The Intercommunication of Structures in Diluted Solution and Polymers Condensed State

6 THE INTERCOMMUNICATION OF STRUCTURES IN DILUTED SOLUTION AND POLYMERS CONDENSED STATE 

As it has been shown above, both solvent type and polymer chain stmcture will influence on solid-phase polymer stmcture and, hence, its properties. Both indicated factors have an influence on value and it is obvious, that the chain stmcture will have main influence on the dimension variation, since the data only for PESF solutions in tetrachloroethane 

The Fractal Physical Chemistry of Polymer Solutions and Melts 

FIGURE 48 The dependence of intrinsic viscosity [t ] on sulfone fragments contents for PESF solutions in tetrachloroethane. 

Z) calculation according to the Eq. (11) confirms this supposition. The dependence of on formal fragments eontents in PESF, shown in Fig. 30, is also nonadditive and copol5miers Devalues are disposed below the additive dependence. Thus, the data of Figs. 30 and 48 allow one to trace PESF macromolecular coil structure in tetrachloroethane solution change as a function of either chain fragments contents. 

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