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Styrene development

Ethylbenzene Also called UOP Ethylbenzene. A liquid-phase process for making ethylbenzene by reacting ethylene with benzene, catalyzed by a zeolite. The process is usually coupled with one for converting ethylbenzene to styrene. Developed by Unocal Corporation and now licensed by UOP and ABB Lummus Crest. [Pg.103]

Styromax Not a process but a proprietary name for a range of catalysts for making styrene, developed and sold by the Nissan Girdler Catalyst Company. [Pg.348]

Styrene—acrylonitrile (SAN) copolymers [9003-54-7] have superior properties to polystyrene in the areas of toughness, rigidity, and chemical and thermal resistance (2), and, consequendy, many commercial appHcations for them have developed. These optically clear materials containing between 15 and 35% AN can be readily processed by extmsion and injection mol ding, but they lack real impact resistance. [Pg.191]

An emulsion model that assumes the locus of reaction to be inside the particles and considers the partition of AN between the aqueous and oil phases has been developed (50). The model predicts copolymerization results very well when bulk reactivity ratios of 0.32 and 0.12 for styrene and acrylonitrile, respectively, ate used. [Pg.193]

The combination of stmctural strength and flotation has stimulated the design of pleasure boats using a foamed-in-place polyurethane between thin skins of high tensUe strength (231). Other ceUular polymers that have been used in considerable quantities for buoyancy appHcations are those produced from polyethylene, poly(vinyl chloride), and certain types of mbber. The susceptibUity of polystyrene foams to attack by certain petroleum products that are likely to come in contact with boats led to the development of foams from copolymers of styrene and acrylonitrUe which are resistant to these materials... [Pg.416]

The first resins to be produced on a commercial scale were the coumarone—indene or coal-tar resins (1) production in the United States was started before 1920. These resins were dominant until the development of petroleum resins, which were estabHshed as important raw materials by the mid-1940s. Continued development of petroleum-based resins has led to a wide variety of aHphatic, cyclodiene, and aromatic hydrocarbon-based resins. The principal components of petroleum resins are based on piperylenes, dicyclopentadiene (DCPD), styrene, indene, and their respective alkylated derivatives. [Pg.350]

G-9 Aromatic Petroleum Resins. Feedstocks typically used for aromatic petroleum resin synthesis boil in the approximate range of 100—300°C at atmospheric pressure, with most boiling in the 130—200°C range. The C-9 designation actually includes styrene (C-8) through C-10 hydrocarbons (eg, methylindene). Many of the polymerizable monomers identified in Table 1 for coumarone—indene type cmdes from coal tar are also present in aromatic fractions from cracked petroleum distillates. Therefore, the technology developed for the polymerization of coal-tar cmdes is also appHcable to petroleum-derived aromatic feedstocks. In addition to availabiHty, aromatic petroleum resins offer several advantages over coumarone—indene resins. These include improved color and odor, as weU as uv and thermal stabiHty (46). [Pg.354]

Developments in aliphatic isocyanates include the synthesis of polymeric aliphatic isocyanates and masked or blocked diisocyanates for appflcafions in which volatility or reactivity ate of concern. Polymeric aliphatic isocyanates ate made by copolymerizing methacrylic acid derivatives, such as 2-isocyanatoethyl methacrylate, and styrene [100-42-5] (100). Blocked isocyanates ate prepared via the reaction of the isocyanate with an active hydrogen compound, such as S-caprolactam, phenol [108-95-2] or acetone oxime. [Pg.459]

The reaction rate of fumarate polyester polymers with styrene is 20 times that of similar maleate polymers. Commercial phthaHc and isophthaHc resins usually have fumarate levels in excess of 95% and demonstrate full hardness and property development when catalyzed and cured. The addition polymerization reaction between the fumarate polyester polymer and styrene monomer is initiated by free-radical catalysts, commercially usually benzoyl peroxide (BPO) and methyl ethyl ketone peroxide (MEKP), which can be dissociated by heat or redox metal activators into peroxy and hydroperoxy free radicals. [Pg.317]

Catalyst Selection. The low resin viscosity and ambient temperature cure systems developed from peroxides have faciUtated the expansion of polyester resins on a commercial scale, using relatively simple fabrication techniques in open molds at ambient temperatures. The dominant catalyst systems used for ambient fabrication processes are based on metal (redox) promoters used in combination with hydroperoxides and peroxides commonly found in commercial MEKP and related perketones (13). Promoters such as styrene-soluble cobalt octoate undergo controlled reduction—oxidation (redox) reactions with MEKP that generate peroxy free radicals to initiate a controlled cross-linking reaction. [Pg.318]

As more complex multicomponent blends are being developed for commercial appHcations, new approaches are needed for morphology characterization. Often, the use of RuO staining is effective, as it is sensitive to small variations in the chemical composition of the component polymers. For instance PS, PC, and styrene—ethylene/butylene—styrene block copolymers (SEES) are readily stained, SAN is stained to a lesser degree, and PET and nylons are not stained (158,225—228). [Pg.418]

However, the ethylben2ene or styrene process based on side-chain alkylation has not been developed for commercial appHcations. [Pg.48]

Almost all IDA derived chain extenders are made through ortho-alkylation. Diethyltoluenediamine (DE I DA) (C H gN2) (53), with a market of about 33,000 t, is the most common. Many uses for /-B I DA have been cited (1,12). Both DE I DA and /-B I DA are especially useful in RIM appHcations (49,53—55). Di(methylthio)-TDA, made by dithioalkylation of TDA, is used in cast urethanes and with other TDI prepolymers (56). Styrenic alkylation products of TDA are said to be useful, eg, as in the formation of novel polyurethane—polyurea polymers (57,58). Progress in understanding aromatic diamine stmcture—activity relationships for polyurethane chain extenders should allow progress in developing new materials (59). Chlorinated IDA is used in polyurethane—polyurea polymers of low hysteresis (48) and in reinforced polyurethane tires (60). The chloro-TDA is made by hydrolysis of chloro-TDI, derived from TDA (61). [Pg.239]

Propylene oxide [75-56-9] (methyloxirane, 1,2-epoxypropane) is a significant organic chemical used primarily as a reaction intermediate for production of polyether polyols, propylene glycol, alkanolamines (qv), glycol ethers, and many other useful products (see Glycols). Propylene oxide was first prepared in 1861 by Oser and first polymerized by Levene and Walti in 1927 (1). Propylene oxide is manufactured by two basic processes the traditional chlorohydrin process (see Chlorohydrins) and the hydroperoxide process, where either / fZ-butanol (see Butyl alcohols) or styrene (qv) is a co-product. Research continues in an effort to develop a direct oxidation process to be used commercially. [Pg.133]

Rhenium oxides have been studied as catalyst materials in oxidation reactions of sulfur dioxide to sulfur trioxide, sulfite to sulfate, and nitrite to nitrate. There has been no commercial development in this area. These compounds have also been used as catalysts for reductions, but appear not to have exceptional properties. Rhenium sulfide catalysts have been used for hydrogenations of organic compounds, including benzene and styrene, and for dehydrogenation of alcohols to give aldehydes (qv) and ketones (qv). The significant property of these catalyst systems is that they are not poisoned by sulfur compounds. [Pg.164]

The commodity nature of the product and the easy access to the Hcensed processes enable new producers, particularly in developing countries, to enter the global styrene merchant market with Htde experience in styrene technology. Access to ethylene, which caimot be easily transported by means other than pipelines, is a key factor in considering new styrene faciHties. Timing, or luck, is even more important because the supply and demand of styrene are seldom in balance and the price fluctuates broadly and rapidly as a result. Most of the time, the producers either suffer losses (1981—1985, 1991—1993) or enjoy handsome profits (1987—1990, 1994—mid-1995). Investments in styrene plants are known to have been recovered in less than a year, but prosperity encourages over-investment and lean years may foUow. [Pg.476]


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See also in sourсe #XX -- [ Pg.279 ]




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