Adsorbed removal

Adsorption for gas purification comes under the category of dynamic adsorption. Where a high separation efficiency is required, the adsorption would be stopped when the breakthrough point is reached. The relationship between adsorbate concentration in the gas stream and the solid may be determined experimentally and plotted in the form of isotherms. These are usually determined under static equilibrium conditions but dynamic adsorption conditions operating in gas purification bear little relationship to these results. Isotherms indicate the affinity of the adsorbent for the adsorbate but do not relate the contact time or the amount of adsorbent required to reduce the adsorbate from one concentration to another. Factors which influence the service time of an adsorbent bed include the grain size of the adsorbent depth of adsorbent bed gas velocity temperature of gas and adsorbent pressure of the gas stream concentration of the adsorbates concentration of other gas constituents which may be adsorbed at the same time moisture content of the gas and adsorbent concentration of substances which may polymerize or react with the adsorbent adsorptive capacity of the adsorbent for the adsorbate over the concentration range applicable over the filter or carbon bed efficiency of adsorbate removal required. 

SOH represents any surface site unassociated with any species of M, SOM a metal/surface-site complex and x the apparent ratio of moles of protons released or consumed per mole of adsorbate removed from solution. 

The rate at which clean adsorbent must be added and spent adsorbent removed in order to maintain steady state may also be found from an overall balance ... 

Industrial examples of adsorbent separations shown above are examples of bulk separation into two products. The basic principles behind trace impurity removal or purification by liquid phase adsorption are similar to the principles of bulk liquid phase adsorption in that both systems involve the interaction between the adsorbate (removed species) and the adsorbent. However, the interaction for bulk liquid separation involves more physical adsorption, while the trace impurity removal often involves chemical adsorption. The formation and breakages of the bonds between the adsorbate and adsorbent in bulk liquid adsorption is weak and reversible. This is indicated by the heat of adsorption which is <2-3 times the latent heat of evaporahon. This allows desorption or recovery of the adsorbate from the adsorbent after the adsorption step. The adsorbent selectivity between the two adsorbates to be separated can be as low as 1.2 for bulk Uquid adsorptive separation. In contrast, with trace impurity removal, the formation and breakages of the bonds between the adsorbate and the adsorbent is strong and occasionally irreversible because the heat of adsorption is >2-3 times the latent heat of evaporation. The adsorbent selectivity between the impurities to be removed and the bulk components in the feed is usually several times higher than the adsorbent selectivity for bulk Uquid adsorptive separation. 

Measurement of the extent to which the adsorbent removes the adsorbate from a liquid or gaseous phase. The data is used to construct adsorption isotherms and is often fitted to a model to provide information about binding constants, adsorption maxima and other parameters, and also speciation of surface complexes. Kinetic data may also be obtained. 

Sometimes also the coverage itself can be obtained from the TDS spectra, since a suitable integration over the spectra should give the amount of adsorbate removed. 

Adsorbent heated to achieve rapid desorption and change in flowmeter signal recorded until all adsorbate removed. 

SER [Sorption Enhanced Reaction] A modification of the steam reforming process for making hydrogen, in which a selective adsorbent removes the carbon dioxide, thereby reducing the temperature required from 800 to 1000°C to 500 to 800°C Developed by Air Products and Chemicals Ltd. in 1998. 

The variety of activated carbons, carbon fiben, and carbon monoliths present on the market along with differences in the molecules to be adsorbed— removed causes that the choice of the adsorbents for a desired application becomes a difficult task. The capacities, for H2S, SO2, NO,., HCN, or VOCs removal depend on the type of carbon used (Fig. 21.3). The problem is even more complex when multicomponent adsorption is expected to occur and the regeneration options have to be considered. Usually carbon specifications... 

The adsorption density, which is the amount of adsorbate removed from the solution to the interface, can be mathematically expressed as ... 

Adsorbate the solute that is to be adsorbed (removed from the gas or liquid stream). 

Many environmentally significant pesticides are highly lipophilic and therefore relatively insoluble in water. Removal of pesticides from the hydrosphere may occur by volatilization, absorption by aquatic organisms, settling of particles to which pesticides are adsorbed. Removal by degradation processes occurs by transformation and ultimately mineralization. Photochemical decomposition of pesticides may also proceed via series of photolysis reactions - for example, photooxidation,... 

To generate adsorption data, a known amount of adsorbate in aqueous solution is mixed with a known amount of adsorbent. At equilibrium, the amount of adsorbate removed from solution is assumed to be adsorbed. Secondary reactions (such as precipitation) must be eliminated or corrected for. Precipitation is indicated in some cases by a rapid increase in apparent adsorption (disappearance from solution) with a small change in solution concentration. Three equations are commonly used to describe adsorption the Langmuir, Freundlich, and Brunauer-Emmett-Teller (BET) equations. 

SPILL CLEAN-UP use water spray to cool and disperse vapors absorb as much as possible with noncombustible materials such as dry earth or sand cover spill with activated carbon adsorbent remove all ignition sources. 

---