Battery, defined

Primary batteries, 3 434—469. See also Alkaline primary cells Batteries Carbon-zinc cells Lithium primary cells Secondary batteries defined, 3 409... 

The lEC Designation System for Primary Batteries Defined in I EC Standard 60 086 1... 

Most battery electrodes are porous stmctures in which an interconnected matrix of soHd particles, consisting of both nonconductive and electronically conductive materials, is filled with electrolyte. When the active mass is nonconducting, conductive materials, usually carbon or metallic powders, are added to provide electronic contact to the active mass. The soHds occupy 50% to 70% of the volume of a typical porous battery electrode. Most battery electrode stmctures do not have a well defined planar surface but have a complex surface extending throughout the volume of the porous electrode. MacroscopicaHy, the porous electrode behaves as a homogeneous unit. 

Self-Discharge Processes. The shelf life of the lead—acid battery is limited by self-discharge reactions, first reported in 1882 (46), which proceed slowly at room temperature. High temperatures reduce shelf life significantly. The reactions which can occur are well defined (47) and self-discharge rates in lead—acid batteries having immobilized electrolyte (48) and limited acid volumes (49) have been measured. 

The fixed capital estimate depends on the definition of the plant. A grass-roots plant is a complete faciUty at a new location, including all utihties, services, storage faciUties, land, and improvements. If a process plant is located at an existing processing complex, it can usually share some of these auxihary faciUties. A battery-limits plant is defined as the process faciUty itself, so that the auxiUaries, off-site, and land-related items are excluded from the fixed capital estimation. However, a battery-limits plant maybe assigned allocated capital charges for the share of common utihty and service faciUties used by the plant. 

Total Capital Cost The installed cost of the fixed-capital investment Cpc is obviously an essential item which must be forecast before an investment decision can be made. It forms pai4 of the total capital investment Cfc, defined by Eq. (9-14). The fixed-capital investment is usually regarded as the capital needed to provide all the depreciable facihties. It is sometimes divided into two classes by defining battery limits and auxiliaiy facilities for the project. The boundary for batteiy limits includes all manufacturing equipment but excludes administrative offices, storage areas, utihties, and other essential and nonessential auxihaiy facilities. 

Base equipment includes all equipment within the battery limits whose cost is as significant as the cost of a pump. For example, storage tanks, knockout drums, accumulators, heat exchangers, and pumps are classed as main-plant items (MPl). Early in the development of the process-flow diagram, it is advisable to increase the estimated (MPl) cost by 10 to 20 percent to allow for later additions. When the scope of the process has been well defined, (MPl) costs should be increased by 1 to 10 percent. 

Total Offsite Costs. The offsite costs can range from 20% to 50% of the total cost of the project. If a preliminary built-up estimate of the offsites is less than 30% of the total costs, it should be suspect. Unless the offsites are very well defined, it would be better to use a factor of 50% to 75% of battery limits estimate as the offsite figure. 

Work (W) is done by a battery whenever it pushes a positive charge (+q) away from the ( + ) terminal (through space outside the batteiy) to the (-) terminal. The potential or emf or voltage (V) of a batteiy is defined as the work done in this process divided by... 

An important property of this or any electrical circuit is the rate that charge moves past a place in the circuit (e.g., out from or into a battery terminal). The electrical current (I) is defined to be the charge (Q) that flows, divided by the time (t) required for the flow I = Q/t. In S.I. units the current (I) is in amperes (A). 

Viewing things from the perspective of his physical theory of contact electricity, Volta was intrigued by the apparently endless power of the battery to keep the electric fluid in motion without the mechanical actions needed to operate the classical, friction, electrostatic machine, and the electrophorus. He called his batteiy alternately the artificial electric organ, in homage to the torpedo fish that had supplied the idea, and the electromotive apparatus, alluding to the perpetual motion (his words) of the electric fluid achieved by the machine. To explain that motion Volta relied, rather than on the concepts of energy available around 1800, on his own notion of electric tension. He occasionally defined tension as the effort each point of an electrified body makes to get rid of its electricity but above all he confidently and consistently measured it with the electrometer. 

Another important parameter for describing a secondary electrochemical cell is the achievable number of cycles or the lifetime. For economic and ecological reasons, systems with a high cycle life are preferred. The number of cycles indicates how often a secondary battery can be charged and discharged repeatedly before a lower limit (defined as a failure) of the capacity is reached. This value is often set at 80 percent of the nominal capacity. To compare different battery systems, besides the number of cycles, the depth of discharge must be quoted. 

Karigl [71] defined a format diffusion coefficient for bromine transport through a poly thy lene separator of a zinc-flow battery by considering the separator a diffusion layer. A value of Dsep(Br3 ) = 2.77 10 10 m2 s l was obtained. 

The categories (AB2C1) to (AB2C3) may be similarly subdivided by considering the different cathode materials and thus defining a particular battery system. 

A question of practical interest is the amount of electrolyte adsorbed into nanostructures and how this depends on various surface and solution parameters. The equilibrium concentration of ions inside porous structures will affect the applications, such as ion exchange resins and membranes, containment of nuclear wastes [67], and battery materials [68]. Experimental studies of electrosorption studies on a single planar electrode were reported [69]. Studies on porous structures are difficult, since most structures are ill defined with a wide distribution of pore sizes and surface charges. Only rough estimates of the average number of fixed charges and pore sizes were reported [70-73]. Molecular simulations of nonelectrolyte adsorption into nanopores were widely reported [58]. The confinement effect can lead to abnormalities of lowered critical points and compressed two-phase envelope [74]. 

EEC Directive defining the detailed arrangements for the system of specific information relating to dangerous preparations with respect to the implementation of 88/379/EEC 91/157/EEC Directive on batteries and accumulators... 

Federal universal wastes In the United States, the universal wastes (such as batteries, pesticides, thermostats, lamps, and mercury-containing wastes) are decided and legally defined by the U.S. EPA. 

Battery limits investment The battery limit is a geographic boundary that defines the manufacturing area of the process. This is that part of the manufacturing system that converts raw materials into products. It includes process equipment and buildings or structures to house it but excludes boiler-house facilities, site storage, pollution control, site infrastructure, and so on. The term battery limit... 

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