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SUBJECTS compounds

Kinetics are slow and many hours are requited for a 95% conversion of the reactants. In the case of the subject compound, there is evidence that the reaction is autocatalytic but only when approximately 30% conversion to the product has occurred (19). Reaction kinetics are heavily dependent on the species of halogen ia the alkyl haHde and decrease ia the order I >Br >C1. Tetrabutylphosphonium chloride exhibits a high solubiHty ia a variety of solvents, for example, >80% ia water, >70% ia 2-propanol, and >50% ia toluene at 25°C. Its analogues show similar properties. One of the latest appHcations for this phosphonium salt is the manufacture of readily dyeable polyester yams (20,21). [Pg.319]

The present procedures represent simplified methods for obtaining the subject compounds and for accomplishing the illustrated conversions. [Pg.98]

Very few imidazo[4,5-b] pyrazines have been reported in the literature1-3 and no good general method has been available for preparing compounds in this most interesting heterocyclic class. We have found that the Curtius reaction of a 3-aminopyrazine-2-carboxylic acid azide (Scheme I) proceeds with intramolecular cyclization to provide, in good yield, a wide variety of the subject compounds. We will report here only the 6-substituted 5-chloro-l, 3-dihydro-2tf-... [Pg.6]

Pd then plates onto the terrace sites (Fig. 11). On Au(lll), only terrace sites are exposed. In this manner, the surface electrochemical properties of the subject compounds at the steps and on the terraces surfaces can be compared. It should be recalled that aromatic molecules chemisorb only on Pd but not on Au " the expectation is then that the lower the Pd coverage, the lower the amount (and subsequent electrocatalysis) of chemisorbed benzene. [Pg.295]

In this first comprehensive work on the subject of pharmaceutical photostabilitytesting, he subjected compounds listed as "should be protected from light" in the fourth edition of the Dutch Pharmacopoeia, to various bands of light and measured their effect on the chosen test substances. [Pg.4]

This prompted us to develop a novel regioselective nitrosation procedure for resorcinol monoethers, e.g. for monobenzyl resorcinol, as starting material (Fig. (11)). Solid sodium nitrite in anhydrous propionic acid as solvent was an effective system for the completely regioselective nitrosation of the subject compounds. High yields of pure 2-nitroso products were obtained. Attack at the 4-position becomes only competitive in the presence of water in the solvent. Absence of water was ensured by addition of one percent of propionic anhydride. The excellent regioselectivity observed is obviously related to the presence of nitrosyl... [Pg.201]

Initial attempts to establish growth potential must be accompanied by careful evaluation of impurity contamination. This can be difficult when the struchire of the impurities may not be known. One experimental technique to evaluate the effect of impurities that are inherent in the process but whose structures may not be known is to recrystallize the subject compound both from pure solvents and from the same solvents spiked with mother liquors horn a primary crystallization. This technique can be very successful in revealing whether crystal growth is affected by the impurities in the spiked liquors. [Pg.216]

The comprehensive treatment given the subject compounds by Ellis has restricted the literature which is to be presented to material published after 1936, although on occasion important earlier references will be given. Emphasis has been placed on those publications which contain fairly extensive bibliographies, e.g., review articles and monographs. [Pg.370]

The preceding method is known as reversed isotope dilution analysis when the compound to be measured is already radioactive. The principle remains the same the activity of the subject compound (measured from a fraction), is carried out before and after dilution with the same compound, non-labelled. The calculations are identical. This analysis is used for the determination of the isotopic carrier in a solution of a radionuclide using one of its stable isotopes. [Pg.421]

Before the seminar begins we conduct an exhaustive survey of the literature on the subject compound. To this are added the results of the application research done in the course of our search for uses for the product. The data presented are also generally made available in book form. We have published a number of books summarizing, for example, all the available data on acetone or, more recently, acrolein. [Pg.115]

The symmetric disposition of cyclophosphazenes renders them useful as models for n.m.r. spectroscopy. In studies concerning this subject compounds have been used with either endocyclicorexocyclic N incorporation, e.., ( NPR2)a (R = F, Cl, Br, SEt) and N3P3CI4R2 (R = NHMe, i NMe2). The... [Pg.271]

Two observations led to the conclusion that the subject compounds exhibited anaerobic polymerization behavior. These were the necessity of carrying out the addition reaction in an air atmosphere to prevent gel formation, particularly when using the BF3 etherate catalyst, and the... [Pg.583]

Nitrogen compounds in coal liquids can be analyzed by GC-MS. GC is capable of separating nitrogen compounds with similar molecular weights within the same class,butindistinguishablebyMS(e.g.,6-methylquinolme and 7-methylquinoline) as shown in Figure 32.7 [21]. MS is valuable in estabUshing measurement in the presence of impurities with identical or nearly identical retention time as the subject compounds. [Pg.714]

Nor- A prefix for organic compounds indicating the parent compound from which the subject compound may be derived, usually by removal of one or more carbon atoms and their attache hydrogens. Example norcamphor is camphor from which three -CH3 groups have been removed. [Pg.489]

In certain cases, it is not possible to establish a proton transfer equilibrium, for example, if the subject compound, M, is unstable, or if MH+ undergoes a fast reaction with M, or a reaction other than proton transfer with B. In these instances, other strategies have been adopted to determine relative gas-phase basicities or proton affinities. The simplest such approach is called the bracketing technique the ion MH+ is generated and the occurrence or nonoccurrence of proton transfer with a series of molecules, Bj, B2, etc., is observed. Reference compounds are chosen whose position in the relative scale of gas basicities is known. [Pg.733]


See other pages where SUBJECTS compounds is mentioned: [Pg.623]    [Pg.294]    [Pg.164]    [Pg.640]    [Pg.640]    [Pg.1563]    [Pg.43]    [Pg.45]    [Pg.318]    [Pg.139]    [Pg.233]    [Pg.246]    [Pg.170]    [Pg.736]    [Pg.70]    [Pg.424]    [Pg.37]    [Pg.392]    [Pg.623]    [Pg.8]    [Pg.623]    [Pg.36]    [Pg.218]    [Pg.200]    [Pg.658]    [Pg.47]    [Pg.126]    [Pg.733]   
See also in sourсe #XX -- [ Pg.209 ]

See also in sourсe #XX -- [ Pg.134 , Pg.296 ]

See also in sourсe #XX -- [ Pg.2 , Pg.33 ]




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2-Butene, 1-bromoreaction with organochromium compounds Subject

Allyl compounds Subject

Aluminium compounds Subject

Amides, p-ketoSubject organosamarium compounds

Anticancer compounds Subject

Boron compounds Subject

Carbonyl compounds Subject

Cobalt complex compounds Subject

Compound Name, Code Number and Subject , Volume

Coordination compounds Subject

Cumulative Subject carbonyl compounds

Cumulative Subject compounds

Cumulative Subject reaction with carbonyl compounds

Cumulative Subject reactions with organometallic compounds

Cumulative Subject unsaturated carbonyl compounds

Diazonium compounds, reaction with Subject

Fused compounds Subject

Gold compounds Subject

Iron compounds Subject

Mercury compounds Subject

Nitroso compounds Subject

Organoaluminum compounds Subject

Organoboron compounds Subject

Organozinc compounds Subject

Palladium compounds, as chiral catalysts for Subject inde

Phenolic compounds Subject

Polar compounds Subject

Refractory compounds Subject

Ring compounds Subject

SUBJECTS compounds 239 dioxide

SUBJECTS compounds 678 contains carbon

SUBJECTS compounds 718, oxide

SUBJECTS compounds 838 formic acid

SUBJECTS ferric compounds

SUBJECTS ferrous compounds

Subject Reissert compounds

Subject addition to carbonyl compounds

Subject aromatic compounds

Subject compound glasses

Subject compounds, uses

Subject flavour compounds

Subject from propargylic compound

Subject organic compounds

Subject organometallic compounds

Subject organosulfur compounds

Subject oxygen compounds

Subject phosphorus compounds

Subject reactions with carbonyl compounds

Subject reactions with organometallic compounds

Subject silicon compounds

Subject sulfur compounds

Subject unsaturated carbonyl compounds

Subject volatile organic compounds

Subject with organolithium compounds

Sulfur-nitrogen compounds Subject

Tellurium compounds Subject

Ternary compounds Subject

Thioamide compounds Subject

Thiocarbonyl compounds Subject

Transition-metal binary compounds Subject

Type indicate pages on which a compound or subject is mentioned in connection

Type indicate pages on which a compound or subject is mentioned in connection with other

Vinyl-metal compounds Subject

Which a compound or subject is mentioned in the indicated volume

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