Surface area particulate

Physical processes may also be used to deposit Pt onto various types of supports. An example of this type of approach is the preparation of Pt-metal monolayers supported on low-cost transition metal carbides, prepared by magnetron sputtering of Pt onto thin films of W and Mo carbides. While Pt monolayers were achieved on the thin-film electrode geometry used in this study, uniform deposition of Pt onto high surface area particulate materials or mesoporous structures by these methods remains challenging [48]. 

Oxide products from thorium oxalate decomposition are normally characterized by their behavior as slurries. In addition, they have been characterized by means of electron micrograph pictures, their nitrogen adsorption surface areas, particulate properties as measured by sedimenta-... 

Finally, a number of useful definitions of quantities directly or indirectly involved in the study of the surface area and porosity of both particulate and massive solids are given in Table 1.6. 

The most widely used particulate support is diatomaceous earth, which is composed of the silica skeletons of diatoms. These particles are quite porous, with surface areas of 0.5-7.5 m /g, which provides ample contact between the mobile phase and stationary phase. When hydrolyzed, the surface of a diatomaceous earth contains silanol groups (-SiOH), providing active sites that absorb solute molecules in gas-solid chromatography. 

Particulate systems composed of identical particles are extremely rare. It is therefore usefiil to represent a polydispersion of particles as sets of successive size intervals, containing information on the number of particle, length, surface area, or mass. The entire size range, which can span up to several orders of magnitude, can be covered with a relatively small number of intervals. This data set is usually tabulated and transformed into a graphical representation. 

When a liquid or solid substance is emitted to the air as particulate matter, its properties and effects may be changed. As a substance is broken up into smaller and smaller particles, more of its surface area is exposed to the air. Under these circumstances, the substance, whatever its chemical composition, tends to combine physically or chemically with other particles or gases in the atmosphere. The resulting combinations are frequently unpredictable. Very small aerosol particles (from 0.001 to 0.1 Im) can act as condensation nuclei to facilitate the condensation of water vapor, thus promoting the formation of fog and ground mist. Particles less than 2 or 3 [Lm in size (about half by weight of the particles suspended in urban air) can penetrate the mucous membrane and attract and convey harmful chemicals such as sulfur dioxide. In order to address the special concerns related to the effects of very fine, iuhalable particulates, EPA replaced its ambient air standards for total suspended particulates (TSP) with standards for particlute matter less than 10 [Lm in size (PM, ). 

Collecting surface area The actual surface area of a filter on which particulate matter is collected, normally greater than the filter face area. 

HEPA (high-efficiency particulate air) filters Also known as absolute filters, the large collection filter surface area provides a high collection efficiency for particulate matter. 

Purely physical laws mainly control the behaviour of very large particles. Further down the particle size range, however, specific surface area, i.e. surface area per unit mass, increases rapidly. Chemical effects then become important, as in the nucleation and growth of crystals. Thus, a study of particulate systems within this size range of interest has become very much within the ambit of chemical engineering, physical chemistry and materials science. 

When using animal inhalation e.xpcrimcnts to estimate lifetime human risks for partially soluble vapors or gases, the air concentration (ppm) is generally considered to be the equivalent dose between species based on cqui alcnt c.xposure times (measured as fractions of a lifetime). For inhalation of particulates or completely absorbed gases, the amount absorbed per unit of body surface area is considered to be the equivalent dose between species. 

C removes metal particulates and CGettering with Zr foil (sponge gives a larger surface area) at 700°C for 24 h is recommended for the removal of the nonmetals, O, H and C . Stainless steel turnings also reduce both O and C contents. 

Aluminum sulfate, AI2 (804)3 > widely used in water purification to remove finely divided particulate matter. When added to water, aluminum sulfate forms a precipitate of aluminum hydroxide that has a very open structure and large surface area. This precipitate, called a gel, traps dispersed particulate matter as it settles out of the liquid phase. 

Airborne particulate matter may comprise liquid (aerosols, mists or fogs) or solids (dust, fumes). Refer to Figure 5.2. Some causes of dust and aerosol formation are listed in Table 4.3. In either case dispersion, by spraying or fragmentation, will result in a considerable increase in the surface area of the chemical. This increases the reactivity, e.g. to render some chemicals pyrophoric, explosive or prone to spontaneous combustion it also increases the ease of entry into the body. The behaviour of an airborne particle depends upon its size (e.g. equivalent diameter), shape and density. The effect of particle diameter on terminal settling velocity is shown in Table 4.4. As a result ... 

Table 2.7 lists techniques used to characterise carbon-blacks. Analysis of CB in rubber vulcanisates requires recovery of CB by digestion of the matrix followed by filtration, or by nonoxidative pyrolysis. Dispersion of CB within rubber products is usually assessed by the Cabot dispersion test, or by means of TEM. Kruse [46] has reviewed rubber microscopy, including the determination of the microstructure of CB in rubber compounds and vulcanisates and their qualitative and quantitative determination. Analysis of free CB features measurements of (i) particulate and aggregate size (SEM, TEM, XRD, AFM, STM) (ii) total surface area according to the BET method (ISO 4652), iodine adsorption (ISO 1304) or cetyltrimethylammonium bromide (CTAB) adsorption (ASTM D 3765) and (iii) external surface area, according to the dibutylphthalate (DBP) test (ASTM D 2414). TGA is an excellent technique for the quantification of CB in rubbers. However, it is very limited in being able to distinguish the different types of... 

For small amounts of powder, dissolution of the particulate material can often be assessed (and compared with that of other compounds) by placing the powder in a calorimeter [68] and measuring the heat evolved as a function of time. The surface area must be assessed microscopically (or by image analyzer), and the data must be plotted by a cube root equation [39] ... 

Strictly speaking, sink conditions are when the amount dissolved plotted versus time yields a line which, within experimental error, is linear. When the surface area, A, is constant, then this corresponds to 15% dissolved. When the surface area changes (e.g., during particulate dissolution), then this number may be smaller. 

The experimental results of Capes and Danckwerts (C6) and Kanetkar (K1), using a balling drum and a disk granulator, respectively, have shown that the thickness of the snowballed layer is approximately independent of the initial size of the seed pellet. It then follows that the rate of pick up of the loose particulate material is proportional to the surface area of the granule hence,... 

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