Stress-strain relations viscoelastic materials

Other coordinate systems may be used for failure surface representations in addition to stress space. Blatz and Ko (11) indicate that either stress (Stress space is most commonly used because the failure surface concept was originally applied to metals, for which stress and strain are more simply related. Viscoelastic materials, on the other hand, may show a multitude of strain values at a given stress level, depending on test conditions. 

The stress-strain relations for viscoelastic materials are reviewed. The simplest case of intrinsic absorption in polymers is a molecular relaxation mechanism with a single relaxation time. However, the relaxation mechanisms which lead to absorption of sound are usually more complicated, and are characterized by a distribution of relaxation times. Under causal linear response conditions the attenuation and dispersion of sound in a... 

Many materials, particularly polymers, exhibit both the capacity to store energy (typical of an elastic material) and the capacity to dissipate energy (typical of a viscous material). When a sudden stress is applied, the response of these materials is an instantaneous elastic deformation followed by a delayed deformation. The delayed deformation is due to various molecular relaxation processes (particularly structural relaxation), which take a finite time to come to equilibrium. Very general stress-strain relations for viscoelastic response were proposed by Boltzmann, who assumed that at low strain amplitudes the effects of prior strains can be superposed linearly. Therefore, the stress at time t at a given point in the material depends both on the strain at time t, and on the previous strain history at that point. The stress-strain relations proposed by Boltzmann are [4,39] ... 

Stress-Strain Relations for Viscoelastic Materials. The viscoelastic behaviour of an elastomer varies with temperature, pressure, and rate of strain. This elastic behaviour varies when stresses are repeatedly reversed. Hence any single mathematical model can only be expected to approximate the elastic behaviour of actual substances under limited conditions 2J. ... 

The failure phenomena of viscoelastic materials consist of two factors. One is the time dependence of the hulk stress-strain relation of the material. For example, higher strain rate increases the stress level of the material and consequently the stress or the strain at break will he different from those of the case of the lower rate. The second factor is the time dependence of the failure mechanism itself, namely, the time dependence of the failure initiation mechanism. 

For example, the stress-strain relation for shear strain in an isotropic material is <7 = Ge. For a viscoelastic material this relation is modified as follows ... 

Definition of terms relating to the non-ultimate mechanical properties of polymers. " This document defines mechanical terms of significance prior to failure of polymers. It deals in particular with bulk polymers and concentrated polymer solutions and their respective viscoelastic properties. It contains the basic definitions of experimentally observed stress, strain, deformations, viscoelastic properties, and the corresponding quantities that are commonly met in conventional mechanical characterization of polymeric materials. Definitions from ISO and ASTM publications are adapted. Only isotropic polymeric materials are considered. 

In the field of rubber elasticity both experimentalists and theoreticians have mainly concentrated on the equilibrium stress-strain relation of these materials, i e on the stress as a function of strain at infinite time after the imposition of the strain > This approach is obviously impossible for polymer melts Another complication which has thwarted the comparison of stress-strain relations for networks and melts is that cross-linked networks can be stretched uniaxially more easily, because of their high elasticity, than polymer melts On the other hand, polymer melts can be subjected to large shear strains and networks cannot because of slippage at the shearing surface at relatively low strains These seem to be the main reasons why up to some time ago no experimental results were available to compare the nonlinear viscoelastic behaviour of these two types of material Yet, in the last decade, apparatuses have been built to measure the simple extension properties of polymer melts >. It has thus become possible to compare the stress-strain relation at large uniaxial extension of cross-linked rubbers and polymer melts ... 

Particulate materials, such as clay or particulate gels of the type discussed in Chapter 4, may be plasticy rather than viscoelastic. Two simple types of plastic behavior are illustrated in Fig. 18b a perfectly plastic material is elastic up to t)xt yield stress, Oy > but it deforms without limit if a higher stress is applied in a linearly hardening material there is a finite slope after the yield stress. In real plastic materials, the stress-strain relations are likely to be curved, rather than linear. If the stress is raised above Oy and then released, the elastic strain is recovered but the plastic strain is not. This differs from viscous behavior in its time-dependence if the stress on a linearly hardening plastic material is raised to Oh and held constant, the strain remains at a viscoelastic material would continue to deform at a rate proportional to Ou/ri-... 

II. One-dimensional Constitutive Equations, (a) One-dimensional stress-strain relations for a non-aging linear viscoelastic material take the form... 

The general formulation of the evolution of linear isotropic viscoelastic material in time is governed by the stress-strain relation, in which the stress can be expressed as a convolution of the strain rate with a relaxation function as in... 

Figure 1 Diagram showing the viscoelastic behavior of a mucous gel. The first two panels illustrate stress-strain relations in idealized materials, namely an elastic solid, for which the displacement or strain is proportional to the applied force or stress, and a viscous liquid, for which the rate of strain (displacement/time) is proportional to the stress. Mucus is a viscoelastic semisolid. It responds instantaneously as a solid, with a very rapid displacement in response to an applied force. This is followed by a transition to a liquidlike response, in which the rate of strain is constant with time. Finally a zone of viscous response is reached, in which the rate of displacement is constant with time. After release of the applied force, the mucous gel recoils only partially to its initial position.

Whether a viscoelastic material behaves as a viscous Hquid or an elastic soHd depends on the relation between the time scale of the experiment and the time required for the system to respond to stress or deformation. Although the concept of a single relaxation time is generally inappHcable to real materials, a mean characteristic time can be defined as the time required for a stress to decay to 1/ of its elastic response to a step change in strain. The... 

The theory relating stress, strain, time and temperature of viscoelastic materials is complex. For many practical purposes it is often better to use an ad hoc system known as the pseudo-elastic design approach. This approach uses classical elastic analysis but employs time- and temperature-dependent data obtained from creep curves and their derivatives. In outline the procedure consists of the following steps ... 

When the magnitude of deformation is not too great, viscoelastic behavior of plastics is often observed to be linear, i.e., the elastic part of the response is Hookean and the viscous part is Newtonian. Hookean response relates to the modulus of elasticity where the ratio of normal stress to corresponding strain occurs below the proportional limit of the material where it follows Hooke s law. Newtonian response is where the stress-strain curve is a straight line. 

There are many types of deformation and forces that can be applied to material. One of the foundations of viscoelastic theory is the Boltzmann Superposition Principle. This principle is based on the assumption that the effects of a series of applied stresses acting on a sample results in a strain which is related to the sum of the stresses. The same argument applies to the application of a strain. For example we could apply an instantaneous stress to a body and maintain that stress constant. For a viscoelastic material the strain will increase with time. The ratio of the strain to the stress defines the compliance of the body ... 

Polymers are viscoelastic materials meaning they can act as liquids, the visco portion, and as solids, the elastic portion. Descriptions of the viscoelastic properties of materials generally falls within the area called rheology. Determination of the viscoelastic behavior of materials generally occurs through stress-strain and related measurements. Whether a material behaves as a viscous or elastic material depends on temperature, the particular polymer and its prior treatment, polymer structure, and the particular measurement or conditions applied to the material. The particular property demonstrated by a material under given conditions allows polymers to act as solid or viscous liquids, as plastics, elastomers, or fibers, etc. This chapter deals with the viscoelastic properties of polymers. 

Majerus (61, 62) has approached the failure behavior of highly filled polymers by a thermodynamic treatment in which the ability to resist rupture is related to the propellant s ability to absorb and dissipate energy at a certain rate. An energy criterion which requires failure to be a function of both stress and strain was originally stated by Griffith (36) for brittle materials and later adapted to polymers by Rivlin and Thomas (80). Williams (115) has applied an energy criterion to viscoelastic materials such as solid propellants where appropriate terms are included for viscous energy dissipation. 

When a sinusoidal (harmonic) sound wave propagates through a viscoelastic material, the stresses and strains in the material vay sinusoidally. Eg.22 predicts, in this case, a phase lage between the stress and the strain, which leads to conversion of acoustic energy to heat. From the Fourier transform of Eg.22 it follows that the sinusoidal stress and strain are related by complex, freguency-dependent elastic moduli as follows. 

Consider two experiments carried out with identical samples of a viscoelastic material. In experiment (a) the sample is subjected to a stress CT for a time t. The resulting strain at f is ei, and the creep compliance measured at that time is D t) = e la. ln experiment (b) a sample is stressed to a level CT2 such that strain i is achieved immediately. The stress is then gradually decreased so that the strain remains at f for time t (i.e., the sample does not creep further). The stress on the material at time t will be a-i, and the corresponding relaxation modulus will be y 2(t) = CT3/C1. In measurements of this type, it can be expected that az> 0 > ct and Y t) (D(r)) , as indicated in Eq. (11-14). G(t) and Y t) are obtained directly only from stress relaxation measurements, while D(t) and J(t) require creep experiments for their direct observation. Tliese various parameters can be related in the linear viscoelastic region described in Section 11.5.2. 

Dynamic mechanical measurements are performed at very small strains in order to ensure that linear viscoelasticity relations can be applied to the data. Stress-strain data involve large strain behavior and are accumulated in the nonlinear region. In other words, the tensile test itself alters the structure of the test specimen, which usually cannot be cycled back to its initial state. (Similarly, dynamic deformations at large strains test the fatigue resistance of the material.)... 

The methods utilized to measure the viscoelastic functions are often close to the stress patterns occurring in certain conditions of use of polymeric materials. Consequently, information of technological importance can be obtained from knowledge of these functions. Even the so-called ultimate properties imply molecular mechanisms that are closely related to those involved in viscoelastic behavior. Chapters 16 and 17 deal with the stress-strain multiaxial problems in viscoelasticity. Application of the boundary problems for engineering apphcations is made on the basis of the integral and differential constitutive stress-strain relationships. Several problems of the classical theory of elasticity are revisited as viscoelastic problems. Two special cases that are of special interest from the experimental point of view are studied viscoelastic beams in flexion and viscoelastic rods in torsion. 

Stress is related to strain through constitutive equations. Metals and ceramics typically possess a direct relationship between stress and strain the elastic modulus (2) Polymers, however, may exhibit complex viscoelastic behavior, possessing characteristics of both liquids and solids (4.). Their stress-strain behavior depends on temperature, degree of cure, and thermal history the behavior is made even more complicated in curing systems since material properties change from a low molecular weight liquid to a highly crosslinked solid polymer (2). ... 

In Figure 5.8d an intermediate behavior, called viscoelastic, is depicted such a relation is often called a creep curve, and the time-dependent value of the strain over the stress applied is called creep compliance. On application of the stress, the material at first deforms elastically, i.e., instantaneously, but then it starts to deform with time. After some time the material thus exhibits flow for some materials, the strain can even linearly increase with time (as depicted). When the stress is released, the material instantaneously loses some of it deformation (which is called elastic recovery), and then the deformation decreases ever slower (delayed elasticity), until a constant value is obtained. Part of the deformation is thus permanent and viscous. The material has some memory of its original shape but tends to forget more of it as time passes. 

Figure 13.7 The phase relation is shown between dynamic strain and stress for viscous, elastic, and viscoelastic materials.

Structures and sub-structures composed of a number of different components and/or materials, including traditional materials, obey the same principles of design analysis. Stresses, strains, and displacements within individual components must be related through the characteristics (anisotropy, viscoelasticity, etc.) relevant to the particular material, and loads and displacements must be compatible at component interfaces. Thus, each individual component or sub-component must be treated. 

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