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Aromatic compounds alkenes

Ozone ALkenes, aromatic compounds, bromine, diethyl ether, ethylene, HBr, HI, nitric oxide, nitrogen dioxide, rubber, stibine... [Pg.1210]

Methanol can then be used as a starting material for the synthesis of alkenes, aromatic compounds, acetic acid, formaldehyde, and ethyl alcohol (ethanol). Synthesis gas can also be nsed to produce methane, or synthetic natrrral gas (SNG) (Demirbas, 2007) ... [Pg.13]

Incomplete combustion of gasoline and other motorfuels releases significant quantities of volatile organic compounds (VOCs) into the atmosphere. VOCs are composed of short-chained alkanes, alkenes, aromatic compounds, and a variety of other hydrocarbons. VOCs are components of air pollution and contribute to cardiac and respiratory diseases. [Pg.97]

Like alkenes, aromatic compounds show unsaturated = C—H stretching just above 3000 cm-1 (usually around 3030 cm-1). The combination of the aromatic C=C stretch around 1600 cm-1 and the = C—H stretch just above 3000 cm-1 leaves little doubt of the presence of an aromatic ring. The sample spectra labeled Compounds 4,5, and 7 in Chapter 12 (pages 539-540) show compounds containing aromatic rings. [Pg.743]

Examples of photoreactions may be found among nearly all classes of organic compounds. From a synthetic point of view a classification by chromo-phore into the photochemistry of carbonyl compounds, enones, alkenes, aromatic compounds, etc., or by reaction type into photochemical oxidations and reductions, eliminations, additions, substitutions, etc., might be useful. However, photoreactions of quite different compounds can be based on a common reaction mechanism, and often the same theoretical model can be used to describe different reactions. Thus, theoretical arguments may imply a rather different classification, based, for instance, on the type of excited-state minimum responsible for the reaction, on the number and arrangement of centers in the reaction complex, or on the number of active orbitals per center. (Cf. Michl and BonaCid-Kouteck, 1990.)... [Pg.360]

Unlike alkenes, aromatic compounds such as benzene undergo substitution reactions instead of addition reactions. Tlie most common reaction for benzene to undergo is electrophilic aromatic substitution (EAS), although in a few special cases, it can undergo nucleophilic aromatic substitution. [Pg.108]

So far all our examples have been cyclic compounds as stereochemistry is much easier to control in rings than in chains. One strategy for open chain compounds is to use a rigid structure—an alkene, aromatic compound, or ring — to set up the stereochemistry correctly and then to break down the rigid structure to reveal the open chain. [Pg.329]

Radicals generated at the cathode by either direct or indirect reduction (see also Section 2.6.5.2) have been added to alkenes, aromatic compounds, pyridinium salts, nitriles, alkynes, carbon and metals. [Pg.285]

Oxidations/hydroxylations of linactivated saturated carbons (polyunsaturated) fatty acids epoxidation and dihydroxylation of alkenes aromatic compounds (- unsaturated diols) hydroxylated compounds and aldehydes diols (and lactonization) enzyme catalyzed Baeyer-Villiger oxidations organic sulfides (sulfoxidation) Be, Mi, Mp, Po, Ra, CytP450 enzymes, monooxygenases SLO An, Nc, Po Pp (mutant strain), Ce Go, Ps Bp, Go, Ko, Ps, HLADH Ac, Ps, CHO BY, An, Ceq, Mi, Po, CPO, BSA... [Pg.179]

Volatile organic compounds include many products such as volatile hydrocarbons (alkanes, alkenes, aromatic compounds), carbonyl compounds (ketones, aldehydes), etc. In urban areas, they originate from motor vehicle exhaust gases, the evaporation of gasoline at filling stations, liquid fuels and industrial activities using solvents. Then-concentration may reach 50 ag-m in the atmosphere of large urban areas. [Pg.253]

After this introductory Chapter 1, Chapter 2 provides a proper chemical introduction to the phenomenon of chirality and to the polarimetric and spectroscopic methods of its assessment. First, the authors discuss structural asymmetry of the compounds in general terms and also a variety of structural preconditions for its appearance. Then they focus in greater detail on different classes of organic compounds, such as alkanes and cycloalkanes, alkenes, aromatic compounds, heterocyclic compounds, other compounds containing heteroatoms, and complexes. [Pg.8]

We will show here the classification procedure with a specific dataset [28]. A reaction center, the addition of a C-H bond to a C=C double bond, was chosen that comprised a variety of different reaction types such as Michael additions, Friedel-Crafts alkylation of aromatic compounds by alkenes, or photochemical reactions. We wanted to see whether these different reaction types can be discerned by this... [Pg.193]

The authors of this work were concerned chiefly with additions to alkenes, and evidence about the mechanism of aromatic nitration arises by analogy. Certain aspects of their work have been repeated to investigate whether the nitration of aromatic compounds shows the same phenomena ( 5-3-6). It was shown that solutions of acetyl nitrate in acetic anhydride were more powerful nitrating media for anisole and biphenyl than the corresponding solutions of nitric acid in which acetyl nitrate had not been formed furthermore, it appeared that the formation of acetyl nitrate was faster when 95-98% nitric acid was used than when 70 % nitric acid was used. [Pg.85]

The Pd—C cr-bond can be prepared from simple, unoxidized alkenes and aromatic compounds by the reaction of Pd(II) compounds. The following are typical examples. The first step of the reaction of a simple alkene with Pd(ll) and a nucleophile X or Y to form 19 is called palladation. Depending on the nucleophile, it is called oxypalladation, aminopalladation, carbopalladation, etc. The subsequent elimination of b-hydrogen produces the nucleophilic substitution product 20. The displacement of Pd with another nucleophile (X) affords the nucleophilic addition product 21 (see Chapter 3, Section 2). As an example, the oxypalladation of 4-pentenol with PdXi to afford furan 22 or 23 is shown. [Pg.13]

Palladation of aromatic compounds with Pd(OAc)2 gives the arylpalladium acetate 25 as an unstable intermediate (see Chapter 3, Section 5). A similar complex 26 is formed by the transmetallation of PdX2 with arylmetal compounds of main group metals such as Hg Those intermediates which have the Pd—C cr-bonds react with nucleophiles or undergo alkene insertion to give oxidized products and Pd(0) as shown below. Hence, these reactions proceed by consuming stoichiometric amounts of Pd(II) compounds, which are reduced to the Pd(0) state. Sometimes, but not always, the reduced Pd(0) is reoxidized in situ to the Pd(II) state. In such a case, the whole oxidation process becomes a catalytic cycle with regard to the Pd(II) compounds. This catalytic reaction is different mechanistically, however, from the Pd(0)-catalyzed reactions described in the next section. These stoichiometric and catalytic reactions are treated in Chapter 3. [Pg.14]

The reactions of the second class are carried out by the reaction of oxidized forms[l] of alkenes and aromatic compounds (typically their halides) with Pd(0) complexes, and the reactions proceed catalytically. The oxidative addition of alkenyl and aryl halides to Pd(0) generates Pd(II)—C a-hondi (27 and 28), which undergo several further transformations. [Pg.15]

Mechanistic studies show that the arylation of alkenes proceeds via the palladation of aromatic compounds to form a rr-aryl-Pd bond (261), into which insertion of alkene takes place to form 262. The final step is i3-elimina-tion to form the arylated alkenes 259 and Pd(0). [Pg.56]

Three oxidative reactions of benzene with Pd(OAc)2 via reactive rr-aryl-Pd complexes are known. The insertion of alkenes and elimination afford arylalk-enes. The oxidative functionalization of alkenes with aromatics is treated in Section 2.8. Two other reactions, oxidative homocoupling[324,325] and the acetoxylation[326], are treated in this section. The palladation of aromatic compounds is possible only with Pd(OAc)2. No reaction takes place with PdCl2. [Pg.74]

The transmetallation of various organometallic compounds (Hg, Tl, Sn, B, Si, etc.) with Pd(II) generates the reactive cr-aryl, alkenyl, and alkyl Pd compounds. These carbopalladation products can be used without isolation for further reactions. Pd(II) and Hg(II) salts have similar reactivity toward alkenes and aromatic compounds, but Hg(II) salts form stable mercuration products with alkenes and aromatic rings. The mercuration products are isolated and handled easily. On the other hand, the corresponding palladation products are too reactive to be isolated. The stable mercuration products can be used for various reactions based on facile transmetallation with Pd(II) salts to generate the very reactive palladation products 399 and 400 in rim[364,365]. [Pg.79]

Thallation of aromatic compounds with thallium tris(trifluoroacetate) proceeds more easily than mercuration. Transmetallation of organothallium compounds with Pd(II) is used for synthetic purposes. The reaction of alkenes with arylthallium compounds in the presence of Pd(Il) salt gives styrene derivatives (433). The reaction can be made catalytic by use of CuCl7[393,394], The aryla-tion of methyl vinyl ketone was carried out with the arylthallium compound 434[395]. The /9-alkoxythallium compound 435, obtained by oxythallation of styrene, is converted into acetophenone by the treatment with PdCh[396]. [Pg.83]

Cyclic compounds that contain at least one atom other than carbon within their ring are called heterocyclic compounds, and those that possess aromatic stability are called het erocyclic aromatic compounds Some representative heterocyclic aromatic compounds are pyridine pyrrole furan and thiophene The structures and the lUPAC numbering system used m naming their derivatives are shown In their stability and chemical behav lor all these compounds resemble benzene more than they resemble alkenes... [Pg.460]

A chlorohydrin has been defined (1) as a compound containing both chloio and hydroxyl radicals, and chlorohydrins have been described as compounds having the chloro and the hydroxyl groups on adjacent carbon atoms (2). Common usage of the term appHes to aUphatic compounds and does not include aromatic compounds. Chlorohydrins are most easily prepared by the reaction of an alkene with chlorine and water, though other methods of preparation ate possible. The principal use of chlorohydrins has been as intermediates in the production of various oxitane compounds through dehydrochlorination. [Pg.70]

FRIEDEL - CRAFTS Alkylation-Acylation Alkylation or acylation ol aromatic compounds by means of alryl halides, alcohols.alkenes, acyl halides in the presence of Lewis acids... [Pg.131]

The generation of caibocations from these sources is well documented (see Section 5.4). The reaction of aromatics with alkenes in the presence of Lewis acid catalysts is the basis for the industrial production of many alkylated aromatic compounds. Styrene, for example, is prepared by dehydrogenation of ethylbenzene made from benzene and ethylene. [Pg.583]

Aromatic compounds such as toluene, xylene, and phenol can photosensitize cis-trans interconversion of simple alkenes. This is a case in which the sensitization process must be somewhat endothermic because of the energy relationships between the excited states of the alkene and the sensitizers. The photostationary state obtained under these conditions favors the less strained of the alkene isomers. The explanation for this effect can be summarized with reference to Fig. 13.12. Isomerization takes place through a twisted triplet state. This state is achieved by a combination of energy transfer Irom the sensitizer and thermal activation. Because the Z isomer is somewhat higher in energy, its requirement for activation to the excited state is somewhat less than for the E isomer. If it is also assumed that the excited state forms the Z- and -isomers with equal ease, the rate of... [Pg.769]

These reactions are believed to proceed through a complex of the alkene with a singlet excited state of the aromatic compound (an exciplex). The alkene and aromatic ring are presumed to be oriented in such a manner that the alkene n system reacts with p orbitals on 1,3-carbons of the aromatic. The structure of the excited-state species has been probed in more detail using CAS-SCF ab initio calculations. ... [Pg.780]

The photochemical cycloadditions of alkenes and alkynes with aromatic compounds have received by far the most attention. Yields of [2+2] cydoadducts can be good, but reaction times are often long and secondary rearrangement products are common [139, 140, 141,142, 143,144, 145,146] (equations 63-65). The pioneering mechanistic and synthetic work on aromatic photocycloadditions has been reviewed [147],... [Pg.790]

Because of Us high polarity and low nucleophilicity, a trifluoroacetic acid medium is usually used for the investigation of such carbocationic processes as solvolysis, protonation of alkenes, skeletal rearrangements, and hydride shifts [22-24] It also has been used for several synthetically useful reachons, such as electrophilic aromatic substitution [25], reductions [26, 27], and oxidations [28] Trifluoroacetic acid is a good medium for the nitration of aromatic compounds Nitration of benzene or toluene with sodium nitrate in trifluoroacetic acid is almost quantitative after 4 h at room temperature [25] Under these conditions, toluene gives the usual mixture of mononitrotoluenes in an o m p ratio of 61 6 2 6 35 8 A trifluoroacetic acid medium can be used for the reduction of acids, ketones, and alcohols with sodium borohydnde [26] or triethylsilane [27] Diary Iketones are smoothly reduced by sodium borohydnde in trifluoroacetic acid to diarylmethanes (equation 13)... [Pg.946]

FITS reagents), has undergone considerable development recently [141,142,143, 144, 14S. These compounds, available fromperfluoroalkyhodides (equation 76), are very effective electrophilicperfluoroalkylating agents They react with carban-lons, aromatic compounds, alkenes, alkynes, silyl enol ethers, and other nucleophiles under mild conditions to introduce the perfluoroalkyl moiety mto organic substrates (equation 77) (see the section on alkylation, page 446). [Pg.969]

We saw in Chapter 12 that aromaticity reveals itself in various ways. Qualitatively, aromatic compounds are more stable and less reactive than alkenes. Quantitatively, their heats of hydrogenation are smaller than expected. Theory, especially Huckel s rule, furnishes a structural basis for aromaticity. Now let s examine some novel features of their NMR spectra. [Pg.530]

The synthesis of an alkylated aromatic compound 3 by reaction of an aromatic substrate 1 with an alkyl halide 2, catalyzed by a Lewis acid, is called the Friedel-Crafts alkylation This method is closely related to the Friedel-Crafts acylation. Instead of the alkyl halide, an alcohol or alkene can be used as reactant for the aromatic substrate under Friedel-Crafts conditions. The general principle is the intermediate formation of a carbenium ion species, which is capable of reacting as the electrophile in an electrophilic aromatic substitution reaction. [Pg.120]

The reaction of ozone with an aromatic compound is considerably slower than the reaction with an alkene. Complete ozonolysis of one mole of benzene with workup under non-oxidative conditions will yield three moles of glyoxal. The selective ozonolysis of particular bonds in appropriate aromatic compounds is used in organic synthesis, for example in the synthesis of a substituted biphenyl 8 from phenanthrene 7 ... [Pg.219]


See other pages where Aromatic compounds alkenes is mentioned: [Pg.53]    [Pg.95]    [Pg.579]    [Pg.814]    [Pg.916]    [Pg.90]    [Pg.265]    [Pg.53]    [Pg.95]    [Pg.579]    [Pg.814]    [Pg.916]    [Pg.90]    [Pg.265]    [Pg.182]    [Pg.551]    [Pg.69]    [Pg.58]   
See also in sourсe #XX -- [ Pg.9 , Pg.10 ]

See also in sourсe #XX -- [ Pg.197 ]




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Addition reactions, alkenes aromatic compounds

Alkenes from aromatic compounds

Alkenes reaction with aromatic compounds

Alkenes, Alkynes, and Aromatic Compounds

Alkenes, ketones and aromatic compounds

Aromatic alkenes

Aromatic compounds from aryl alkenes

Aromatic compounds, fused alkenes

Cycloaddition reactions, alkenes aromatic compounds

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