic acid, are similar to fatty acid ethoxylates in surfactant properties and manufacture, except for thek stabiHty to hydrolysis. No noticeable decomposition is observed when a rosin ester of this type is boiled for 15 min in 10% sulfuric acid or 25% sodium hydroxide (90). Steric hindrance of the carboxylate group associated with the aHcycHc moiety has been suggested as the cause of this unexpectedly great hydrolytic stabiHty. [Pg.250]


See other pages where Unsaturated carboxylic is mentioned: [Pg.253]    [Pg.470]    [Pg.28]    [Pg.7]    [Pg.91]    [Pg.96]    [Pg.253]    [Pg.470]    [Pg.28]    [Pg.7]    [Pg.91]    [Pg.96]    [Pg.133]    [Pg.167]    [Pg.173]    [Pg.412]    [Pg.70]    [Pg.388]    [Pg.498]    [Pg.1102]    [Pg.711]    [Pg.117]    [Pg.482]    [Pg.36]    [Pg.43]    [Pg.535]    [Pg.256]   
See also in sourсe #XX -- [ Pg.650 ]

See also in sourсe #XX -- [ Pg.37 ]




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A, 3-unsaturated carboxylic acids and

A, P-unsaturated carboxylic acid derivatives

A,/?-unsaturated carboxylic

A,/?-unsaturated carboxylic ester

Addition of Carboxylic Acids to Unsaturated Compounds

Addition of halogen to unsaturated carboxylic acids

Anionic rearrangement unsaturated carboxylic acids

Asymmetric hydrogenation of unsaturated carboxylic acids

Carboxylic acids compounds, Unsaturated carbonyl

Carboxylic acids unsaturated

Carboxylic acids unsaturated analogues

Carboxylic acids unsaturated, esterification

Carboxylic acids, unsaturated Perkin reaction

Carboxylic acids, unsaturated degradative oxidation

Carboxylic acids, unsaturated dehydrative cyclization

Carboxylic acids, unsaturated hydroxylation

Carboxylic acids, unsaturated via Friedel-Crafts reaction

Carboxylic esters unsaturated, conjugated additions

Favorskii rearrangement unsaturated carboxylic acids

Fluoro-a,p-unsaturated carboxylic acids

From unsaturated carboxylic acids

Hydrocarbons, unsaturated catalytic carboxylation

Hydrogenation of unsaturated carboxylic acid

Lactones From unsaturated carboxylic acids

Lactones unsaturated carboxylic acids

Polymerization unsaturated carboxylic acids

Prochiral unsaturated carboxylic acid

Rhodium unsaturated carboxylic acid

Ruthenium-catalyzed hydrogenation unsaturated carboxylic acids

Unsaturated Carboxylic Acids and Related Compounds

Unsaturated carbonyl compounds) From carboxylic acids

Unsaturated carboxylic acid derivates

Unsaturated carboxylic acid derivative

Unsaturated carboxylic acids asymmetric hydrogenation

Unsaturated carboxylic acids epoxidation

Unsaturated carboxylic acids hydrogenation

Unsaturated carboxylic acids lactonizations

Unsaturated carboxylic acids oxidative cleavage

Unsaturated carboxylic acids structural effects

Unsaturated carboxylic acids synthesis

Unsaturated carboxylic acids, Favorskii

Unsaturated carboxylic acids, acylation

Unsaturated carboxylic acids, cyclization

Unsaturated carboxylic acids, lithium salts

Unsaturated carboxylic acids, reactions

Unsaturated carboxylic acids, reactions with phosphites

Unsaturated carboxylic add

Unsaturated carboxylic esters

Unsaturated carboxylic esters acylation

Unsaturated carboxylic esters alkylation

Unsaturated carboxylic esters compounds

Unsaturated carboxylic esters condensation

Unsaturated carboxylic esters epoxidation

Unsaturated carboxylic esters formation

Unsaturated carboxylic esters metal hydride

Unsaturated carboxylic esters metathesis

Unsaturated carboxylic esters reaction

Unsaturated carboxylic esters rearrangement

Unsaturated carboxylic esters synthesis

Unsaturated carboxylic esters with active hydrogen

Unsaturated carboxylic esters with aldehydes

Unsaturated carboxylic esters with ketones

Unsaturated carboxylic esters with organometallic

Unsaturated compounds carboxylic adds

Unsubstituted Diorganotin Carboxylates of Heterocyclic and Unsaturated Acids

Wittig reaction Unsaturated carboxylic acid synthesis

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