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Atomisation, heat

Purge gas Dry time Dry temperature Pre-atomisation heating time Pre-atomisation heating temperature Atomisation time Atomisation temperature... [Pg.296]

We have seen that in a metal the atoms are close-packed, i.e. each metal atom is surrounded by a large number of similar atoms (often 12, or 8). The heat required to break up 1 mole of a metal into its constituent atoms is the heat of atomisation or heat of sublimation. Values of this enthalpy vary between about 80 and 800 kJ. for metals in their standard states these values indicate that the bonds between metal atoms can vary from weak to very strong. There is a rough proportionality between the m.p. of a metal and its heat of atomisation. so that the m.p. gives an approximate measure of bond strength. [Pg.58]

The enthalpy changes AH involved in this equilibrium are (a) the heat of atomisation of the metal, (b) the ionisation energy of the metal and (c) the hydration enthalpy of the metal ion (Chapter 3). [Pg.97]

Heat of atomisation Sum of 1st and 2nd ionisation energies Hydration enthalpy AH... [Pg.97]

Table 14.2 shows that all three elements have remarkably low melting points and boiling points—an indication of the weak metallic bonding, especially notable in mercury. The low heat of atomisation of the latter element compensates to some extent its higher ionisation energies, so that, in practice, all the elements of this group can form cations in aqueous solution or in hydrated salts anhydrous mercuryfll) compounds are generally covalent. [Pg.434]

A more useful quantity for comparison with experiment is the heat of formation, which is defined as the enthalpy change when one mole of a compound is formed from its constituent elements in their standard states. The heat of formation can thus be calculated by subtracting the heats of atomisation of the elements and the atomic ionisation energies from the total energy. Unfortunately, ab initio calculations that do not include electron correlation (which we will discuss in Chapter 3) provide uniformly poor estimates of heats of formation w ith errors in bond dissociation energies of 25-40 kcal/mol, even at the Hartree-Fock limit for diatomic molecules. [Pg.105]

Airless Spraying the process of atomisation of paint by forcing it through an orifice at high pressure. This effect is often aided by the vaporisation of the solvents especially if the paint has been previously heated. The term is not generally applied to those electrostatic spraying processes which do not use air for atomisation. [Pg.682]

Catalyst characterization - Characterization of mixed metal oxides was performed by atomic emission spectroscopy with inductively coupled plasma atomisation (ICP-AES) on a CE Instraments Sorptomatic 1990. NH3-TPD was nsed for the characterization of acid site distribntion. SZ (0.3 g) was heated up to 600°C using He (30 ml min ) to remove adsorbed components. Then, the sample was cooled at room temperatnre and satnrated for 2 h with 100 ml min of 8200 ppm NH3 in He as carrier gas. Snbseqnently, the system was flashed with He at a flowrate of 30 ml min for 2 h. The temperatnre was ramped np to 600°C at a rate of 10°C min. A TCD was used to measure the NH3 desorption profile. Textural properties were established from the N2 adsorption isotherm. Snrface area was calcnlated nsing the BET equation and the pore size was calcnlated nsing the BJH method. The resnlts given in Table 33.4 are in good agreement with varions literature data. [Pg.299]

GC-AAS has found late acceptance because of the relatively low sensitivity of the flame graphite furnaces have also been proposed as detectors. The quartz tube atomiser (QTA) [186], in particular the version heated with a hydrogen-oxygen flame (QF), is particularly effective [187] and is used nowadays almost exclusively for GC-AAS. The major problem associated with coupling of GC with AAS is the limited volume of measurement solution that can be injected on to the column (about 100 xL). Virtually no GC-AAS applications have been reported. As for GC-plasma source techniques for element-selective detection, GC-ICP-MS and GC-MIP-AES dominate for organometallic analysis and are complementary to PDA, FTIR and MS analysis for structural elucidation of unknowns. Only a few industrial laboratories are active in this field for the purpose of polymer/additive analysis. GC-AES is generally the most helpful for the identification of additives on the basis of elemental detection, but applications are limited mainly to tin compounds as PVC stabilisers. [Pg.456]

Heavy fuel oil feedstock is delivered into the suction of metering-type ram pumps which feed it via a steam preheater into the combustor of a refractory-lined flame reactor. The feedstock must be heated to 200°C in the preheater to ensure efficient atomisation in the combustor. A mixture of oxygen and steam is also fed to the combustor, the oxygen being preheated in a separate steam preheater to 210°C before being mixed with the reactant steam. [Pg.979]

Carbon black produced by the thermal decomposition of natural gas or atomised oil in a pre-heated refractory furnace where the fuel is cracked into carbon and hydrogen. The process is cyclic, two furnaces being used as one production unit, one furnace being heated up as the other is producing. [Pg.65]

In similar work, Sturgeon et al. [125] compared direct furnace methods with extraction methods for cadmium in coastal seawater samples. They could measure cadmium down to 0.1 pg/1. They used 10 pg/1 ascorbic acid as a matrix modifier. Various organic matrix modifiers were studied by Guevremont [116] for this analysis. He found citric acid to be somewhat preferable to EDTA, aspartic acid, lactic acid, and histidine. The method of standard additions was required. The standard deviation was better than 0.01 pg/1 in a seawater sample containing 0.07 pg/1. Generally, he charred at 300 °C and atomised at 1500 °C. This method required compromise between char and atomisation temperatures, sensitivity, heating rates, and so on, but the analytical results seemed precise and accurate. Nitrate added as sodium nitrate delayed the cadmium peak and suppressed the cadmium signal. [Pg.148]

A hanging mercury drop electrodeposition technique has been used [297] for a carbon filament flameless atomic absorption spectrometric method for the determination of copper in seawater. In this method, copper is transferred to the mercury drop in a simple three-electrode cell (including a counterelectrode) by electrolysis for 30 min at -0.35 V versus the SCE. After electrolysis, the drop is rinsed and transferred directly to a prepositioned water-cooled carbon-filament atomiser, and the mercury is volatilised by heating the filament to 425 °C. Copper is then atomised and determined by atomic absorption. The detection limit is 0.2 pg copper per litre simulated seawater. [Pg.174]

The sensitivity achieved should enable seawater samples to be analysed for molybdenum, because the concentration of molybdenum in seawater is usually 2.1 -18.8 pg/1. The selected temperature of 1700-1850 °C during the charring stage permits separation of the seawater matrix from the analyte prior to atomisation with the Perkin-Elmer Model 603 atomic absorption spectrometer equipped with a heated graphite atomiser (HGA-2100). [Pg.204]

Stein et al. [673] have described a simplified, sensitive, and rapid method for determining low concentrations of cadmium, lead, and chromium in estuarine waters. To minimise matrix interferences, nitric acid and ammonium nitrate are added for cadmium and lead only nitric acid is added for chromium. Then 10,20, or 50 pi of the sample or standard (the amount depending on the sensitivity required) is injected into a heated graphite atomiser, and specific atomic absorbance is measured. Analyte concentrations are calculated from calibration curves for standard solutions in demineralised water for chromium, or an artificial seawater medium for lead and cadmium. [Pg.241]

Maximum power heating, the L vov platform, gas stop, the smallest possible temperature step between thermal pretreatment and atomisation, peak area integration, and matrix modification have been applied in order to eliminate or at least reduce interferences in graphite furnace AAS. With Zeeman effect background correction, much better correction is achieved, making method development and trace metal determinations in samples containing high salt concentrations much simpler or even possible at all. [Pg.250]

A major cost in the operation of a dryer is in heating the air or gas. Frequently, the hot gases are produced by combustion of a fuel gas or atomised liquid, and considerable economy may be effected by using a combined heat and power system in which the hot gases are first passed through a turbine connected to an electrical generator. [Pg.920]

If the water were to be injected into a cold engine cylinder, the flash steam would immediately condense and there would be no pressure rise. To overcome this problem, the cylinder head and walls are heated and supply additional heat to the wet steam entering the cylinder. The atomised water droplets experience extremely high collision rates with the cylinder walls because of the explosive effect of the flash process. The tiny size of the droplets, coupled with high collision rates ensure rapid absorption of heat allowing them to be quickly converted to steam which is then heated further to superheat. [Pg.40]

All novel bioreactors attempt to increase productivity by increasing yeast cell concentration or by reducing ethanol inhibition and much work has been reported on ethanol production in fluidized beds by Bauer, Hayes, Moebus, Rottenbacher, Teuber and their co-workers aqueous glucose solutions can be atomised within a bed of yeast particles with the latent heat for vaporisation of both ethanol and... [Pg.185]

The feed system consisted of a reservoir, a plunger-type feed pump, a twin-fluid atomising nozzle (giving a round spray of angle 13° in free air) and a mini-compressor. Inert gas for the twin-fluid nozzle was drawn between the outlet of the heat exchanger and the rotameter... [Pg.200]

Concerning AFS, the atomiser can be a flame, plasma, electrothermal device or a special-purpose atomiser e.g. a heated quartz cell). Nowadays, commercially available equipment in AFS is simple and compact, specifically configured for particular applications e.g. determination of mercury, arsenic, selenium, tellurium, antimony and bismuth). Therefore, particular details about the components of the instrumentation used in AFS will not be given in this chapter. [Pg.10]


See other pages where Atomisation, heat is mentioned: [Pg.304]    [Pg.304]    [Pg.304]    [Pg.304]    [Pg.58]    [Pg.59]    [Pg.74]    [Pg.425]    [Pg.56]    [Pg.9]    [Pg.610]    [Pg.8]    [Pg.186]    [Pg.256]    [Pg.361]    [Pg.199]    [Pg.58]    [Pg.59]    [Pg.74]    [Pg.425]    [Pg.146]    [Pg.172]    [Pg.199]    [Pg.413]    [Pg.65]   
See also in sourсe #XX -- [ Pg.59 , Pg.73 , Pg.74 , Pg.75 , Pg.97 ]

See also in sourсe #XX -- [ Pg.59 , Pg.73 , Pg.74 , Pg.75 , Pg.97 ]




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