Amyl acetate nitrite

Pentanone, see Methyl n-propyl ketone 3- Pentanone, see Diethyl ketone Pentene, see Amylene n-Pentyl acetate, see n-Amyl acetate sec-Pentyl acetate, see sec-Amyl acetate Pentyl alcohol, see n-Amyl alcohol Pentyl amine, see n-Amylamine iso-Pentyl nitrite, see Amyl nitrite Peracetic acid (40% acetic acid 1.23 41... 

Ammonolysis, 401 Ampoules, glass. 205 n-Amylamine, 413, 417 n-Amyl acetate, 383 -Amyl alcohol, 247, 249 n-Amylbenzene, 511, 517 n-Amyl borate, 305 n-Amyl bromide, 279 tao-Amyl bromide, 279 n-Amyl chloride, 273 tao-Amyl chloride, 273 tert.-Amyl chloride, 275 n-Amyl cyanide, 407, 408 Amylene, 239 n-Amyl fluoride, 272, 289 n-Amyl iodide, 288 n-Amyl nitrite, 302, 306... 

Amoxicillin Amyl Acetate Amyl Nitrite Ascorbic Acid Benzene Benzoic Acid Beta-Carotene Butane Butyl Acetate Butyl M.ercaptan Butylated Hydroxyanisole and Butylated Hydroxytoluene Caffeine... 

Amyl Acetate Amyl Nitrite Cyanoacrylate Ethyl Acetate Isoamyl Acetate L-Aspartyl-L-Phenylalanine Methyl Ester Nitroglycerin... 

If a mixture of amyl nitrite and ethyl alcohol containing an acid catalyst is wanned, ethyl nitrite distills out. Friedel and Crafts heated ethyl acetate with amyl alcohol and amyl acetate with ethyl alcohol aijd observed alcoholysis in both cases. They also heated ethyl benzoate and amyl acetate together and obtained ethyl acetate and amyl benzoate, although this reaction was slow below 300°C. 

Ammonium nitrate Ammonium nitrite Ammonium oxalate Ammonium salicylate Ammonium sulfate Ammonium sulfide Ammonium sulfite Ammonium thiosulfate Amyl acetate Amyl alcohol Amyl chloride Amyl mercaptan Amyl naphthalene Amyl nitrate Amyl nitrite Amyl phenol Aniline hydrdochloride Aniline sulfate Aniline sulfite Animal fats Animal oils Anthraquinone Antimony sulfate Antimony tribromide Antimony trichloride Antimony trioxide Aqua regia Arsenic oxide Arsenic trichloride Arsenic trioxide Arsenic trisulfide Ascorbic acid Barium carbonate Barium chlorate Barium chloride, aqueous Barium cyanide Barium hydroxide Barium iodide Barium nitrate Barium oxide Barium peroxide Barium salts Beet sugar liquors Benzaldehyde Benzene... 

Diazoaminobenzene has been prepared by the action of sodium nitrite on aniline sulfate by the action of sodium nitrite on aniline hydrochloride by the action of sodium nitrite and sodium acetate on aniline hydrochloride by the action of ammonium nitrate and hydrogen sulfide on aniline hydrochloride in the presence of iron and by the action of amyl nitrite on aniline. ... 

Pentyl amine, see n-Amylamine Iso-Pentyl nitrite, see Amyl nitrite Peracetic acid (40% acetic acid solution)... 

In the preparation of the nitrosochloride, Wallach proposed to use pinene in glacial acetic acid and amyl nitrite. Ehestadt has recently proposed the following method, which is very simple and yields excellent results The pinene (or oil of turpentine) is diluted with its own volume of ether, the solution cooled with ice, and the gas generated hy dropping a saturated solution of sodium nitrite into concentrated hydrochloric acid passed through the solution. Fine crystals of pinene-nitrosochloride soon commence to separate out. Schimmel Co. obtained the following yields of nitrosochloride by the methods quoted —... 

Five parts of the terpene, 7 of amyl nitrite, and 12 of glacial acetic acid are mixed and cooled with ice and salt, and a mixture of 6 parts of hydrochloric acid and 6 parts of glacial acetic acid added in small quantities at a time. Five parts of alcohol are then added and the mixture allowed to stand in a freezing mixture for a itime. A mass of crystals separates, which consists of the crude nitrosochlorides. This is filtered off and washed with alcohol. When perfectly dry 100 grams of the crystals are digested with 200 c.c. of chloroform for a few moments and at once filtered. The chloroform dissolves a-nitrosochloride, which is precipitated by the addition of excess of methyl alcohol. The crude compound is filtered off, dried and digested with anhydrous ether for... 

H0.N CH.CgH3(N02).N( N).Cl mw 228.60, N 24.51% pink ndls, mp stable at 60-80° but expl on strong heating. Can be prepd from 2-nitro-4-amino-phenyl acetic acid in cold coned HC1 by reaction with amyl nitrite. On heating with ale, this eompd forms 2-nitrobenzaldehyde-anti-oxime(qv)... 

The slight solubility of yellow phosphorus in several other liquids has been notioed— e.g. ethyl chloride, ethylene chloride, chloroform, bromoform, ohloral, acetic ether, acetone aldehyde, cacodyl sulphide, allyl thiooyanate, mercury methide, valerianic acid, amyl valerate, fusel oil, benzoyl chloride, stannic chloride, ethyl nitrite, nicotine, coniine, cavutchin, styrene, aniline, quinoline, creosote, etc. J. Hartmann found that 100 grms. of bile at 38-5° dissolved 0 02424 grm. of phosphorus, and more at a higher temp. 

Alternatively, the reaction of diaminopyridines with A-nitrosodiphenylamine <67CB1646> or amyl nitrite-acetic acid (93KGS398) is especially useful for those diamines that are sparingly soluble in aqueous media. 

This compound is obtained as the amyl ester by adding sodium nitrite to the amyl ester of phenylmethylglycine-4-arsinic add in dilute sulphuric acid. It separates ftom acetic acid in colourless crystals, decomposing at 160° C. The nitroso-group is eliminated on heating with concentrated hydrochloric acid, the N-alkyl add being produced. 

Esters.— The simplest class of compounds present in essential oils are the esters or ethereal salts (p. 140). In our early discussion of these compounds in the aliphatic series it was stated that the odor and flavor of common fruits is probably due to ester compounds and that certain empirical mixtures of esters are used as artificial fruit essences. Artificial apple essence, for example, may be prepared by mixing certain proportions of ethyl nitrite, ethyl acetate and amyl valerate with chloroform, aldehyde and alcohol. An example of an essential oil which consists of a single ester is oil of wintergreen. vAdxh is the methyl ester of salicylic acid, ortho-hydroxy benzoic acid (p. 714). 

Fluorene is oxidized to fluorenone in 65-70% yield by refluxing for 3 h with sodium dichromate in acetic acid [622], and 2-methylfluorene is converted into 2-methylfluorenone via its oxime on treatment with amyl nitrite (pentyl nitrite) [452]. The methylene group between two aromatic rings is oxidized in preference to the methyl group because nitrites react only with highly activated methylene groups (equation 177). 

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