Bottles polyester

Beer/wine bottles, polyester, 20 52-53 Beeswax, 26 207 alcohols from, 2 2 cosmetically useful lipid, 7 833t in cosmetic molded sticks, 7 840t in dental waxes, 3 296 in eye makeup, 7 862 Beet juice... 

In 1993, collaboration between Patagonia and Malden Mills (now Polartec) led to the early development of recycled polyester fibre (from Wellman Inc.) for use in Synchilla fleece made from plastic soda bottles that diverted waste from landfills. Later, PCR filament yam was made for linings and shell fabrics from 30% to 50% post-consumer materials (bottles, polyester uniforms, tents and garments) with the remainder sourced from post-industrial waste. Clothes, at end of life, if constituted from one fibre type, can be recyclable. In theory, consumers may return a polyester garment to be forwarded to a processor to be re-made into fibre or downgraded to other forms of plastic. 

Bio-PET Popularity of bio-PET is due to its successful application in beverage bottles. Polyester is made by polycondensation of EG with terephthalic acid [TPA]. Bio-based EG is made from molasses, sugarcane, switchgrass, and bagasse via their fermentation into ethanol. Using this bio-EG with fossil fuel-based TPA, a PET that is partially bio-based is obtained. The PlantBottle by Coca-Cola in 2009 is made using this partly (22.5%) bio-based resin. The Bio-PET is recyclable. 

The drying of a virgin PET resin and reground PET flakes at temperature levels of 160-180°C to below 0.005% moisture content is essential for the production of amorphous multilayer polyester bottles. Polyester is an effective desiccant. The water absorption depends on a relative humidity, residence time, temperature, and dimension of the flakes. 

The third, and fastest growing, area of isophthahc acid use is in other types of polymers, primarily as a minor comonomer with terephthahc acid in saturated polyesters. Over 20% of the isophthahc acid is sold in this apphcation. One rapidly expanding use is in polyester beverage bottles where addition of up to 3% isophthahc acid to the terephthahc acid allows faster production of more complex shapes. In this way, single piece bottles can be made, vs a round-bottomed bottle that needs a separate base cup. Fibers are also modified with isophthahc acid. 

R = (CH2 )2) and terephthaUc acid (R = ) is familiar in the form of soda bottles, recording tape, and polyester fiber (see Fibers, polyester). 

Since the last edition several new materials have been aimounced. Many of these are based on metallocene catalyst technology. Besides the more obvious materials such as metallocene-catalysed polyethylene and polypropylene these also include syndiotactic polystyrenes, ethylene-styrene copolymers and cycloolefin polymers. Developments also continue with condensation polymers with several new polyester-type materials of interest for bottle-blowing and/or degradable plastics. New phenolic-type resins have also been announced. As with previous editions I have tried to explain the properties of these new materials in terms of their structure and morphology involving the principles laid down in the earlier chapters. 

Labels for soft drink bottles, shampoo bottles, plastic food containers and the like, require high adhesion to materials like polyester and polyolefins. Once applied, the adhesive may have to withstand repeated flexing, freezing, water and other fluid spillage, while maintaining aesthetic appearance. 

Many other polymers compete with cellophane such as polyethylene which is extruded as a tough film or in greater thickness as a nonbreakable bottles. Vinyl products used in films are polystyrene, polyesters, and nylon. A chemical derivative from nature rubber, chlorinated rubber, gives films of extraordinary stretch ability. 

Current world production of ethylene glycol is approximately 15 billion pounds. Most of that is used for producing polyethylene terephtha-late (PET) resins (for fiber, film, bottles), antifreeze, and other products. Approximately 50% of the world EG was consumed in the manufacture of polyester fibers and another 25% went into the antifreeze. 

Problem 31.8 I Polyfethylene terephthalate), or PET, is a polyester used to make soft-drink bottles. 

Perhaps the most important polyester is polyethylene terephthalate), commonly known as PET (or PETE 1 on plastic beverage bottles). The annual production of PET in the United States is of the order of 108 kg (105 metric tons). Much of this is converted into fabric (trade name, Dacron) or magnetically coated film (Mylar). 

A description is given of a comparative study of the glycolysis of PETP waste soft drinks bottles by various mixtures of EG and DEG with subsequent polyesterification of the glycolysed products by maleic anhydride in order to obtain unsaturated polyesters suitable for the production of varnishes. The processing characteristics such as viscosity, exotherm temperatures of curing, compatibility of resins with monomers was investigated with respect to the type and amount of reactive monomers. The mechanical properties of varnishes produced were analysed. 13 refs. 

Groupe TBI is investing about FFr3m to build a 15,0001/ y aromatic polyester polyols plant on a greenfield site at Issoire, near Lyons. The novel, patented process uses postconsumer waste bottles made from PETP as feedstock. PU and modified PIR foams made using the APPs have excellent fire performance and good dimensional stability. GROUPE TBI... 

Over 4 billion PETP bottles will be available for colleetion across Europe in 1999. PUR Products has introduced technology into the UK which involves glycolysis of postconsumer PETP into materials for the manufacture of rigid urethane foams for building insulation. This application offers a substantial new market for aromatic polyester polyols derived from glycolised PETP recyclate. PUR(PRODUCTS)LTD. 

Both terephthalic acid (TPA) and dimethyl terephthalate (DMT) are used exclusively for the manufacture of polyesters for textile fibers (e.g,. Dacron ), films, soft-drink bottles, and engineering resins for automotive applications. The glycol used for most TPA-based polyesters is ethylene glycol. The polyester is then known as polyethylene terephthalate, or PET. 

The functional groups that typically participate in this type of polymerization are carboxyl, amine, and alcohol groups. Examples of step growth polymers include polyesters and nylons, which are often spun into fibers used to manufacture carpeting and fabrics, and polycarbonates, which are converted into compact discs, jewel cases, and the large bottles used in water coolers. 

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