Thin-film solar cells amorphous silicon-based

Although conventional solar cells based on silicon are produced from abundant raw materials, the high-temperature fabrication routes to single-crystal and polycrystalline silicon are energy intensive and expensive. The search for alternative solar cells has therefore focused on thin films composed of amorphous silicon and on other semiconductor heterojunction cells (e.g., cadmium telluride and copper indium... 

We have already mentioned amorphous silicon solar cells. New processes have been developed to manufacture solar cells based upon deposition of very thin films of photosensitive materials. Such processes have a distinct cost advantage since once the films are deposited, little further processing is needed to form the final solar cell module. 

Although ZnO has also been applied in so-called amorphous/crystalline heterojunction solar cells consisting of a (doped) silicon wafer and thin doped a-Si H layers to build the p-n junction, we will restrict ourselves here to solar cells and modules with amorphous and/or microcrystalline absorber layers, i.e., real thin film silicon solar cells. For detailed information on the use of ZnO in crystalline silicon wafer based devices, the reader is referred to the literature (see e.g. [23,24]). 

Abstract Photovoltaic cells have been dominated so far by solid state p-n junction devices made from silicon or gallium arsenide wavers or thin film embodiments based on amorphous silicon, CdTe and copper indium gallium diselenide (CIGS) profiting from the experience and material availability of the semiconductor industry. Recently there has been a surge of interest for devices that are based on nanoscale inorganic or organic semiconductors commonly referred to as bulk junctions due to their interconnected three-dimensional structure. The present chapter describes the state of the art of the academic and industrial development of nanostructured solar cells, with emphasis in the development of the dye-sensitized nanocristalline solar cell. 

Yang, J., Yan, B., Guha, S. Amorphous and nanocrystalline silicon-based multi-junction solar cells. Thin Solid Films 487, 162-169 (2005)... 

Solar voltaic cells based on crystalline silicon have operated with a 30% efficiency for experimental cells and 15-20% for commercial units available in 2008, at a cost of around 15 cents/kWh, compared to 4-7 cents/kWh for fossil fuel-fired power plants and 6-9 cents for those fired by biomass. Costs of photovoltaic electricity have shown a continuous downward trend. Part of the high cost in the past has resulted from the fact that the silicon used in the cells must be cut as small wafers from silicon crystals for mounting on the cell surfaces. Significant advances in costs and technology are being made with thin-fllm photovoltaics, which use an amorphous silicon alloy. These cells are only about half as efficient as those made with crystalline silicon, but cost only about 25% as much. A newer approach to the design and construction of amorphous silicon film photovoltaic devices... 

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