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Three Alternative

The foregoing indicate that there are three alternative ways to represent the combined field in the degrees of freedom written as r, R. [Pg.151]

Clearly it is the same as the three step synthesis, 73%. So it is better to assemble two more or less equal parts of a molecule separately and join them together at the end. Let s look at this in practice. What three alternative disconnections are immediately obvious on TM 311 ... [Pg.101]

Several alternative methods have been considered in order to increase the energy density of natural gas and facilitate its use as a road vehicle fuel. It can be dissolved in organic solvents, contained in a molecular cage (clathrate), and it may be adsorbed in a porous medium. The use of solvents has been tested experimentally but there has been little improvement so far over the methane density obtained by simple compression. Clathrates of methane and water, (methane hydrates) have been widely investigated but seem to offer little advantage over ANG [4]. Theoretical comparison of these storage techniques has been made by Dignam [5]. In practical terms, ANG has shown the most promise so far of these three alternatives to CNG and LNG. [Pg.274]

If the pattern does not fit into an immediately identifiable pattern, the process worker may then consciously apply more explicit "if-then" rules to link the various symptoms with likely causes. Three alternative outcomes are possible from this process. If the diagnosis and the required actions are very closely linked (because this situation arises frequently) then a branch to the Execute Actions box will occur. If the required action is less obvious, then the branch to the Select/Formulate Actions box will be likely, where specific action rules of the form "if situation is X then do Y" will be applied. A third possibility is that the operating team are unable or imwilling to respond immediately to the situation because they are uncertain about its implications for safety and/or production. They will then move to the Implications of plant state box. [Pg.94]

Bupleurol is a primary alcohol, which according to the authors must, have one of the three alternative constitutions —... [Pg.123]

The relation is solved for Sr/Sj. The results are not exact, because the feed tray composition is very seldom the same as the feed which is the assumption in this relation. Actually, the feed point or correct location for the feed may be off by two or three theoretical trays. This will vary with the system. It does mean, however, that when this approach is used for feed plate location, alternate feed nozzles should be installed on the column to allow for experimental location of the best feed point. These extra nozzles are usually placed on alternate trays (or more) both above and below the calculated location. A minimum of three alternate nozzles should be available. [Pg.85]

When the project begins to fall behind in schedule, three alternatives may correct the problem. The first is to examine the work remaining to be done and decide whether the lost time can be recovered in the next steps. If this is not feasible, consider offering an incentive for on-time completion of the project. The incentive could be justified if you compare this expenditure to potential losses due to late completion. Finally, consider deploying more resources. This too will cost more, but may offset further losses from delayed completion. [Pg.836]

Fig. 1.40 Schematic anodic polarisation curve for a passivatable metal (solid line), shown together with three alternative cathodic reactions (broken line). Open-circuit corrosion potentials are determined by the intersection between the anodic and cathodic reaction rates. Cathode a intersects the anodic curve in the active region and the metal corrodes. Cathode b intersects at three possible points for which the metal may actively corrode or passivate, but passivity could be unstable. Only cathode c provides stable passivity. The lines a, b and c respectively could represent different cathodic reactions of increasing oxidizing power, or they could represent the same oxidizing agent at increasing concentration. Fig. 1.40 Schematic anodic polarisation curve for a passivatable metal (solid line), shown together with three alternative cathodic reactions (broken line). Open-circuit corrosion potentials are determined by the intersection between the anodic and cathodic reaction rates. Cathode a intersects the anodic curve in the active region and the metal corrodes. Cathode b intersects at three possible points for which the metal may actively corrode or passivate, but passivity could be unstable. Only cathode c provides stable passivity. The lines a, b and c respectively could represent different cathodic reactions of increasing oxidizing power, or they could represent the same oxidizing agent at increasing concentration.
The situation is not as clearly solved in a positive or negative sense for arenediazo phenyl ethers. Here three alternatives have to be considered, namely an intramolecular rearrangement of the arenediazo phenyl ether (Scheme 12-11, A), and two types of intermolecular rearrangement, either by heterolytic dissociation into a diazonium ion and a phenoxide ion (B) or by homolytic dissociation into a radical pair or two free radicals (C). [Pg.314]

After a study of the three alternatives we concluded that pyroredox offered the most promise for anode residue recovery. Pyroredox is a molten-salt process in which plutonium metal is oxidized chemically into the salt phase and then reduced chemically into the metal phase. Most of the impurities are not oxidized and remain in the metal residue. Thus, for a Pu-Ga anode residual, the reactions would be ... [Pg.421]

These lead, respectively, to energetic recoil, to recoil followed by ionization, and to ionization in situ. The transitions for Mn given in Fig. 1 are grouped according to these three alternatives. The logical fourth possibility—ionization followed by recoil—is in effect the same as the first... [Pg.213]

There are three alternative methods available when conducting sterility tests. [Pg.446]

This chapter is aimed at presenting an overview of the state of the art in phytofiltration of heavy metals using any of the three different treatment systems. It has been considered useful to discuss the three alternatives in one single document, since usually, information for each of the systems is reviewed separately, missing the advantages of a holistic discussion. [Pg.390]

Three alternative routes to 3-vinylsalicylic acid derivatives were also investigated briefly, without success carbonation of... [Pg.45]

The large heterogeneities in Mg isotopic composition found for the B2 and A inclusions confuse the simple chronological interpretation possible with the B1 data. The B2 and A data are generally consistent with three alternatives - actual differences in age, isotopic variation due to alteration, or heterogeneity in (26A1/ 27A1)0 which lead to different models for the early solar... [Pg.131]

Fig. 19 Perspective view of three alternate 2D Fe[Ag(CN)2]2 n corrugated layers connected by rods, which represent the organic ligand (4,4 -bipy and bpe). The void space in between these layers is occupied by an identical 3D network... [Pg.267]

Three alternative mechanisms have been mentioned in the literature. Reduction of C02 to CO followed by carbonylation of dimethylamine was ruled out by Haynes et al. [3] for RhCl(PPh3)3 because no carbonyl complexes were detected. Aminolysis of formate complexes (Eq. (14)) was proposed by Kudo et al. [69], but strong evidence has not been obtained. Finally, C02 is known to react with the amine to produce a carbamate salt (Eq. (15)), and it is possible that the pathway to the formamide is by hydrogenation of the carbamate rather than of the C02. [Pg.504]

It is one thing to design, test, and maintain a recovery system that effectively recovers NAPL, but the handling of the coproduced groundwater is another matter. The effectiveness of a recovery system can suffer if the disposal capacity is insufficient or treatment costs are high. Additionally, a cost-effective, low operation and maintenance recovery system can quickly be turned into a high-cost system if the coproduced water fate is not coordinated with the recovery system. A key factor will be the level of treatment required, if any, prior to disposal. Three alternatives are explored surface discharge refinery reuse and reinjection. [Pg.255]

Nitrophenols in fog and atmospheric particles were determined by GC of the underiva-tized compounds and their corresponding acetate esters. Four fused-silica columns were used with three alternative detection modes, namely mass-selective detection, nitrogen-specific detection and ECD. GC-ECD of the acetate derivatives gave the best results501. A capillary GC-UVD method was developed for the determination of small amounts of nitrophenols present in the environment. The method was compared with HPLC-UVD from the point of view of selectivity and sensitivity. LOD for GC were about one-tenth of those for HPLC502. [Pg.1133]

To accomplish the first task, the NRC will review and evaluate the results of demonstrations for three alternative technologies for de-... [Pg.41]

Example 16.5. Yu and Luyben (Ind. Eng. Chem. Process Des. Dev., 1986, Vol. 25, p. 498) give the following steadystate gain matrices for three alternative choices of manipulated variables reflux and vapor boilup (R — V), distillate and vapor boilup (D — V), and refiux ratio and vapor boilup (RR — V). [Pg.574]


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See also in sourсe #XX -- [ Pg.119 ]




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